NP-MRD: Showing NP-Card for (1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate (NP0184159)

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Record Information

Version

2.0

Created at

2022-09-03 23:13:21 UTC

Updated at

2022-09-03 23:13:21 UTC

NP-MRD ID

NP0184159

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate

Description

(1S,2R,4R,5S,6S,8S,10R,11S,12S,14R,15R,16S,19R,20S,21R)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]Henicosan-16-yl (2R)-2-methylbutanoate belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17. (1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate is found in Melia azedarach. Based on a literature review very few articles have been published on (1S,2R,4R,5S,6S,8S,10R,11S,12S,14R,15R,16S,19R,20S,21R)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]Henicosan-16-yl (2R)-2-methylbutanoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042201132D          

 54 60  0  0  1  0            999 V2000
    5.2662    5.1198    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3098    4.2959    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6181    3.8463    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8828    4.2205    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6616    3.0224    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3969    2.6482    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.9699    2.5728    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0135    1.7489    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.0825    1.5337    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.9940    0.6156    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3495   -0.1288    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.1273   -0.4039    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.1708   -1.2277    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.9061   -1.6019    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5978   -1.1523    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9497   -2.4258    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8718   -0.0484    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.4851   -0.6001    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.2696   -0.3448    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    6.8830   -0.8966    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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    5.9706    0.7730    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.3448    1.5082    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8952    2.1999    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.1687    1.5518    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7913    1.4739    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.3430    2.0873    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8700    0.8528    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.2981    1.2992    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4736    1.2695    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.0356    1.9686    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.0871    0.5406    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8866    1.3409    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5250   -0.1585    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    1.3140   -0.9171    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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    0.8761   -0.2179    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.4155   -0.9024    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0635   -0.0756    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.5294   -0.6493    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4137   -1.4661    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1548   -1.8286    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -1.3420   -0.5069    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0522    0.7413    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6889    1.1038    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.4891    1.3042    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2626    0.5109    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  6  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  8  7  1  1  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 11 10  1  1  0  0  0
 11 12  1  0  0  0  0
 12 13  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 14 16  2  0  0  0  0
 12 17  1  0  0  0  0
 17 18  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 19 21  2  0  0  0  0
 17 22  1  0  0  0  0
 22 23  1  1  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  2  0  0  0  0
 22 27  1  0  0  0  0
  8 27  1  0  0  0  0
 27 28  1  6  0  0  0
 27 29  1  0  0  0  0
 11 29  1  0  0  0  0
 29 30  1  1  0  0  0
 30 31  1  0  0  0  0
 31 32  1  1  0  0  0
 31 33  1  0  0  0  0
 33 34  1  1  0  0  0
 33 35  1  0  0  0  0
 11 35  1  0  0  0  0
 35 36  1  1  0  0  0
 36 37  2  0  0  0  0
 36 38  1  0  0  0  0
 38 39  1  6  0  0  0
 39 40  1  0  0  0  0
 40 41  1  0  0  0  0
 40 42  2  0  0  0  0
 38 43  1  0  0  0  0
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 43 45  1  0  0  0  0
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 49 50  1  0  0  0  0
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 52 53  1  6  0  0  0
 54 53  1  6  0  0  0
 52 54  1  0  0  0  0
 43 54  1  0  0  0  0
 33 54  1  0  0  0  0
M  END

