Record Information |
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Version | 1.0 |
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Created at | 2022-09-03 21:24:04 UTC |
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Updated at | 2022-09-03 21:24:05 UTC |
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NP-MRD ID | NP0182653 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | {4-[(acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate |
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Description | {4-[(Acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate belongs to the class of organic compounds known as 9,9'-epoxylignans. These are lignans with a structure based on the 9,9'-epoxylignan skeleton, which consists of a tetrahydrofuran that carries two benzyl groups at the 3- and 4-positions. Additionally they are oxygenated at the 2-position to form dibenzylbutyrolactones (oxo group) or a dibenzylbutyrolactols (hydroxyl group). {4-[(acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate is found in Pleione bulbocodioides. {4-[(Acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate is an extremely weak basic (essentially neutral) compound (based on its pKa). |
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Structure | COC1=CC(=CC=C1O)C(OC(C)=O)C1COCC1C(OC(C)=O)C1=CC=C(O)C(OC)=C1 InChI=1S/C24H28O9/c1-13(25)32-23(15-5-7-19(27)21(9-15)29-3)17-11-31-12-18(17)24(33-14(2)26)16-6-8-20(28)22(10-16)30-4/h5-10,17-18,23-24,27-28H,11-12H2,1-4H3 |
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Synonyms | Value | Source |
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{4-[(acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetic acid | Generator |
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Chemical Formula | C24H28O9 |
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Average Mass | 460.4790 Da |
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Monoisotopic Mass | 460.17333 Da |
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IUPAC Name | {4-[(acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate |
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Traditional Name | {4-[(acetyloxy)(4-hydroxy-3-methoxyphenyl)methyl]oxolan-3-yl}(4-hydroxy-3-methoxyphenyl)methyl acetate |
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CAS Registry Number | Not Available |
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SMILES | COC1=CC(=CC=C1O)C(OC(C)=O)C1COCC1C(OC(C)=O)C1=CC=C(O)C(OC)=C1 |
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InChI Identifier | InChI=1S/C24H28O9/c1-13(25)32-23(15-5-7-19(27)21(9-15)29-3)17-11-31-12-18(17)24(33-14(2)26)16-6-8-20(28)22(10-16)30-4/h5-10,17-18,23-24,27-28H,11-12H2,1-4H3 |
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InChI Key | XTVMVCMAKJEEEJ-UHFFFAOYSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Spectrum Type | Description | Depositor ID | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 25 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 252 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 50 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 75 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 101 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 126 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 151 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 176 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 201 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 226 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, H2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as 9,9'-epoxylignans. These are lignans with a structure based on the 9,9'-epoxylignan skeleton, which consists of a tetrahydrofuran that carries two benzyl groups at the 3- and 4-positions. Additionally they are oxygenated at the 2-position to form dibenzylbutyrolactones (oxo group) or a dibenzylbutyrolactols (hydroxyl group). |
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Kingdom | Organic compounds |
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Super Class | Lignans, neolignans and related compounds |
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Class | Furanoid lignans |
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Sub Class | Tetrahydrofuran lignans |
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Direct Parent | 9,9'-epoxylignans |
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Alternative Parents | |
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Substituents | - 9,9p-epoxylignan
- Benzyloxycarbonyl
- Methoxyphenol
- Anisole
- Phenoxy compound
- Phenol ether
- Methoxybenzene
- Alkyl aryl ether
- 1-hydroxy-2-unsubstituted benzenoid
- Phenol
- Monocyclic benzene moiety
- Dicarboxylic acid or derivatives
- Benzenoid
- Tetrahydrofuran
- Carboxylic acid ester
- Oxacycle
- Ether
- Dialkyl ether
- Carboxylic acid derivative
- Organoheterocyclic compound
- Organooxygen compound
- Hydrocarbon derivative
- Carbonyl group
- Organic oxide
- Organic oxygen compound
- Aromatic heteromonocyclic compound
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Molecular Framework | Aromatic heteromonocyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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