Record Information |
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Version | 1.0 |
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Created at | 2022-09-04 00:54:10 UTC |
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Updated at | 2022-09-04 00:54:10 UTC |
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NP-MRD ID | NP0185480 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | (3r,4r,5r,6s)-6-{[(1s,4ar,5s,7as)-7-(hydroxymethyl)-1-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-1h,4ah,5h,7ah-cyclopenta[c]pyran-5-yl]oxy}-4,5-dihydroxyoxan-3-yl (2e)-3-(4-hydroxyphenyl)prop-2-enoate |
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Description | Phlomoidoside belongs to the class of organic compounds known as iridoid o-glycosides. These are iridoid monoterpenes containing a glycosyl (usually a pyranosyl) moiety linked to the iridoid skeleton. (3r,4r,5r,6s)-6-{[(1s,4ar,5s,7as)-7-(hydroxymethyl)-1-{[(2s,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-1h,4ah,5h,7ah-cyclopenta[c]pyran-5-yl]oxy}-4,5-dihydroxyoxan-3-yl (2e)-3-(4-hydroxyphenyl)prop-2-enoate is found in Verbascum phlomoides. Based on a literature review very few articles have been published on Phlomoidoside. |
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Structure | OC[C@H]1O[C@@H](O[C@@H]2OC=C[C@H]3[C@H](O[C@@H]4OC[C@@H](OC(=O)\C=C\C5=CC=C(O)C=C5)[C@H](O)[C@H]4O)C=C(CO)[C@@H]23)[C@H](O)[C@@H](O)[C@@H]1O InChI=1S/C29H36O15/c30-10-14-9-17(16-7-8-39-27(21(14)16)44-29-26(38)24(36)22(34)18(11-31)43-29)42-28-25(37)23(35)19(12-40-28)41-20(33)6-3-13-1-4-15(32)5-2-13/h1-9,16-19,21-32,34-38H,10-12H2/b6-3+/t16-,17+,18+,19+,21+,22+,23-,24-,25+,26+,27-,28-,29-/m0/s1 |
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Synonyms | Not Available |
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Chemical Formula | C29H36O15 |
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Average Mass | 624.5920 Da |
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Monoisotopic Mass | 624.20542 Da |
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IUPAC Name | (3R,4R,5R,6S)-6-{[(1S,4aR,5S,7aS)-7-(hydroxymethyl)-1-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-1H,4aH,5H,7aH-cyclopenta[c]pyran-5-yl]oxy}-4,5-dihydroxyoxan-3-yl (2E)-3-(4-hydroxyphenyl)prop-2-enoate |
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Traditional Name | (3R,4R,5R,6S)-6-{[(1S,4aR,5S,7aS)-7-(hydroxymethyl)-1-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-1H,4aH,5H,7aH-cyclopenta[c]pyran-5-yl]oxy}-4,5-dihydroxyoxan-3-yl (2E)-3-(4-hydroxyphenyl)prop-2-enoate |
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CAS Registry Number | Not Available |
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SMILES | OC[C@H]1O[C@@H](O[C@@H]2OC=C[C@H]3[C@H](O[C@@H]4OC[C@@H](OC(=O)\C=C\C5=CC=C(O)C=C5)[C@H](O)[C@H]4O)C=C(CO)[C@@H]23)[C@H](O)[C@@H](O)[C@@H]1O |
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InChI Identifier | InChI=1S/C29H36O15/c30-10-14-9-17(16-7-8-39-27(21(14)16)44-29-26(38)24(36)22(34)18(11-31)43-29)42-28-25(37)23(35)19(12-40-28)41-20(33)6-3-13-1-4-15(32)5-2-13/h1-9,16-19,21-32,34-38H,10-12H2/b6-3+/t16-,17+,18+,19+,21+,22+,23-,24-,25+,26+,27-,28-,29-/m0/s1 |
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InChI Key | QMXKOUSEDUDBEY-LNYAFLLHSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Not Available | Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as iridoid o-glycosides. These are iridoid monoterpenes containing a glycosyl (usually a pyranosyl) moiety linked to the iridoid skeleton. |
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Kingdom | Organic compounds |
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Super Class | Lipids and lipid-like molecules |
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Class | Prenol lipids |
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Sub Class | Terpene glycosides |
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Direct Parent | Iridoid O-glycosides |
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Alternative Parents | |
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Substituents | - Iridoid o-glycoside
- Coumaric acid ester
- Cinnamic acid or derivatives
- Coumaric acid or derivatives
- Hydroxycinnamic acid or derivatives
- Cinnamic acid ester
- Glycosyl compound
- Iridoid-skeleton
- O-glycosyl compound
- Aromatic monoterpenoid
- Bicyclic monoterpenoid
- Monoterpenoid
- Styrene
- Phenol
- 1-hydroxy-2-unsubstituted benzenoid
- Fatty acid ester
- Fatty acyl
- Benzenoid
- Oxane
- Monocyclic benzene moiety
- Monosaccharide
- Alpha,beta-unsaturated carboxylic ester
- Enoate ester
- Secondary alcohol
- Carboxylic acid ester
- Oxacycle
- Organoheterocyclic compound
- Polyol
- Carboxylic acid derivative
- Monocarboxylic acid or derivatives
- Acetal
- Primary alcohol
- Carbonyl group
- Organooxygen compound
- Alcohol
- Organic oxygen compound
- Organic oxide
- Hydrocarbon derivative
- Aromatic heteropolycyclic compound
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Molecular Framework | Aromatic heteropolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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