NP-MRD: Showing NP-Card for methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate (NP0188232)

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Record Information

Version

2.0

Created at

2022-09-04 04:31:35 UTC

Updated at

2022-09-04 04:31:35 UTC

NP-MRD ID

NP0188232

Secondary Accession Numbers

None

Natural Product Identification

Common Name

methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate

Description

CHEMBL3582106 belongs to the class of organic compounds known as dihydropyranones. Dihydropyranones are compounds containing a hydrogenated pyran ring which bears a ketone, and contains one double bond. methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate is found in Cipadessa baccifera. Based on a literature review very few articles have been published on CHEMBL3582106.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042206312D          

 36 40  0  0  1  0            999 V2000
    3.3179   -6.0523    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.7954   -5.3795    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.4516   -4.6296    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.6302   -4.5524    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.9291   -3.9568    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.5853   -3.2069    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.7639   -3.1297    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8305   -3.9520    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9657   -3.3381    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4200   -2.3798    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5987   -2.3026    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8976   -1.7070    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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  1  2  1  0  0  0  0
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  7  8  1  0  0  0  0
  7  9  1  0  0  0  0
  7 10  1  0  0  0  0
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 34 16  1  6  0  0  0
 34 35  1  0  0  0  0
  6 35  1  0  0  0  0
 14 35  1  0  0  0  0
 35 36  1  1  0  0  0
M  END

     RDKit          3D

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M  END


  Mrv1652309042206312D          

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 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 17 19  1  0  0  0  0
 19 20  2  0  0  0  0
 20 21  1  0  0  0  0
 21 22  2  0  0  0  0
 21 23  1  0  0  0  0
 23 24  1  0  0  0  0
 24 25  1  1  0  0  0
 25 26  1  0  0  0  0
 26 27  2  0  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 25 29  2  0  0  0  0
 24 30  1  0  0  0  0
 19 30  1  0  0  0  0
 30 31  1  1  0  0  0
 30 32  1  0  0  0  0
 32 33  1  1  0  0  0
 32 34  1  0  0  0  0
 34 16  1  6  0  0  0
 34 35  1  0  0  0  0
  6 35  1  0  0  0  0
 14 35  1  0  0  0  0
 35 36  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0188232

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)C[C@@H]1[C@]2(C)[C@@H](OC3=C(C)C4=CC(=O)O[C@@H](C5=COC=C5)[C@]4(C)[C@@H](O)[C@H]23)[C@@H](O)[C@@H](O)C1(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C27H34O9/c1-12-14-9-17(29)35-23(13-7-8-34-11-13)26(14,4)21(31)18-20(12)36-24-19(30)22(32)25(2,3)15(27(18,24)5)10-16(28)33-6/h7-9,11,15,18-19,21-24,30-32H,10H2,1-6H3/t15-,18+,19-,21-,22+,23-,24-,26-,27-/m0/s1

> <INCHI_KEY>
GPZPYMSRAMXUEU-ASYAXOBVSA-N

> <FORMULA>
C27H34O9

> <MOLECULAR_WEIGHT>
502.56

> <EXACT_MASS>
502.220282675

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
70

> <JCHEM_AVERAGE_POLARIZABILITY>
51.665867928136265

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
methyl 2-[(7R,8S,9S,10S,11S,12S,14S,15S,16R)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0^{3,8}.0^{11,16}]heptadeca-1,3-dien-12-yl]acetate

