NP-MRD: Showing NP-Card for (1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate (NP0184001)

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Record Information

Version

2.0

Created at

2022-09-03 23:01:20 UTC

Updated at

2022-09-03 23:01:20 UTC

NP-MRD ID

NP0184001

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate

Description

(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]Hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units. (1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate is found in Euphorbia antiquorum. Based on a literature review very few articles have been published on (1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]Hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042201012D          

 35 38  0  0  1  0            999 V2000
    6.1649    3.7400    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    4.2733    2.1439    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.6428    1.6119    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652309042201012D          

 35 38  0  0  1  0            999 V2000
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  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  3  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  8  7  1  6  0  0  0
  8  9  1  0  0  0  0
  9 10  1  6  0  0  0
 10 11  1  0  0  0  0
 11 12  1  1  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 13 15  2  0  0  0  0
 11 16  1  0  0  0  0
 16 17  1  1  0  0  0
 16 18  1  0  0  0  0
 18 19  2  0  0  0  0
 18 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  6  0  0  0
 22 24  1  0  0  0  0
 24 25  1  6  0  0  0
 24 26  1  0  0  0  0
 20 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
 28 29  1  0  0  0  0
 28 30  1  0  0  0  0
  8 30  1  0  0  0  0
 30 31  1  1  0  0  0
 26 32  1  6  0  0  0
 20 32  1  6  0  0  0
 10 33  1  6  0  0  0
  9 33  1  0  0  0  0
 33 34  1  0  0  0  0
 33 35  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0184001

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C\C=C(/C)C(=O)O[C@@H]1[C@H]2[C@@H]([C@@H](OC(C)=O)[C@@H](C)C(=O)[C@@]34C[C@H](C)[C@H](O)[C@@]3(O4)\C=C(C)/[C@H]1O)C2(C)C

> <INCHI_IDENTIFIER>
InChI=1S/C27H38O8/c1-9-12(2)24(32)34-21-18-17(25(18,7)8)20(33-16(6)28)15(5)23(31)27-11-14(4)22(30)26(27,35-27)10-13(3)19(21)29/h9-10,14-15,17-22,29-30H,11H2,1-8H3/b12-9+,13-10-/t14-,15+,17-,18+,19+,20-,21+,22-,26-,27-/m0/s1

> <INCHI_KEY>
LXAAZEDGZDPXIG-WSTYWUMHSA-N

> <FORMULA>
C27H38O8

> <MOLECULAR_WEIGHT>
490.593

> <EXACT_MASS>
490.256668184

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
73

> <JCHEM_AVERAGE_POLARIZABILITY>
52.34217533376601

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0^{1,12}.0^{5,7}]hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate

> <JCHEM_LOGP>
3.1735211889999984

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.896671044528432

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.294240147691841

> <JCHEM_PKA_STRONGEST_BASIC>
-3.4030066982752594

> <JCHEM_POLAR_SURFACE_AREA>
122.66000000000001

> <JCHEM_REFRACTIVITY>
127.18199999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
1

