NP-MRD: Showing NP-Card for (1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol (NP0205860)

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Record Information

Version

2.0

Created at

2022-09-05 01:53:08 UTC

Updated at

2022-09-05 01:53:08 UTC

NP-MRD ID

NP0205860

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol

Description

Spirotropin B belongs to the class of organic compounds known as pterocarpans. These are benzo-pyrano-furano-benzene compounds, containing the 6H-[1]benzofuro[3,2-c]chromene skeleton. They are derivatives of isoflavonoids. (1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol is found in Spirotropis longifolia. (1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol was first documented in 2012 (PMID: 22137037). Based on a literature review very few articles have been published on Spirotropin B.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309052203532D          

 32 37  0  0  1  0            999 V2000
    2.8009    4.5783    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4203    3.8464    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5960    3.8101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8638    3.1508    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4831    2.4188    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9266    1.7232    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.3817    2.4113    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2052    2.3613    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.5736    1.6231    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1185    0.9350    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4869    0.1968    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3103    0.1467    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.6787   -0.5915    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.7654    0.8348    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3971    1.5730    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8522    2.2611    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.6756    2.2111    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.0440    1.4729    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    7.6427    0.9052    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    3.2950    0.9850    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
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    1.9749    0.7872    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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    5.0732    0.0286   -1.1492 C   0  0  0  0  0  0  0  0  0  0  0  0
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    0.8627   -1.2191    3.1807 H   0  0  0  0  0  0  0  0  0  0  0  0
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 22  6  1  0
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M  END


  Mrv1652309052203532D          

 32 37  0  0  1  0            999 V2000
    2.8009    4.5783    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4203    3.8464    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5960    3.8101    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8638    3.1508    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0205860

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)=CC[C@]12COC3=C(C=C(O)C4=C3CCC(C)(C)O4)[C@H]1OC1=CC3=C(OCO3)C=C21

> <INCHI_IDENTIFIER>
InChI=1S/C26H28O6/c1-14(2)5-8-26-12-28-22-15-6-7-25(3,4)32-23(15)18(27)9-16(22)24(26)31-19-11-21-20(10-17(19)26)29-13-30-21/h5,9-11,24,27H,6-8,12-13H2,1-4H3/t24-,26-/m1/s1

> <INCHI_KEY>
NDKYXXZPTNWIAM-AOYPEHQESA-N

> <FORMULA>
C26H28O6

> <MOLECULAR_WEIGHT>
436.504

> <EXACT_MASS>
436.188588622

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
60

> <JCHEM_AVERAGE_POLARIZABILITY>
48.094497678292676

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1S,14S)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0^{2,11}.0^{5,10}.0^{15,23}.0^{17,21}]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol

> <JCHEM_LOGP>
5.0215629213333335

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
6

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_ACIDIC>
10.297899657673831

> <JCHEM_PKA_STRONGEST_BASIC>
-4.251147495695446

> <JCHEM_POLAR_SURFACE_AREA>
66.38000000000001

> <JCHEM_REFRACTIVITY>
119.34010000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
2

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1S,14S)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0^{2,11}.0^{5,10}.0^{15,23}.0^{17,21}]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 05-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-SEP-22         0                                  
HETATM    1  C   UNK     0       5.228   8.546   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       4.518   7.180   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       2.979   7.112   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       5.346   5.881   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       4.635   4.515   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       5.463   3.217   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       6.313   4.501   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0       7.850   4.408   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0       8.537   3.030   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       7.688   1.745   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       8.375   0.367   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       9.913   0.274   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      10.600  -1.104   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0      10.762   1.558   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      10.075   2.936   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      10.924   4.221   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      12.461   4.127   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      13.149   2.749   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      14.386   3.666   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      14.266   1.690   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      12.299   1.465   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       6.151   1.839   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       5.053   0.759   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       3.686   1.470   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       2.244   0.930   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       1.055   1.909   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       1.309   3.428   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       2.751   3.968   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       3.940   2.988   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -0.057   4.138   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      -1.155   3.059   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      -0.468   1.681   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   22   29                                             
CONECT    7    6    8                                                       
CONECT    8    7    9                                                       
CONECT    9    8   10   15                                                  
CONECT   10    9   11   22                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13   14                                                  
CONECT   13   12                                                            
CONECT   14   12   15   21                                                  
CONECT   15   14    9   16                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   20   21                                             
CONECT   19   18                                                            
CONECT   20   18                                                            
CONECT   21   18   14                                                       
CONECT   22   10    6   23                                                  
CONECT   23   22   24                                                       
CONECT   24   23   25   29                                                  
CONECT   25   24   26                                                       
CONECT   26   25   27   32                                                  
CONECT   27   26   28   30                                                  
CONECT   28   27   29                                                       
CONECT   29   28   24    6                                                  
CONECT   30   27   31                                                       
CONECT   31   30   32                                                       
CONECT   32   31   26                                                       
MASTER        0    0    0    0    0    0    0    0   32    0   74    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₆H₂₈O₆

