NP-MRD: Showing NP-Card for (1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione (NP0188427)

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Record Information

Version

2.0

Created at

2022-09-04 04:45:33 UTC

Updated at

2022-09-04 04:45:33 UTC

NP-MRD ID

NP0188427

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione

Description

Formosterol B belongs to the class of organic compounds known as cholesterols and derivatives. Cholesterols and derivatives are compounds containing a 3-hydroxylated cholestane core. (1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione is found in Gibellula formosana. Based on a literature review very few articles have been published on Formosterol B.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042206452D          

 35 39  0  0  1  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309042206452D          

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    4.4247   -3.1470    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.1444   -3.9229    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8928   -2.5163    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.5330   -3.2587    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  6  0  0  0
  3  2  1  6  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  3  5  1  0  0  0  0
  5  6  1  6  0  0  0
  6  7  1  1  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
  8 10  1  0  0  0  0
  8 11  1  0  0  0  0
 12  2  1  1  0  0  0
 12 13  1  0  0  0  0
 13 14  1  1  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  1  0  0  0
 16 18  1  0  0  0  0
 18 19  2  0  0  0  0
 19 20  1  0  0  0  0
 21 20  1  1  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 23 24  2  0  0  0  0
 23 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 21 27  1  0  0  0  0
 27 28  1  1  0  0  0
 27 29  1  0  0  0  0
 29 18  1  1  0  0  0
 29 30  1  0  0  0  0
 30 31  2  0  0  0  0
 30 32  1  0  0  0  0
 32 33  1  6  0  0  0
 32 34  1  0  0  0  0
 12 34  1  0  0  0  0
 16 34  1  0  0  0  0
 34 35  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0188427

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H]([C@@H]1O[C@@H]1[C@H](C)C(C)(C)O)[C@H]1[C@@H](O)C[C@]2(O)C3=CC[C@H]4CC(=O)CC[C@]4(C)[C@H]3C(=O)[C@H](O)[C@]12C

> <INCHI_IDENTIFIER>
InChI=1S/C28H42O7/c1-13(22-23(35-22)14(2)25(3,4)33)19-18(30)12-28(34)17-8-7-15-11-16(29)9-10-26(15,5)20(17)21(31)24(32)27(19,28)6/h8,13-15,18-20,22-24,30,32-34H,7,9-12H2,1-6H3/t13-,14-,15-,18-,19-,20+,22-,23+,24-,26-,27-,28-/m0/s1

> <INCHI_KEY>
RZIUDOGWMCMHAN-JBBRKPIOSA-N

> <FORMULA>
C28H42O7

> <MOLECULAR_WEIGHT>
490.637

> <EXACT_MASS>
490.293053692

> <JCHEM_ACCEPTOR_COUNT>
7

> <JCHEM_ATOM_COUNT>
77

> <JCHEM_AVERAGE_POLARIZABILITY>
53.67399415002315

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1R,2S,7S,11S,13S,14R,15S,16R)-11,13,16-trihydroxy-14-[(1S)-1-[(2S,3R)-3-[(2S)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-9-ene-5,17-dione

