NP-MRD: Showing NP-Card for (1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate (NP0192377)

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Record Information

Version

2.0

Created at

2022-09-04 09:34:40 UTC

Updated at

2022-09-04 09:34:41 UTC

NP-MRD ID

NP0192377

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate

Description

Cinnzeylanin belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units. (1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate is found in Persea indica. Based on a literature review very few articles have been published on Cinnzeylanin.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042211342D          

 30 34  0  0  1  0            999 V2000
    4.9783    2.2977    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.1699    1.4952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9606    1.2599    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.5707    0.9281    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7623    0.1256    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.5982   -0.0394    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    6.1341    0.5878    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8872   -0.8272    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2684   -1.4024    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4371   -1.1906    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.5905   -2.0012    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7279   -1.7007    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.3483   -2.2445    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3307   -2.4417    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9322   -1.6920    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.2161   -2.1016    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6309   -1.0985    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0920   -0.3986    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.2017   -0.2871    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.9644    0.5031    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.4598   -0.9224    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.9172   -1.5439    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6942   -0.5850    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.1783   -1.2287    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2051    0.0794    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3852   -0.0120    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5360    0.8351    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4653   -0.2824    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0495   -1.0337    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.4332   -1.5823    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  6  0  0  0
  5  6  1  0  0  0  0
  6  7  1  1  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  1  0  0  0
 10 12  1  0  0  0  0
 12 13  1  1  0  0  0
 12 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  6  0  0  0
 15 17  1  0  0  0  0
 18 17  1  6  0  0  0
  5 18  1  0  0  0  0
 10 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  1  0  0  0
 19 21  1  0  0  0  0
 15 21  1  0  0  0  0
 21 22  1  6  0  0  0
 21 23  1  0  0  0  0
 23 24  1  6  0  0  0
 23 25  1  1  0  0  0
 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
 23 28  1  0  0  0  0
 28 29  1  0  0  0  0
 12 29  1  0  0  0  0
 19 29  1  0  0  0  0
 29 30  1  1  0  0  0
M  END

     RDKit          3D

 64 68  0  0  0  0  0  0  0  0999 V2000
   -2.7510   -1.8109    4.0378 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7316   -0.8368    2.9153 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1108    0.3355    3.1642 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3067   -1.2186    1.6364 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3082   -0.2707    0.6253 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.3147   -0.6968   -0.4554 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.5784   -1.2077    0.1279 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5584    0.4424   -1.4215 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2631    0.9206   -2.0269 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2954    1.2180   -0.9534 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.7302    2.1772   -0.0742 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.0982    1.5175   -1.3690 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2652    2.7902   -2.1350 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7274    0.3410   -2.0700 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6797   -0.8877   -1.2344 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.2224   -1.9659   -1.8893 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6941   -1.1101   -0.9518 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0341   -0.0520   -0.1086 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.1642    0.3290    0.6549 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.0616    0.3862    2.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1970   -0.7004    0.1647 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.0790   -2.0105    0.8816 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4827   -0.0162    0.3161 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.8021    0.0111    1.6967 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6719   -0.5677   -0.3754 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0871   -1.9518    0.0514 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9026    0.3263   -0.2097 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2159    1.4301   -0.0426 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7415    1.5942    0.0208 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.3173    2.7379    0.6636 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7971   -1.9655    4.4206 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3918   -2.8050    3.7162 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1169   -1.4575    4.8700 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6693    0.7364    0.9802 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8228   -1.5093   -1.0278 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3016   -1.9835    0.9011 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1230   -1.7749   -0.6567 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1946   -0.4428    0.6172 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.2516    0.0535   -2.1953 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0990    1.2248   -0.8704 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9197    0.1506   -2.7123 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4623    1.8525   -2.5950 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5141    2.6846   -0.3604 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.1936    2.7041   -2.7471 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5708    2.8927   -2.8616 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.3238    3.6921   -1.4898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0933    0.1409   -2.9844 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.7130    0.6095   -2.4752 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5869   -1.7390   -2.7797 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1943    1.3224    2.2672 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0147   -2.3203    0.9009 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -2.7753    0.2497 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5327   -1.9629    1.8772 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.3153    0.8446    1.9084 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.4968   -0.6301   -1.4750 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7697   -2.7457   -0.6722 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7595   -2.2508    1.0443 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.2088   -2.0545    0.0641 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.7595    1.1856   -0.8925 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.0714    0.6071    0.8377 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.7532   -0.2555   -0.6115 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.6519    1.6958   -1.0305 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.6884    2.1210    0.6839 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.8700    2.9010    1.4593 H   0  0  0  0  0  0  0  0  0  0  0  0
 26 25  1  0
 25 27  1  0
 25 23  1  0
 23 24  1  1
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 29 30  1  1
 29 12  1  0
 12 13  1  6
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 18 17  1  6
 18  5  1  0
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  2  1  1  0
  2  3  2  0
  5  6  1  0
  6  7  1  0
  6  8  1  0
  8  9  1  0
  9 10  1  0
 10 11  1  1
 18 19  1  0
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 21 23  1  0
 19 29  1  0
 10 12  1  0
 21 15  1  0
 10 18  1  0
 26 56  1  0
 26 57  1  0
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 25 55  1  0
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 24 54  1  0
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 28 63  1  0
 30 64  1  0
 13 44  1  0
 13 45  1  0
 13 46  1  0
 14 47  1  0
 14 48  1  0
 16 49  1  0
  5 34  1  1
  1 31  1  0
  1 32  1  0
  1 33  1  0
  6 35  1  6
  7 36  1  0
  7 37  1  0
  7 38  1  0
  8 39  1  0
  8 40  1  0
  9 41  1  0
  9 42  1  0
 11 43  1  0
 20 50  1  0
 22 51  1  0
 22 52  1  0
 22 53  1  0
M  END