> <JCHEM_LOGP>
0.8445274983333342

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.060775349692172

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.025488654001766

> <JCHEM_PKA_STRONGEST_BASIC>
-2.8838601999478843

> <JCHEM_POLAR_SURFACE_AREA>
135.66

> <JCHEM_REFRACTIVITY>
127.491

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
methyl [(7R,8S,9S,10S,11S,12S,14S,15S,16R)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0^{3,8}.0^{11,16}]heptadeca-1,3-dien-12-yl]acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0       6.193 -11.298   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       7.085 -10.042   0.000  0.00  0.00           O+0
HETATM    3  C   UNK     0       6.443  -8.642   0.000  0.00  0.00           C+0
HETATM    4  O   UNK     0       4.910  -8.498   0.000  0.00  0.00           O+0
HETATM    5  C   UNK     0       7.334  -7.386   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       6.693  -5.986   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       5.159  -5.842   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       5.284  -7.377   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       3.669  -6.231   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       4.517  -4.442   0.000  0.00  0.00           C+0
HETATM   11  O   UNK     0       2.984  -4.298   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0       5.409  -3.186   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       4.767  -1.787   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       6.942  -3.331   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0       8.075  -2.288   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0       9.417  -3.043   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      10.876  -2.551   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      11.180  -1.041   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      12.032  -3.569   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      13.491  -3.077   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      14.647  -4.094   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0      16.107  -3.602   0.000  0.00  0.00           O+0
HETATM   23  O   UNK     0      14.344  -5.604   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      12.884  -6.096   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      12.581  -7.606   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      13.624  -8.739   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      12.869 -10.081   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      11.359  -9.777   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0      11.181  -8.248   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      11.729  -5.078   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      11.425  -6.588   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      10.269  -5.570   0.000  0.00  0.00           C+0
HETATM   33  O   UNK     0       9.966  -7.080   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       9.114  -4.553   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       7.584  -4.730   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       8.369  -6.056   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6                                                       
CONECT    6    5    7   35                                                  
CONECT    7    6    8    9   10                                             
CONECT    8    7                                                            
CONECT    9    7                                                            
CONECT   10    7   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13   14                                                  
CONECT   13   12                                                            
CONECT   14   12   15   35                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17   34                                                  
CONECT   17   16   18   19                                                  
CONECT   18   17                                                            
CONECT   19   17   20   30                                                  
CONECT   20   19   21                                                       
CONECT   21   20   22   23                                                  
CONECT   22   21                                                            
CONECT   23   21   24                                                       
CONECT   24   23   25   30                                                  
CONECT   25   24   26   29                                                  
CONECT   26   25   27                                                       
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   25                                                       
CONECT   30   24   19   31   32                                             
CONECT   31   30                                                            
CONECT   32   30   33   34                                                  
CONECT   33   32                                                            
CONECT   34   32   16   35                                                  
CONECT   35   34    6   14   36                                             
CONECT   36   35                                                            
MASTER        0    0    0    0    0    0    0    0   36    0   80    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₇H₃₄O₉

Average Mass

502.5600 Da

Monoisotopic Mass

502.22028 Da

IUPAC Name

methyl 2-[(7R,8S,9S,10S,11S,12S,14S,15S,16R)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0^{3,8}.0^{11,16}]heptadeca-1,3-dien-12-yl]acetate

Traditional Name

methyl [(7R,8S,9S,10S,11S,12S,14S,15S,16R)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0^{3,8}.0^{11,16}]heptadeca-1,3-dien-12-yl]acetate

CAS Registry Number

Not Available

SMILES

COC(=O)C[C@@H]1[C@]2(C)[C@@H](OC3=C(C)C4=CC(=O)O[C@@H](C5=COC=C5)[C@]4(C)[C@@H](O)[C@H]23)[C@@H](O)[C@@H](O)C1(C)C

InChI Identifier

InChI=1S/C27H34O9/c1-12-14-9-17(29)35-23(13-7-8-34-11-13)26(14,4)21(31)18-20(12)36-24-19(30)22(32)25(2,3)15(27(18,24)5)10-16(28)33-6/h7-9,11,15,18-19,21-24,30-32H,10H2,1-6H3/t15-,18+,19-,21-,22+,23-,24-,26-,27-/m0/s1

InChI Key

GPZPYMSRAMXUEU-ASYAXOBVSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Cipadessa baccifera	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as dihydropyranones. Dihydropyranones are compounds containing a hydrogenated pyran ring which bears a ketone, and contains one double bond.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Pyrans

Sub Class

Pyranones and derivatives

Direct Parent

Dihydropyranones

Alternative Parents

Substituents

Dihydropyranone
Dicarboxylic acid or derivatives
Cyclic alcohol
Furan
Tetrahydrofuran
Methyl ester
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Heteroaromatic compound
Secondary alcohol
Lactone
Carboxylic acid ester
Polyol
Carboxylic acid derivative
Oxacycle
Organooxygen compound
Organic oxide
Carbonyl group
Alcohol
Organic oxygen compound
Hydrocarbon derivative
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	0.84	ChemAxon
pKa (Strongest Acidic)	13.03	ChemAxon
pKa (Strongest Basic)	-2.9	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	3	ChemAxon
Polar Surface Area	135.66 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	127.49 m³·mol⁻¹	ChemAxon
Polarizability	51.67 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

59006329

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

122179353

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate (NP0188232)

MOL for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

3D MOL for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

3D SDF for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

3D-SDF for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

PDB for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

3D PDB for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

SMILES for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

INCHI for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

Structure for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)

3D Structure for NP0188232 (methyl 2-[(7s,8s,9s,10s,11s,12s,14s,15s,16r)-7-(furan-3-yl)-9,14,15-trihydroxy-2,8,11,13,13-pentamethyl-5-oxo-6,17-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁶]heptadeca-1,3-dien-12-yl]acetate)