     RDKit          3D

104110  0  0  0  0  0  0  0  0999 V2000
    7.8056    4.4211   -0.8098 C   0  0  0  0  0  0  0  0  0  0  0  0
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    2.4721    0.1756    0.9541 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1188    0.1332    1.1016 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.3094   -0.3284   -0.0593 C   0  0  2  0  0  0  0  0  0  0  0  0
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   -1.6321   -3.2909    0.2511 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -3.4429    0.5379    2.5166 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.3408   -2.7801    2.3149 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7992   -3.7853    2.4365 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.3589   -3.0720    0.8651 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0811    2.9678    1.0203 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7983    2.6452    2.2107 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.4454    3.3613    0.5525 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.0026   -0.2972   -0.4637 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.8536    1.6051    2.7486 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.4611    1.3367    3.1742 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.7317    0.0880   -0.7739 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.9449    1.1714   -1.9411 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.5885    2.6680   -0.9096 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7274    2.0751   -2.8088 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  3  4  1  0
  3  5  1  0
  5  6  2  0
  5  7  1  0
  7  8  1  0
  8  9  1  0
  9 10  1  0
 11 10  1  1
 11 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  0
 14 16  2  0
 12 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  1  0
 19 21  2  0
 17 22  1  0
 22 23  1  0
 23 24  1  0
 24 25  1  0
 24 26  2  0
 22 27  1  0
 27 28  1  6
 27 29  1  0
 29 30  1  0
 30 31  1  0
 31 32  1  0
 31 33  1  0
 33 34  1  1
 33 35  1  0
 35 36  1  0
 36 37  2  0
 36 38  1  0
 38 39  1  0
 39 40  1  0
 40 41  1  0
 40 42  2  0
 38 43  1  0
 43 44  1  1
 43 45  1  0
 45 51  1  0
 51 52  1  0
 52 53  1  0
 54 53  1  6
 45 46  1  0
 46 50  2  0
 50 49  1  0
 49 48  1  0
 48 47  2  0
 27  8  1  0
 54 33  1  0
 47 46  1  0
 29 11  1  0
 54 43  1  0
 35 11  1  0
 54 52  1  0
  1 55  1  0
  1 56  1  0
  1 57  1  0
  2 58  1  0
  2 59  1  0
  3 60  1  6
  4 61  1  0
  4 62  1  0
  4 63  1  0
  8 64  1  6
 10 65  1  0
 10 66  1  0
 12 67  1  1
 15 68  1  0
 15 69  1  0
 15 70  1  0
 17 71  1  6
 20 72  1  0
 20 73  1  0
 20 74  1  0
 22 75  1  6
 25 76  1  0
 25 77  1  0
 25 78  1  0
 28 79  1  0
 28 80  1  0
 28 81  1  0
 29 82  1  6
 30 83  1  0
 30 84  1  0
 31 85  1  6
 32 86  1  0
 34 87  1  0
 34 88  1  0
 34 89  1  0
 35 90  1  6
 38 91  1  1
 41 92  1  0
 41 93  1  0
 41 94  1  0
 44 95  1  0
 44 96  1  0
 44 97  1  0
 45 98  1  6
 51102  1  0
 51103  1  0
 52104  1  6
 50101  1  0
 48100  1  0
 47 99  1  0
M  END