  Mrv1652309042211342D          

 30 34  0  0  1  0            999 V2000
    4.9783    2.2977    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.1699    1.4952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9606    1.2599    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.5707    0.9281    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7623    0.1256    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.5982   -0.0394    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    6.1341    0.5878    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8872   -0.8272    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.2684   -1.4024    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.4371   -1.1906    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.5905   -2.0012    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7279   -1.7007    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.3483   -2.2445    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3307   -2.4417    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.9322   -1.6920    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.2161   -2.1016    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6309   -1.0985    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0920   -0.3986    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.2017   -0.2871    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.9644    0.5031    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.4598   -0.9224    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.9172   -1.5439    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6942   -0.5850    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.1783   -1.2287    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2051    0.0794    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3852   -0.0120    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5360    0.8351    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4653   -0.2824    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0495   -1.0337    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.4332   -1.5823    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  5  4  1  6  0  0  0
  5  6  1  0  0  0  0
  6  7  1  1  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  1  0  0  0
 10 12  1  0  0  0  0
 12 13  1  1  0  0  0
 12 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  6  0  0  0
 15 17  1  0  0  0  0
 18 17  1  6  0  0  0
  5 18  1  0  0  0  0
 10 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  1  0  0  0
 19 21  1  0  0  0  0
 15 21  1  0  0  0  0
 21 22  1  6  0  0  0
 21 23  1  0  0  0  0
 23 24  1  6  0  0  0
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 25 26  1  0  0  0  0
 25 27  1  0  0  0  0
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 12 29  1  0  0  0  0
 19 29  1  0  0  0  0
 29 30  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0192377

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)[C@@]1(O)C[C@@]2(O)[C@@]3(C)C[C@]4(O)O[C@@]5([C@H](OC(C)=O)[C@@H](C)CC[C@]35O)[C@@]2(O)[C@]14C

> <INCHI_IDENTIFIER>
InChI=1S/C22H34O8/c1-11(2)17(24)10-19(26)15(5)9-20(27)16(17,6)22(19,28)21(30-20)14(29-13(4)23)12(3)7-8-18(15,21)25/h11-12,14,24-28H,7-10H2,1-6H3/t12-,14+,15-,16+,17-,18-,19+,20-,21+,22+/m0/s1

> <INCHI_KEY>
DFYFOAFKHRTQLA-PIKMFBPASA-N

> <FORMULA>
C22H34O8

> <MOLECULAR_WEIGHT>
426.506

> <EXACT_MASS>
426.225368055

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
64

> <JCHEM_AVERAGE_POLARIZABILITY>
51.876379895048366

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
5

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1R,2R,3S,6S,7R,9S,10S,11S,13R,14R)-6,9,11,13,14-pentahydroxy-3,7,10-trimethyl-11-(propan-2-yl)-15-oxapentacyclo[7.5.1.0^{1,6}.0^{7,13}.0^{10,14}]pentadecan-2-yl acetate

> <JCHEM_LOGP>
-0.26191288600000007

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.122166701644785

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.320110998745221

> <JCHEM_PKA_STRONGEST_BASIC>
-3.3022929800087146

> <JCHEM_POLAR_SURFACE_AREA>
136.68

> <JCHEM_REFRACTIVITY>
102.65899999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
3

