NP-MRD: Showing NP-Card for 4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate (NP0198415)

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Record Information

Version

2.0

Created at

2022-09-04 16:51:41 UTC

Updated at

2022-09-04 16:51:41 UTC

NP-MRD ID

NP0198415

Secondary Accession Numbers

None

Natural Product Identification

Common Name

4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate

Description

4-(Acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-5-yl benzoate belongs to the class of organic compounds known as agarofurans. These are organic compounds containing an agarofuran moiety( a three-ring system, with core fragment oxatricyclo[7.2.1.0^{1,6}]Dodec-2-ene). 4-(Acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]Dodecan-5-yl benzoate is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1533004161518292D          

 43 47  0  0  0  0            999 V2000
    6.1302    0.3680    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3064    0.4114    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9320    1.1465    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8569   -0.2804    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0331   -0.2371    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6599    0.5054    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1143    1.1940    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8351    0.5561    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0412    1.3549    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0900    0.9101    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.3349   -0.1234    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6531    0.4578    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8934    0.0350    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.5700    0.7940    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1047   -0.2071    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0588   -0.8122    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4269   -1.5948    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2845   -1.6626    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6599   -2.3973    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2114   -3.0897    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3874   -3.0475    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5868   -3.8244    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4107   -3.8666    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.7861   -4.6012    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6100   -4.6434    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9854   -5.3781    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    3.1352   -1.6366    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5838   -0.9369    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    5.1773   -2.4286    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.0016   -2.4605    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3862   -3.1904    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9463   -3.8884    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.1220   -3.8565    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7374   -3.1266    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7368   -0.5133    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1297   -1.2387    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
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  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
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 30 32  1  0  0  0  0
  5 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
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 40 41  2  0  0  0  0
 36 41  1  0  0  0  0
 16 42  1  0  0  0  0
 11 42  1  0  0  0  0
 42 43  1  0  0  0  0
M  END

     RDKit          3D

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   -0.8876    0.8374   -0.2116 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0406    2.0612   -0.8892 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -0.3469    3.2860   -0.5456 C   0  0  0  0  0  0  0  0  0  0  0  0
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M  END


  Mrv1533004161518292D          

 43 47  0  0  0  0            999 V2000
    6.1302    0.3680    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3064    0.4114    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    3.6599    0.5054    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1143    1.1940    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8351    0.5561    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0412    1.3549    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0900    0.9101    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    2.2114   -3.0897    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3874   -3.0475    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5868   -3.8244    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.4107   -3.8666    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.7861   -4.6012    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6100   -4.6434    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9854   -5.3781    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5369   -6.0705    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.7129   -6.0283    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3375   -5.2936    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7420   -0.9114    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.1352   -1.6366    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5838   -0.9369    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9683   -1.6668    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7927   -1.6987    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2326   -1.0007    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.1773   -2.4286    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.0016   -2.4605    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3862   -3.1904    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9463   -3.8884    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.1220   -3.8565    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7374   -3.1266    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7368   -0.5133    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1297   -1.2387    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
  8 10  1  0  0  0  0
  8 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 13 15  1  0  0  0  0
 13 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  2  0  0  0  0
 22 20  1  4  0  0  0
 22 23  2  0  0  0  0
 23 24  1  0  0  0  0
 24 25  2  0  0  0  0
 25 26  1  0  0  0  0
 26 27  2  0  0  0  0
 27 28  1  0  0  0  0
 28 29  2  0  0  0  0
 24 29  1  0  0  0  0
 18 30  1  0  0  0  0
 11 30  1  0  0  0  0
 30 31  1  0  0  0  0
 30 32  1  0  0  0  0
  5 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  2  0  0  0  0
 34 36  1  0  0  0  0
 36 37  2  0  0  0  0
 37 38  1  0  0  0  0
 38 39  2  0  0  0  0
 39 40  1  0  0  0  0
 40 41  2  0  0  0  0
 36 41  1  0  0  0  0
 16 42  1  0  0  0  0
 11 42  1  0  0  0  0
 42 43  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0198415

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(=O)OC1C(O)C(C)(O)C23OC(C)(C)C(CC(OC(=O)C=CC4=CC=CC=C4)C2(C)C1OC(=O)C1=CC=CC=C1)C3O

> <INCHI_IDENTIFIER>
InChI=1S/C33H38O10/c1-19(34)40-25-27(37)32(5,39)33-26(36)22(30(2,3)43-33)18-23(41-24(35)17-16-20-12-8-6-9-13-20)31(33,4)28(25)42-29(38)21-14-10-7-11-15-21/h6-17,22-23,25-28,36-37,39H,18H2,1-5H3