  Mrv1652309042201132D          

 54 60  0  0  1  0            999 V2000
    5.2662    5.1198    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3098    4.2959    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6181    3.8463    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8828    4.2205    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6616    3.0224    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.3969    2.6482    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.9699    2.5728    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0135    1.7489    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.0825    1.5337    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.9940    0.6156    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3495   -0.1288    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.1273   -0.4039    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.1708   -1.2277    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.9061   -1.6019    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5978   -1.1523    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9497   -2.4258    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8718   -0.0484    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.4851   -0.6001    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.2696   -0.3448    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.4408    0.4622    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.8830   -0.8966    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.1468    0.7294    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.9706    0.7730    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.3448    1.5082    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8952    2.1999    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.1687    1.5518    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7913    1.4739    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    5.3430    2.0873    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8700    0.8528    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.2981    1.2992    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4736    1.2695    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.0356    1.9686    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.0871    0.5406    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.8866    1.3409    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5250   -0.1585    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.1385   -0.8874    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5764   -1.5866    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.3140   -0.9171    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.9275   -1.6459    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.3655   -2.3451    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1899   -2.3154    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9789   -3.0740    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8761   -0.2179    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.4155   -0.9024    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0635   -0.0756    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.5294   -0.6493    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4137   -1.4661    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1548   -1.8286    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7285   -1.2358    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3420   -0.5069    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0522    0.7413    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6889    1.1038    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.4891    1.3042    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.2626    0.5109    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  6  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  8  7  1  1  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 11 10  1  1  0  0  0
 11 12  1  0  0  0  0
 12 13  1  6  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 14 16  2  0  0  0  0
 12 17  1  0  0  0  0
 17 18  1  1  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 19 21  2  0  0  0  0
 17 22  1  0  0  0  0
 22 23  1  1  0  0  0
 23 24  1  0  0  0  0
 24 25  1  0  0  0  0
 24 26  2  0  0  0  0
 22 27  1  0  0  0  0
  8 27  1  0  0  0  0
 27 28  1  6  0  0  0
 27 29  1  0  0  0  0
 11 29  1  0  0  0  0
 29 30  1  1  0  0  0
 30 31  1  0  0  0  0
 31 32  1  1  0  0  0
 31 33  1  0  0  0  0
 33 34  1  1  0  0  0
 33 35  1  0  0  0  0
 11 35  1  0  0  0  0
 35 36  1  1  0  0  0
 36 37  2  0  0  0  0
 36 38  1  0  0  0  0
 38 39  1  6  0  0  0
 39 40  1  0  0  0  0
 40 41  1  0  0  0  0
 40 42  2  0  0  0  0
 38 43  1  0  0  0  0
 43 44  1  1  0  0  0
 43 45  1  0  0  0  0
 45 46  1  1  0  0  0
 46 47  1  0  0  0  0
 47 48  2  0  0  0  0
 48 49  1  0  0  0  0
 49 50  1  0  0  0  0
 46 50  2  0  0  0  0
 45 51  1  0  0  0  0
 51 52  1  0  0  0  0
 52 53  1  6  0  0  0
 54 53  1  6  0  0  0
 52 54  1  0  0  0  0
 43 54  1  0  0  0  0
 33 54  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0184159

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC[C@@H](C)C(=O)O[C@@H]1OC[C@]23[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H](OC(C)=O)[C@@]1(C)[C@@H]2C[C@H](O)[C@]1(C)[C@@H]3C(=O)[C@H](OC(C)=O)[C@]2(C)[C@H](C[C@@H]3O[C@]123)C1=COC=C1

> <INCHI_IDENTIFIER>
InChI=1S/C39H50O15/c1-10-17(2)33(46)53-34-35(7)24-14-25(44)37(9)29(38(24,16-48-34)32(52-21(6)43)28(49-18(3)40)31(35)51-20(5)42)27(45)30(50-19(4)41)36(8)23(22-11-12-47-15-22)13-26-39(36,37)54-26/h11-12,15,17,23-26,28-32,34,44H,10,13-14,16H2,1-9H3/t17-,23-,24+,25+,26+,28-,29+,30+,31+,32+,34+,35-,36+,37-,38+,39+/m1/s1

> <INCHI_KEY>
WLVLABKXPHNVTI-RVFLAERRSA-N

> <FORMULA>
C39H50O15

> <MOLECULAR_WEIGHT>
758.814

> <EXACT_MASS>
758.31497091

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
104

> <JCHEM_AVERAGE_POLARIZABILITY>
76.85737522840321

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1S,2R,4R,5S,6S,8S,10R,11S,12S,14R,15R,16S,19R,20S,21R)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0^{1,14}.0^{2,11}.0^{5,10}.0^{8,10}]henicosan-16-yl (2R)-2-methylbutanoate