> <JCHEM_LOGP>
1.010479757000002

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.464080634433675

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.00309131288769

> <JCHEM_PKA_STRONGEST_BASIC>
-2.8026320405243945

> <JCHEM_POLAR_SURFACE_AREA>
127.59

> <JCHEM_REFRACTIVITY>
130.16969999999995

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2S,7S,11S,13S,14R,15S,16R)-11,13,16-trihydroxy-14-[(1S)-1-[(2S,3R)-3-[(2S)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-9-ene-5,17-dione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0       5.363  -7.289   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       4.782  -5.863   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       3.257  -5.652   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       1.830  -6.233   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       2.041  -4.707   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       1.461  -3.281   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       2.406  -2.065   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      -0.065  -3.070   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      -1.590  -2.859   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -0.276  -4.595   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       0.146  -1.544   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       5.727  -4.647   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       5.299  -3.168   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       3.851  -2.645   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       6.574  -2.304   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0       7.790  -3.249   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       8.159  -1.754   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       9.306  -2.978   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       9.829  -1.529   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      11.345  -1.258   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      12.338  -2.436   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      13.854  -2.164   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      14.846  -3.342   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      16.362  -3.071   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0      14.323  -4.790   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      12.807  -5.061   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      11.814  -3.884   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      11.291  -5.332   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      10.299  -4.155   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       9.775  -5.603   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0      10.768  -6.781   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0       8.259  -5.874   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       7.736  -7.323   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       7.267  -4.697   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       6.595  -6.083   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   12                                                  
CONECT    3    2    4    5                                                  
CONECT    4    3    5                                                       
CONECT    5    4    3    6                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9   10   11                                             
CONECT    9    8                                                            
CONECT   10    8                                                            
CONECT   11    8                                                            
CONECT   12    2   13   34                                                  
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16                                                       
CONECT   16   15   17   18   34                                             
CONECT   17   16                                                            
CONECT   18   16   19   29                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21                                                       
CONECT   21   20   22   27                                                  
CONECT   22   21   23                                                       
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26                                                       
CONECT   26   25   27                                                       
CONECT   27   26   21   28   29                                             
CONECT   28   27                                                            
CONECT   29   27   18   30                                                  
CONECT   30   29   31   32                                                  
CONECT   31   30                                                            
CONECT   32   30   33   34                                                  
CONECT   33   32                                                            
CONECT   34   32   12   16   35                                             
CONECT   35   34                                                            
MASTER        0    0    0    0    0    0    0    0   35    0   78    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₈H₄₂O₇

Average Mass

490.6370 Da

Monoisotopic Mass

490.29305 Da

IUPAC Name

(1R,2S,7S,11S,13S,14R,15S,16R)-11,13,16-trihydroxy-14-[(1S)-1-[(2S,3R)-3-[(2S)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-2,15-dimethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-9-ene-5,17-dione

Traditional Name

CAS Registry Number

Not Available

SMILES

C[C@H]([C@@H]1O[C@@H]1[C@H](C)C(C)(C)O)[C@H]1[C@@H](O)C[C@]2(O)C3=CC[C@H]4CC(=O)CC[C@]4(C)[C@H]3C(=O)[C@H](O)[C@]12C

InChI Identifier

InChI=1S/C28H42O7/c1-13(22-23(35-22)14(2)25(3,4)33)19-18(30)12-28(34)17-8-7-15-11-16(29)9-10-26(15,5)20(17)21(31)24(32)27(19,28)6/h8,13-15,18-20,22-24,30,32-34H,7,9-12H2,1-6H3/t13-,14-,15-,18-,19-,20+,22-,23+,24-,26-,27-,28-/m0/s1

InChI Key

RZIUDOGWMCMHAN-JBBRKPIOSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Gibellula formosana	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as cholesterols and derivatives. Cholesterols and derivatives are compounds containing a 3-hydroxylated cholestane core.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Cholestane steroids

Direct Parent

Cholesterols and derivatives

Alternative Parents

Substituents

Cholesterol-skeleton
3-oxo-delta-7-steroid
3-oxosteroid
12-hydroxysteroid
14-hydroxysteroid
Hydroxysteroid
3-oxo-5-alpha-steroid
16-hydroxysteroid
16-beta-hydroxysteroid
11-oxosteroid
Oxosteroid
Delta-7-steroid
Tertiary alcohol
Cyclic alcohol
Secondary alcohol
Ketone
Cyclic ketone
Polyol
Dialkyl ether
Oxirane
Ether
Oxacycle
Organoheterocyclic compound
Organooxygen compound
Organic oxygen compound
Organic oxide
Alcohol
Carbonyl group
Hydrocarbon derivative
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.01	ChemAxon
pKa (Strongest Acidic)	12	ChemAxon
pKa (Strongest Basic)	-2.8	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	7	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	127.59 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	130.17 m³·mol⁻¹	ChemAxon
Polarizability	53.67 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

78437450

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

139585865

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione (NP0188427)

MOL for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

3D MOL for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

3D SDF for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

3D-SDF for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

PDB for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

3D PDB for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

SMILES for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

INCHI for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

Structure for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)

3D Structure for NP0188427 ((1r,2s,3as,5as,9as,9br,11r,11as)-2,3a,11-trihydroxy-1-[(1s)-1-[(2s,3r)-3-[(2s)-3-hydroxy-3-methylbutan-2-yl]oxiran-2-yl]ethyl]-9a,11a-dimethyl-1h,2h,3h,5h,5ah,6h,8h,9h,9bh,11h-cyclopenta[a]phenanthrene-7,10-dione)