NP-MRD: Showing NP-Card for [(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate (NP0193240)

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Record Information

Version

2.0

Created at

2022-09-04 10:37:59 UTC

Updated at

2022-09-04 10:37:59 UTC

NP-MRD ID

NP0193240

Secondary Accession Numbers

None

Natural Product Identification

Common Name

[(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate

Description

Cucurbitoside H belongs to the class of organic compounds known as phenolic glycosides. These are organic compounds containing a phenolic structure attached to a glycosyl moiety. Some examples of phenolic structures include lignans, and flavonoids. Among the sugar units found in natural glycosides are D-glucose, L-Fructose, and L rhamnose. [(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate is found in Cucurbita pepo. Based on a literature review very few articles have been published on Cucurbitoside H.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042212382D          

 38 41  0  0  1  0            999 V2000
    1.0722   -0.7325    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2652   -0.5610    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2868   -1.1741    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0938   -1.0026    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6458   -1.6157    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1978   -1.0026    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9784   -2.1006    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2333   -2.8852    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0583   -2.8852    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.5432   -3.5526    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2077   -4.3063    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.3872   -4.3925    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.9023   -3.7251    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0818   -3.8113    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    0.3074    1.6213    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.5623    0.8367    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  6  0  0  0
  5  7  1  0  0  0  0
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  8  9  1  0  0  0  0
  9 10  1  1  0  0  0
 11 10  1  1  0  0  0
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 35 36  2  0  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 33 38  1  0  0  0  0
M  END

     RDKit          3D

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    2.9001   -1.2665   -0.2806 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.3965    0.0069   -0.2488 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -0.4727   -1.4434   -0.0219 H   0  0  0  0  0  0  0  0  0  0  0  0
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M  END


  Mrv1652309042212382D          

 38 41  0  0  1  0            999 V2000
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 11 10  1  1  0  0  0
 11 12  1  0  0  0  0
 12 13  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  2  0  0  0  0
 15 16  1  0  0  0  0
 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 17 21  1  0  0  0  0
 21 22  2  0  0  0  0
 14 22  1  0  0  0  0
 12 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  6  0  0  0
 25 26  1  0  0  0  0
 24 27  1  0  0  0  0
 27 28  1  1  0  0  0
 27 29  1  0  0  0  0
 11 29  1  0  0  0  0
 29 30  1  6  0  0  0
  9 31  1  0  0  0  0
  5 31  1  0  0  0  0
 31 32  1  6  0  0  0
  2 33  1  0  0  0  0
 33 34  2  0  0  0  0
 34 35  1  0  0  0  0
 35 36  2  0  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 33 38  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0193240

> <DATABASE_NAME>
NP-MRD

> <SMILES>
OCCC1=CC=C(O[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O[C@@H]2OC[C@](O)(COC(=O)C3=CC=CN=C3)[C@H]2O)C=C1

> <INCHI_IDENTIFIER>
InChI=1S/C25H31NO12/c27-9-7-14-3-5-16(6-4-14)36-23-20(19(30)18(29)17(11-28)37-23)38-24-21(31)25(33,13-35-24)12-34-22(32)15-2-1-8-26-10-15/h1-6,8,10,17-21,23-24,27-31,33H,7,9,11-13H2/t17-,18-,19+,20-,21+,23-,24+,25-/m1/s1

> <INCHI_KEY>
SXPOXYLEVCBOBE-KXQNOTADSA-N

> <FORMULA>
C25H31NO12

> <MOLECULAR_WEIGHT>
537.518

> <EXACT_MASS>
537.184625442

> <JCHEM_ACCEPTOR_COUNT>
12

> <JCHEM_ATOM_COUNT>
69

> <JCHEM_AVERAGE_POLARIZABILITY>
53.40872435190341

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
6

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
[(3S,4R,5S)-5-{[(2S,3R,4S,5S,6R)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate

> <JCHEM_LOGP>
-1.075947799666666

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.64518461835278

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.792988355974312

> <JCHEM_PKA_STRONGEST_BASIC>
3.24186812750984

> <JCHEM_POLAR_SURFACE_AREA>
197.49

> <JCHEM_REFRACTIVITY>
126.08950000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
11