> <JCHEM_TRADITIONAL_IUPAC>
(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0^{1,12}.0^{5,7}]hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0      11.508   6.981   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      10.331   5.988   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      10.602   4.472   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      12.051   3.950   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       9.425   3.479   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0       9.697   1.963   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0       7.977   4.002   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0       6.800   3.009   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       7.421   1.600   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       7.182   0.078   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       6.158  -1.072   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0       6.974  -2.379   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0       8.513  -2.325   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       9.237  -0.966   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0       9.329  -3.632   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0       4.675  -1.487   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       4.655  -3.027   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       3.203  -1.033   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       2.354  -2.318   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       2.210   0.144   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       0.820  -0.518   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -0.239   0.601   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -1.766   0.401   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       0.497   1.953   0.000  0.00  0.00           C+0
HETATM   25  O   UNK     0      -0.164   3.344   0.000  0.00  0.00           O+0
HETATM   26  C   UNK     0       2.011   1.671   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.669   3.063   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       3.976   3.878   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       3.561   5.362   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       5.515   3.858   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0       5.969   5.330   0.000  0.00  0.00           O+0
HETATM   32  O   UNK     0       3.433   1.080   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       8.619   0.632   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       9.728  -0.437   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      10.003   1.309   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4    5                                                  
CONECT    4    3                                                            
CONECT    5    3    6    7                                                  
CONECT    6    5                                                            
CONECT    7    5    8                                                       
CONECT    8    7    9   30                                                  
CONECT    9    8   10   33                                                  
CONECT   10    9   11   33                                                  
CONECT   11   10   12   16                                                  
CONECT   12   11   13                                                       
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13                                                            
CONECT   16   11   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19   20                                                  
CONECT   19   18                                                            
CONECT   20   18   21   26   32                                             
CONECT   21   20   22                                                       
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25   26                                                  
CONECT   25   24                                                            
CONECT   26   24   20   27   32                                             
CONECT   27   26   28                                                       
CONECT   28   27   29   30                                                  
CONECT   29   28                                                            
CONECT   30   28    8   31                                                  
CONECT   31   30                                                            
CONECT   32   26   20                                                       
CONECT   33   10    9   34   35                                             
CONECT   34   33                                                            
CONECT   35   33                                                            
MASTER        0    0    0    0    0    0    0    0   35    0   76    0
END

View in JSmol

Synonyms

Value	Source
(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(Acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0,.0,]hexadec-10-en-8-yl (2E)-2-methylbut-2-enoic acid	Generator

Chemical Formula

C₂₇H₃₈O₈

Average Mass

490.5930 Da

Monoisotopic Mass

490.25667 Da

IUPAC Name

(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0^{1,12}.0^{5,7}]hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate

Traditional Name

(1R,3R,4R,5R,7S,8R,9R,10Z,12S,13S,14S)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0^{1,12}.0^{5,7}]hexadec-10-en-8-yl (2E)-2-methylbut-2-enoate

CAS Registry Number

Not Available

SMILES

C\C=C(/C)C(=O)O[C@@H]1[C@H]2[C@@H]([C@@H](OC(C)=O)[C@@H](C)C(=O)[C@@]34C[C@H](C)[C@H](O)[C@@]3(O4)\C=C(C)/[C@H]1O)C2(C)C

InChI Identifier

InChI=1S/C27H38O8/c1-9-12(2)24(32)34-21-18-17(25(18,7)8)20(33-16(6)28)15(5)23(31)27-11-14(4)22(30)26(27,35-27)10-13(3)19(21)29/h9-10,14-15,17-22,29-30H,11H2,1-8H3/b12-9+,13-10-/t14-,15+,17-,18+,19+,20-,21+,22-,26-,27-/m0/s1

InChI Key

LXAAZEDGZDPXIG-WSTYWUMHSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Euphorbia antiquorum	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as diterpenoids. These are terpene compounds formed by four isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Diterpenoids

Direct Parent

Diterpenoids

Alternative Parents

Substituents

Ingol
Diterpenoid
Lathyrane diterpenoid
Fatty acid ester
Dicarboxylic acid or derivatives
Fatty acyl
Oxane
Cyclic alcohol
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Ketone
Carboxylic acid ester
Secondary alcohol
Organoheterocyclic compound
Ether
Oxirane
Oxacycle
Dialkyl ether
Carboxylic acid derivative
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Organic oxygen compound
Alcohol
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	3.17	ChemAxon
pKa (Strongest Acidic)	13.29	ChemAxon
pKa (Strongest Basic)	-3.4	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	122.66 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	127.18 m³·mol⁻¹	ChemAxon
Polarizability	52.34 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

10270624

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

21636314

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate (NP0184001)

MOL for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

3D MOL for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

3D SDF for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

3D-SDF for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

PDB for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

3D PDB for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

SMILES for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

INCHI for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

Structure for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)

3D Structure for NP0184001 ((1r,3r,4r,5r,7s,8r,9r,10z,12s,13s,14s)-4-(acetyloxy)-9,13-dihydroxy-3,6,6,10,14-pentamethyl-2-oxo-16-oxatetracyclo[10.3.1.0¹,¹².0⁵,⁷]hexadec-10-en-8-yl (2e)-2-methylbut-2-enoate)