NP-MRD: Showing NP-Card for 15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one (NP0183883)

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Record Information

Version

2.0

Created at

2022-09-03 22:52:25 UTC

Updated at

2022-09-03 22:52:25 UTC

NP-MRD ID

NP0183883

Secondary Accession Numbers

None

Natural Product Identification

Common Name

15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one

Description

15-(5,6-Dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]Octadeca-2(11),4-dien-3-one belongs to the class of organic compounds known as oxanes. Oxanes are compounds containing an oxane (tetrahydropyran) ring, which is a six-member saturated aliphatic heterocycle with one oxygen atom and five carbon atoms. 15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one is found in Pleurotus eryngii. Based on a literature review very few articles have been published on 15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]Octadeca-2(11),4-dien-3-one.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309042200522D          

 32 35  0  0  0  0            999 V2000
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M  END

     RDKit          3D

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M  END


  Mrv1652309042200522D          

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 30 31  1  0  0  0  0
 25 31  1  0  0  0  0
 20 31  1  0  0  0  0
 31 32  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0183883

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)C(C)C=CC(C)C1CCC2(O)OC1(C)CCC1=C2C(=O)C=C2CC(O)CCC12C

> <INCHI_IDENTIFIER>
InChI=1S/C28H42O4/c1-17(2)18(3)7-8-19(4)22-11-14-28(31)25-23(10-13-27(22,6)32-28)26(5)12-9-21(29)15-20(26)16-24(25)30/h7-8,16-19,21-22,29,31H,9-15H2,1-6H3

> <INCHI_KEY>
MMDBFASABGRZQE-UHFFFAOYSA-N

> <FORMULA>
C28H42O4

> <MOLECULAR_WEIGHT>
442.64

> <EXACT_MASS>
442.308309832

> <JCHEM_ACCEPTOR_COUNT>
4

> <JCHEM_ATOM_COUNT>
74

> <JCHEM_AVERAGE_POLARIZABILITY>
52.24906946771205

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0^{2,11}.0^{5,10}]octadeca-2(11),4-dien-3-one

> <JCHEM_LOGP>
5.244307738333333

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
17.082728030362944

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.2722858267043

> <JCHEM_PKA_STRONGEST_BASIC>
-1.3387449263785984

> <JCHEM_POLAR_SURFACE_AREA>
66.76

> <JCHEM_REFRACTIVITY>
130.7807

> <JCHEM_ROTATABLE_BOND_COUNT>
4

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0^{2,11}.0^{5,10}]octadeca-2(11),4-dien-3-one

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 04-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   04-SEP-22         0                                  
HETATM    1  C   UNK     0      21.104   3.472   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      19.792   2.666   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      19.833   1.127   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      18.438   3.400   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      18.396   4.940   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      17.125   2.594   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      15.771   3.328   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0      14.459   2.522   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0      14.501   0.983   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      13.105   3.256   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      13.331   4.779   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0      12.526   6.092   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0      11.065   6.579   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0      11.023   8.119   0.000  0.00  0.00           O+0
HETATM   15  O   UNK     0      12.052   4.518   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0      11.953   2.235   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      12.518   0.802   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      10.413   2.193   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0       9.207   3.151   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0       8.899   4.660   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       9.633   6.014   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       8.827   7.326   0.000  0.00  0.00           C+0
HETATM   23  O   UNK     0       9.561   8.680   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0       7.287   7.285   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       6.554   5.931   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       5.014   5.889   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       4.281   4.535   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0       2.741   4.493   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       5.086   3.223   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       6.626   3.264   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       7.359   4.618   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0       8.165   3.306   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5    6                                                  
CONECT    5    4                                                            
CONECT    6    4    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   10                                                  
CONECT    9    8                                                            
CONECT   10    8   11   16                                                  
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14   15   21                                             
CONECT   14   13                                                            
CONECT   15   13   16                                                       
CONECT   16   15   10   17   18                                             
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   21   31                                                  
CONECT   21   20   13   22                                                  
CONECT   22   21   23   24                                                  
CONECT   23   22                                                            
CONECT   24   22   25                                                       
CONECT   25   24   26   31                                                  
CONECT   26   25   27                                                       
CONECT   27   26   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30                                                       
CONECT   30   29   31                                                       
CONECT   31   30   25   20   32                                             
CONECT   32   31                                                            
MASTER        0    0    0    0    0    0    0    0   32    0   70    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₂₈H₄₂O₄

Average Mass

442.6400 Da

Monoisotopic Mass

442.30831 Da

IUPAC Name

15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0^{2,11}.0^{5,10}]octadeca-2(11),4-dien-3-one

Traditional Name

15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0^{2,11}.0^{5,10}]octadeca-2(11),4-dien-3-one

CAS Registry Number

Not Available

SMILES

CC(C)C(C)C=CC(C)C1CCC2(O)OC1(C)CCC1=C2C(=O)C=C2CC(O)CCC12C

InChI Identifier

InChI=1S/C28H42O4/c1-17(2)18(3)7-8-19(4)22-11-14-28(31)25-23(10-13-27(22,6)32-28)26(5)12-9-21(29)15-20(26)16-24(25)30/h7-8,16-19,21-22,29,31H,9-15H2,1-6H3

InChI Key

MMDBFASABGRZQE-UHFFFAOYSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Pleurotus eryngii	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as oxanes. Oxanes are compounds containing an oxane (tetrahydropyran) ring, which is a six-member saturated aliphatic heterocycle with one oxygen atom and five carbon atoms.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Oxanes

Sub Class

Not Available

Direct Parent

Oxanes

Alternative Parents

Substituents

Oxane
Cyclic alcohol
Secondary alcohol
Ketone
Hemiacetal
Oxacycle
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.24	ChemAxon
pKa (Strongest Acidic)	11.27	ChemAxon
pKa (Strongest Basic)	-1.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	4	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	66.76 Å²	ChemAxon
Rotatable Bond Count	4	ChemAxon
Refractivity	130.78 m³·mol⁻¹	ChemAxon
Polarizability	52.25 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

163091053

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for 15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one (NP0183883)

MOL for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

3D MOL for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

3D SDF for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

3D-SDF for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

PDB for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

3D PDB for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

SMILES for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

INCHI for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

Structure for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)

3D Structure for NP0183883 (15-(5,6-dimethylhept-3-en-2-yl)-1,7-dihydroxy-10,14-dimethyl-18-oxatetracyclo[12.3.1.0²,¹¹.0⁵,¹⁰]octadeca-2(11),4-dien-3-one)