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
[(3S,4R,5S)-5-{[(2S,3R,4S,5S,6R)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  O   UNK     0       2.001  -1.367   0.000  0.00  0.00           O+0
HETATM    2  C   UNK     0       0.495  -1.047   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      -0.535  -2.192   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0      -2.042  -1.871   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -3.072  -3.016   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      -4.103  -1.871   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0      -1.826  -3.921   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0      -2.302  -5.386   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0      -3.842  -5.386   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0      -4.747  -6.632   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0      -4.121  -8.038   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      -2.589  -8.199   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0      -1.684  -6.954   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0      -0.153  -7.115   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       0.753  -5.869   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       2.284  -6.030   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       2.910  -7.436   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       4.442  -7.597   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       5.068  -9.004   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       6.600  -9.165   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       2.005  -8.682   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       0.474  -8.521   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      -1.963  -9.606   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      -2.868 -10.852   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      -2.242 -12.259   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      -3.147 -13.505   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0      -4.400 -10.691   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -5.305 -11.937   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      -5.026  -9.284   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0      -6.558  -9.123   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0      -4.318  -3.921   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0      -5.783  -3.445   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       0.019   0.417   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -1.487   0.738   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      -1.963   2.202   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      -0.933   3.347   0.000  0.00  0.00           C+0
HETATM   37  N   UNK     0       0.574   3.027   0.000  0.00  0.00           N+0
HETATM   38  C   UNK     0       1.050   1.562   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   33                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6    7   31                                             
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9                                                       
CONECT    9    8   10   31                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12   29                                                  
CONECT   12   11   13   23                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   22                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17                                                       
CONECT   17   16   18   21                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   17   22                                                       
CONECT   22   21   14                                                       
CONECT   23   12   24                                                       
CONECT   24   23   25   27                                                  
CONECT   25   24   26                                                       
CONECT   26   25                                                            
CONECT   27   24   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   11   30                                                  
CONECT   30   29                                                            
CONECT   31    9    5   32                                                  
CONECT   32   31                                                            
CONECT   33    2   34   38                                                  
CONECT   34   33   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35   37                                                       
CONECT   37   36   38                                                       
CONECT   38   37   33                                                       
MASTER        0    0    0    0    0    0    0    0   38    0   82    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₅H₃₁NO₁₂

Average Mass

537.5180 Da

Monoisotopic Mass

537.18463 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

OCCC1=CC=C(O[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O[C@@H]2OC[C@](O)(COC(=O)C3=CC=CN=C3)[C@H]2O)C=C1

InChI Identifier

InChI=1S/C25H31NO12/c27-9-7-14-3-5-16(6-4-14)36-23-20(19(30)18(29)17(11-28)37-23)38-24-21(31)25(33,13-35-24)12-34-22(32)15-2-1-8-26-10-15/h1-6,8,10,17-21,23-24,27-31,33H,7,9,11-13H2/t17-,18-,19+,20-,21+,23-,24+,25-/m1/s1

InChI Key

SXPOXYLEVCBOBE-KXQNOTADSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Cucurbita pepo	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as phenolic glycosides. These are organic compounds containing a phenolic structure attached to a glycosyl moiety. Some examples of phenolic structures include lignans, and flavonoids. Among the sugar units found in natural glycosides are D-glucose, L-Fructose, and L rhamnose.

Kingdom

Organic compounds

Super Class

Organic oxygen compounds

Class

Organooxygen compounds

Sub Class

Carbohydrates and carbohydrate conjugates

Direct Parent

Phenolic glycosides

Alternative Parents

Substituents

Phenolic glycoside
Disaccharide
O-glycosyl compound
Tyrosol derivative
Pyridine carboxylic acid
Pyridine carboxylic acid or derivatives
Phenoxy compound
Phenol ether
Monocyclic benzene moiety
Oxane
Pyridine
Benzenoid
Heteroaromatic compound
Oxolane
Tertiary alcohol
Secondary alcohol
Carboxylic acid ester
Acetal
Carboxylic acid derivative
Monocarboxylic acid or derivatives
Oxacycle
Azacycle
Organoheterocyclic compound
Organic oxide
Hydrocarbon derivative
Organonitrogen compound
Organic nitrogen compound
Alcohol
Organopnictogen compound
Primary alcohol
Aromatic heteromonocyclic compound

Molecular Framework

Aromatic heteromonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00042420

Chemspider ID

9686966

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

11512173

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for [(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate (NP0193240)

MOL for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

3D MOL for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

3D SDF for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

3D-SDF for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

PDB for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

3D PDB for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

SMILES for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

INCHI for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

Structure for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)

3D Structure for NP0193240 ([(3s,4r,5s)-5-{[(2s,3r,4s,5s,6r)-4,5-dihydroxy-2-[4-(2-hydroxyethyl)phenoxy]-6-(hydroxymethyl)oxan-3-yl]oxy}-3,4-dihydroxyoxolan-3-yl]methyl pyridine-3-carboxylate)