Average Mass

436.5040 Da

Monoisotopic Mass

436.18859 Da

IUPAC Name

(1S,14S)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0^{2,11}.0^{5,10}.0^{15,23}.0^{17,21}]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol

Traditional Name

(1S,14S)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0^{2,11}.0^{5,10}.0^{15,23}.0^{17,21}]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol

CAS Registry Number

Not Available

SMILES

CC(C)=CC[C@]12COC3=C(C=C(O)C4=C3CCC(C)(C)O4)[C@H]1OC1=CC3=C(OCO3)C=C21

InChI Identifier

InChI=1S/C26H28O6/c1-14(2)5-8-26-12-28-22-15-6-7-25(3,4)32-23(15)18(27)9-16(22)24(26)31-19-11-21-20(10-17(19)26)29-13-30-21/h5,9-11,24,27H,6-8,12-13H2,1-4H3/t24-,26-/m1/s1

InChI Key

NDKYXXZPTNWIAM-AOYPEHQESA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Spirotropis longifolia	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as pterocarpans. These are benzo-pyrano-furano-benzene compounds, containing the 6H-[1]benzofuro[3,2-c]chromene skeleton. They are derivatives of isoflavonoids.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Isoflavonoids

Sub Class

Furanoisoflavonoids

Direct Parent

Pterocarpans

Alternative Parents

Substituents

Isoflavanol
Pterocarpan
Isoflavan
Pyranochromene
2,2-dimethyl-1-benzopyran
Chromane
Benzopyran
1-benzopyran
Coumaran
Benzofuran
Benzodioxole
1-hydroxy-2-unsubstituted benzenoid
Alkyl aryl ether
Benzenoid
Ether
Acetal
Oxacycle
Organoheterocyclic compound
Hydrocarbon derivative
Organooxygen compound
Organic oxygen compound
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.02	ChemAxon
pKa (Strongest Acidic)	10.3	ChemAxon
pKa (Strongest Basic)	-4.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	66.38 Å²	ChemAxon
Rotatable Bond Count	2	ChemAxon
Refractivity	119.34 m³·mol⁻¹	ChemAxon
Polarizability	48.09 Å³	ChemAxon
Number of Rings	6	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

56958433

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Basset C, Rodrigues AM, Eparvier V, Silva MR, Lopes NP, Sabatier D, Fonty E, Espindola LS, Stien D: Secondary metabolites from Spirotropis longifolia (DC) Baill and their antifungal activity against human pathogenic fungi. Phytochemistry. 2012 Feb;74:166-72. doi: 10.1016/j.phytochem.2011.10.011. Epub 2011 Dec 1. [PubMed:22137037 ]
LOTUS database [Link]

Showing NP-Card for (1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol (NP0205860)

MOL for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

3D MOL for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

3D SDF for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

3D-SDF for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

PDB for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

3D PDB for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

SMILES for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

INCHI for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

Structure for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)

3D Structure for NP0205860 ((1s,14s)-7,7-dimethyl-14-(3-methylbut-2-en-1-yl)-6,12,18,20,24-pentaoxahexacyclo[12.10.0.0²,¹¹.0⁵,¹⁰.0¹⁵,²³.0¹⁷,²¹]tetracosa-2(11),3,5(10),15,17(21),22-hexaen-4-ol)