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2R,3S,6S,7R,9S,10S,11S,13R,14R)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0^{1,6}.0^{7,13}.0^{10,14}]pentadecan-2-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0       9.293   4.289   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       9.650   2.791   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      11.126   2.352   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0       8.532   1.732   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       8.890   0.234   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      10.450  -0.074   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      11.450   1.097   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      10.989  -1.544   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       9.834  -2.618   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       8.282  -2.223   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       8.569  -3.736   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       6.959  -3.175   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       8.117  -4.190   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       6.217  -4.558   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       5.474  -3.158   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       4.137  -3.923   0.000  0.00  0.00           O+0
HETATM   17  O   UNK     0       6.778  -2.051   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       7.638  -0.744   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       5.976  -0.536   0.000  0.00  0.00           C+0
HETATM   20  O   UNK     0       5.534   0.939   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       4.592  -1.722   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       3.579  -2.882   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       3.163  -1.092   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       2.199  -2.294   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       2.250   0.148   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       0.719  -0.022   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.867   1.559   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.602  -0.527   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       5.692  -1.930   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       4.542  -2.954   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6   18                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   12   18                                             
CONECT   11   10                                                            
CONECT   12   10   13   14   29                                             
CONECT   13   12                                                            
CONECT   14   12   15                                                       
CONECT   15   14   16   17   21                                             
CONECT   16   15                                                            
CONECT   17   15   18                                                       
CONECT   18   17    5   10   19                                             
CONECT   19   18   20   21   29                                             
CONECT   20   19                                                            
CONECT   21   19   15   22   23                                             
CONECT   22   21                                                            
CONECT   23   21   24   25   28                                             
CONECT   24   23                                                            
CONECT   25   23   26   27                                                  
CONECT   26   25                                                            
CONECT   27   25                                                            
CONECT   28   23   29                                                       
CONECT   29   28   12   19   30                                             
CONECT   30   29                                                            
MASTER        0    0    0    0    0    0    0    0   30    0   68    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₂H₃₄O₈

Average Mass

426.5060 Da

Monoisotopic Mass

426.22537 Da

IUPAC Name

(1R,2R,3S,6S,7R,9S,10S,11S,13R,14R)-6,9,11,13,14-pentahydroxy-3,7,10-trimethyl-11-(propan-2-yl)-15-oxapentacyclo[7.5.1.0^{1,6}.0^{7,13}.0^{10,14}]pentadecan-2-yl acetate

Traditional Name

(1R,2R,3S,6S,7R,9S,10S,11S,13R,14R)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0^{1,6}.0^{7,13}.0^{10,14}]pentadecan-2-yl acetate

CAS Registry Number

Not Available

SMILES

CC(C)[C@@]1(O)C[C@@]2(O)[C@@]3(C)C[C@]4(O)O[C@@]5([C@H](OC(C)=O)[C@@H](C)CC[C@]35O)[C@@]2(O)[C@]14C

InChI Identifier

InChI=1S/C22H34O8/c1-11(2)17(24)10-19(26)15(5)9-20(27)16(17,6)22(19,28)21(30-20)14(29-13(4)23)12(3)7-8-18(15,21)25/h11-12,14,24-28H,7-10H2,1-6H3/t12-,14+,15-,16+,17-,18-,19+,20-,21+,22+/m0/s1

InChI Key

DFYFOAFKHRTQLA-PIKMFBPASA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Persea indica	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Diterpenoids

Direct Parent

Diterpenoids

Alternative Parents

Substituents

Diterpenoid
Ryanodane diterpenoid
Oxepane
Monosaccharide
Oxane
Cyclic alcohol
Tertiary alcohol
Tetrahydrofuran
Hemiacetal
Carboxylic acid ester
Organoheterocyclic compound
Oxacycle
Monocarboxylic acid or derivatives
Carboxylic acid derivative
Polyol
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Alcohol
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	-0.26	ChemAxon
pKa (Strongest Acidic)	11.32	ChemAxon
pKa (Strongest Basic)	-3.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	7	ChemAxon
Hydrogen Donor Count	5	ChemAxon
Polar Surface Area	136.68 Å²	ChemAxon
Rotatable Bond Count	3	ChemAxon
Refractivity	102.66 m³·mol⁻¹	ChemAxon
Polarizability	51.88 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

C00055301

Chemspider ID

103883396

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

101306938

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate (NP0192377)

MOL for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

3D MOL for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

3D SDF for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

3D-SDF for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

PDB for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

3D PDB for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

SMILES for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

INCHI for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

Structure for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)

3D Structure for NP0192377 ((1r,2r,3s,6s,7r,9s,10s,11s,13r,14r)-6,9,11,13,14-pentahydroxy-11-isopropyl-3,7,10-trimethyl-15-oxapentacyclo[7.5.1.0¹,⁶.0⁷,¹³.0¹⁰,¹⁴]pentadecan-2-yl acetate)