> <INCHI_KEY>
FVTRWXQLJLCVKD-UHFFFAOYSA-N

> <FORMULA>
C33H38O10

> <MOLECULAR_WEIGHT>
594.657

> <EXACT_MASS>
594.246497424

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
81

> <JCHEM_AVERAGE_POLARIZABILITY>
60.51505629929253

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate

> <ALOGPS_LOGP>
3.24

> <JCHEM_LOGP>
3.4377861703333332

> <ALOGPS_LOGS>
-4.79

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.477645805264014

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.482995611468855

> <JCHEM_PKA_STRONGEST_BASIC>
-3.4236379266072268

> <JCHEM_POLAR_SURFACE_AREA>
148.82000000000002

> <JCHEM_REFRACTIVITY>
153.30299999999994

> <JCHEM_ROTATABLE_BOND_COUNT>
9

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
9.72e-03 g/l

> <JCHEM_TRADITIONAL_IUPAC>
4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 16-APR-15   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   16-APR-15         0                                  
HETATM    1  C   UNK     0      11.443   0.687   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       9.905   0.768   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0       9.206   2.140   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       9.066  -0.523   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       7.528  -0.443   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       6.832   0.943   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0       7.680   2.229   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       5.292   1.038   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       5.677   2.529   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0       3.901   1.699   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0       4.358  -0.230   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       3.086   0.855   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0       1.668   0.065   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       1.064   1.482   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       0.195  -0.387   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       1.976  -1.516   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       2.664  -2.977   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       4.264  -3.104   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       4.965  -4.475   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       4.128  -5.767   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       2.590  -5.689   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       4.829  -7.139   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       6.367  -7.218   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       7.067  -8.589   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       8.605  -8.668   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       9.306 -10.039   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       8.469 -11.332   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       6.931 -11.253   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       6.230  -9.881   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       5.118  -1.701   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       5.852  -3.055   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       6.690  -1.749   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       7.408  -3.111   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       8.946  -3.171   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0       9.767  -1.868   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0       9.664  -4.533   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      11.203  -4.593   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      11.921  -5.955   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      11.100  -7.258   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0       9.561  -7.199   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       8.843  -5.836   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0       3.242  -0.958   0.000  0.00  0.00           C+0
HETATM   43  O   UNK     0       3.976  -2.312   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   32                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9   10   11                                             
CONECT    9    8                                                            
CONECT   10    8                                                            
CONECT   11    8   12   30   42                                             
CONECT   12   11   13                                                       
CONECT   13   12   14   15   16                                             
CONECT   14   13                                                            
CONECT   15   13                                                            
CONECT   16   13   17   42                                                  
CONECT   17   16   18                                                       
CONECT   18   17   19   30                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21   22                                                  
CONECT   21   20                                                            
CONECT   22   20   23                                                       
CONECT   23   22   24                                                       
CONECT   24   23   25   29                                                  
CONECT   25   24   26                                                       
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   24                                                       
CONECT   30   18   11   31   32                                             
CONECT   31   30                                                            
CONECT   32   30    5   33                                                  
CONECT   33   32   34                                                       
CONECT   34   33   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34   37   41                                                  
CONECT   37   36   38                                                       
CONECT   38   37   39                                                       
CONECT   39   38   40                                                       
CONECT   40   39   41                                                       
CONECT   41   40   36                                                       
CONECT   42   16   11   43                                                  
CONECT   43   42                                                            
MASTER        0    0    0    0    0    0    0    0   43    0   94    0
END

View in JSmol

Synonyms

Value	Source
4-(Acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0,]dodecan-5-yl benzoic acid	Generator
4-(Acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoic acid	Generator

Chemical Formula

C₃₃H₃₈O₁₀

Average Mass

594.6570 Da

Monoisotopic Mass

594.24650 Da

IUPAC Name

4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate

Traditional Name

4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate

CAS Registry Number

Not Available

SMILES

CC(=O)OC1C(O)C(C)(O)C23OC(C)(C)C(CC(OC(=O)C=CC4=CC=CC=C4)C2(C)C1OC(=O)C1=CC=CC=C1)C3O

InChI Identifier

InChI=1S/C33H38O10/c1-19(34)40-25-27(37)32(5,39)33-26(36)22(30(2,3)43-33)18-23(41-24(35)17-16-20-12-8-6-9-13-20)31(33,4)28(25)42-29(38)21-14-10-7-11-15-21/h6-17,22-23,25-28,36-37,39H,18H2,1-5H3

InChI Key

FVTRWXQLJLCVKD-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as agarofurans. These are organic compounds containing an agarofuran moiety( a three-ring system, with core fragment oxatricyclo[7.2.1.0^{1,6}]Dodec-2-ene).

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Sesquiterpenoids

Direct Parent

Agarofurans

Alternative Parents

Substituents

Agarofuran
Cinnamic acid or derivatives
Cinnamic acid ester
Benzoate ester
Benzoic acid or derivatives
Tricarboxylic acid or derivatives
Benzoyl
Styrene
Fatty acid ester
Oxepane
Cyclitol or derivatives
Monocyclic benzene moiety
Fatty acyl
Benzenoid
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Cyclic alcohol
Tetrahydrofuran
Tertiary alcohol
Carboxylic acid ester
Secondary alcohol
Ether
Dialkyl ether
Carboxylic acid derivative
Organoheterocyclic compound
Oxacycle
Polyol
Organic oxide
Alcohol
Carbonyl group
Organic oxygen compound
Organooxygen compound
Hydrocarbon derivative
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.24	ALOGPS
logP	3.44	ChemAxon
logS	-4.8	ALOGPS
pKa (Strongest Acidic)	12.48	ChemAxon
pKa (Strongest Basic)	-3.4	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	7	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	148.82 Å²	ChemAxon
Rotatable Bond Count	9	ChemAxon
Refractivity	153.3 m³·mol⁻¹	ChemAxon
Polarizability	60.52 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

75166296

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate (NP0198415)

MOL for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

3D MOL for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

3D SDF for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

3D-SDF for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

PDB for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

3D PDB for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

SMILES for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

INCHI for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

Structure for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)

3D Structure for NP0198415 (4-(acetyloxy)-2,3,12-trihydroxy-2,6,10,10-tetramethyl-7-[(3-phenylprop-2-enoyl)oxy]-11-oxatricyclo[7.2.1.0¹,⁶]dodecan-5-yl benzoate)