> <JCHEM_LOGP>
2.3886002783333327

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
7

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.898274787404066

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.538898274714498

> <JCHEM_PKA_STRONGEST_BASIC>
-2.8444173104324646

> <JCHEM_POLAR_SURFACE_AREA>
203.69999999999996

> <JCHEM_REFRACTIVITY>
179.5621

> <JCHEM_ROTATABLE_BOND_COUNT>
13

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2R,4R,5S,6S,8S,10R,11S,12S,14R,15R,16S,19R,20S,21R)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0^{1,14}.0^{2,11}.0^{5,10}.0^{8,10}]henicosan-16-yl (2R)-2-methylbutanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0       9.830   9.557   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       9.912   8.019   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       8.620   7.180   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       7.248   7.878   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       8.702   5.642   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      10.074   4.943   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0       7.411   4.803   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       7.492   3.265   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       5.754   2.863   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       5.589   1.149   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       6.252  -0.241   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       7.704  -0.754   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       7.786  -2.292   0.000  0.00  0.00           O+0
HETATM   14  C   UNK     0       9.158  -2.990   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      10.449  -2.151   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       9.239  -4.528   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       9.094  -0.090   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0      10.239  -1.120   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0      11.703  -0.644   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      12.023   0.863   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      12.848  -1.674   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0       9.607   1.362   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0      11.145   1.443   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      11.844   2.815   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      11.004   4.107   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0      13.382   2.897   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       8.944   2.751   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       9.974   3.896   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       7.224   1.592   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       6.156   2.425   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       4.617   2.370   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       3.800   3.675   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       3.896   1.009   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       3.522   2.503   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       4.713  -0.296   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       3.992  -1.656   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0       4.809  -2.962   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0       2.453  -1.712   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0       1.731  -3.072   0.000  0.00  0.00           O+0
HETATM   40  C   UNK     0       2.549  -4.378   0.000  0.00  0.00           C+0
HETATM   41  C   UNK     0       4.088  -4.322   0.000  0.00  0.00           C+0
HETATM   42  O   UNK     0       1.827  -5.738   0.000  0.00  0.00           O+0
HETATM   43  C   UNK     0       1.635  -0.407   0.000  0.00  0.00           C+0
HETATM   44  C   UNK     0       0.776  -1.684   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0       0.118  -0.141   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0      -0.988  -1.212   0.000  0.00  0.00           C+0
HETATM   47  C   UNK     0      -0.772  -2.737   0.000  0.00  0.00           C+0
HETATM   48  C   UNK     0      -2.156  -3.413   0.000  0.00  0.00           C+0
HETATM   49  O   UNK     0      -3.227  -2.307   0.000  0.00  0.00           O+0
HETATM   50  C   UNK     0      -2.505  -0.946   0.000  0.00  0.00           C+0
HETATM   51  C   UNK     0      -0.098   1.384   0.000  0.00  0.00           C+0
HETATM   52  C   UNK     0       1.286   2.060   0.000  0.00  0.00           C+0
HETATM   53  O   UNK     0       2.780   2.435   0.000  0.00  0.00           O+0
HETATM   54  C   UNK     0       2.357   0.954   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9   27                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12   29   35                                             
CONECT   12   11   13   17                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14                                                            
CONECT   17   12   18   22                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20   21                                                  
CONECT   20   19                                                            
CONECT   21   19                                                            
CONECT   22   17   23   27                                                  
CONECT   23   22   24                                                       
CONECT   24   23   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24                                                            
CONECT   27   22    8   28   29                                             
CONECT   28   27                                                            
CONECT   29   27   11   30                                                  
CONECT   30   29   31                                                       
CONECT   31   30   32   33                                                  
CONECT   32   31                                                            
CONECT   33   31   34   35   54                                             
CONECT   34   33                                                            
CONECT   35   33   11   36                                                  
CONECT   36   35   37   38                                                  
CONECT   37   36                                                            
CONECT   38   36   39   43                                                  
CONECT   39   38   40                                                       
CONECT   40   39   41   42                                                  
CONECT   41   40                                                            
CONECT   42   40                                                            
CONECT   43   38   44   45   54                                             
CONECT   44   43                                                            
CONECT   45   43   46   51                                                  
CONECT   46   45   47   50                                                  
CONECT   47   46   48                                                       
CONECT   48   47   49                                                       
CONECT   49   48   50                                                       
CONECT   50   49   46                                                       
CONECT   51   45   52                                                       
CONECT   52   51   53   54                                                  
CONECT   53   52   54                                                       
CONECT   54   53   52   43   33                                             
MASTER        0    0    0    0    0    0    0    0   54    0  120    0
END

View in JSmol

Synonyms

Value	Source
(1S,2R,4R,5S,6S,8S,10R,11S,12S,14R,15R,16S,19R,20S,21R)-4,19,20,21-Tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0,.0,.0,.0,]henicosan-16-yl (2R)-2-methylbutanoic acid	Generator

Chemical Formula

C₃₉H₅₀O₁₅

Average Mass

758.8140 Da

Monoisotopic Mass

758.31497 Da

IUPAC Name

Traditional Name

CAS Registry Number

Not Available

SMILES

CC[C@@H](C)C(=O)O[C@@H]1OC[C@]23[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H](OC(C)=O)[C@@]1(C)[C@@H]2C[C@H](O)[C@]1(C)[C@@H]3C(=O)[C@H](OC(C)=O)[C@]2(C)[C@H](C[C@@H]3O[C@]123)C1=COC=C1

InChI Identifier

InChI=1S/C39H50O15/c1-10-17(2)33(46)53-34-35(7)24-14-25(44)37(9)29(38(24,16-48-34)32(52-21(6)43)28(49-18(3)40)31(35)51-20(5)42)27(45)30(50-19(4)41)36(8)23(22-11-12-47-15-22)13-26-39(36,37)54-26/h11-12,15,17,23-26,28-32,34,44H,10,13-14,16H2,1-9H3/t17-,23-,24+,25+,26+,28-,29+,30+,31+,32+,34+,35-,36+,37-,38+,39+/m1/s1

InChI Key

WLVLABKXPHNVTI-RVFLAERRSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Melia azedarach	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as limonoids. These are highly oxygenated, modified terpenoids with a prototypical structure either containing or derived from a precursor with a 4,4,8-trimethyl-17-furanylsteroid skeleton. All naturally occurring citrus limonoids contain a furan ring attached to the D-ring, at C-17, as well as oxygen containing functional groups at C-3, C-4, C-7, C-16 and C-17.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Limonoids

Alternative Parents

Substituents

Limonoid skeleton
17-furanylsteroid skeleton
Steroid ester
Pentacarboxylic acid or derivatives
Naphthopyran
Naphthalene
Alpha-acyloxy ketone
Fatty acid ester
Fatty acyl
Oxane
Pyran
Cyclic alcohol
Furan
Heteroaromatic compound
Secondary alcohol
Carboxylic acid ester
Ketone
Carboxylic acid derivative
Organoheterocyclic compound
Dialkyl ether
Oxirane
Ether
Oxacycle
Acetal
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Alcohol
Organic oxygen compound
Organic oxide
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.39	ChemAxon
pKa (Strongest Acidic)	12.54	ChemAxon
pKa (Strongest Basic)	-2.8	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	203.7 Å²	ChemAxon
Rotatable Bond Count	13	ChemAxon
Refractivity	179.56 m³·mol⁻¹	ChemAxon
Polarizability	76.86 Å³	ChemAxon
Number of Rings	7	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

163083011

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate (NP0184159)

MOL for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

3D MOL for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

3D SDF for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

3D-SDF for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

PDB for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

3D PDB for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

SMILES for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

INCHI for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

Structure for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)

3D Structure for NP0184159 ((1s,2r,4r,5s,6r,8s,10r,11s,12s,14r,15r,16s,19r,20s,21r)-4,19,20,21-tetrakis(acetyloxy)-6-(furan-3-yl)-12-hydroxy-5,11,15-trimethyl-3-oxo-9,17-dioxahexacyclo[13.3.3.0¹,¹⁴.0²,¹¹.0⁵,¹⁰.0⁸,¹⁰]henicosan-16-yl (2r)-2-methylbutanoate)