NP-MRD: Showing NP-Card for methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate (NP0163564)

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Record Information

Version

2.0

Created at

2022-09-02 22:14:52 UTC

Updated at

2022-09-02 22:14:52 UTC

NP-MRD ID

NP0163564

Secondary Accession Numbers

None

Natural Product Identification

Common Name

methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate

Description

Methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0²,⁷.0¹¹,¹⁵]Heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units. Based on a literature review very few articles have been published on methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0²,⁷.0¹¹,¹⁵]Heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309032200142D          

 36 39  0  0  1  0            999 V2000
    1.4500   -3.3202    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0375   -4.0347    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2125   -4.0347    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2000   -3.3202    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0250   -3.3202    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.4375   -4.0347    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2625   -4.0347    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0250   -4.7491    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4375   -5.4636    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4375   -2.6057    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.1020   -1.8520    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.2950   -1.6805    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7151   -1.3000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4295   -1.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.5158   -0.8920    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2142   -1.4576    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8273   -2.0096    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -2.8711   -3.0715    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2580   -2.5195    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.0031   -3.3041    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6119   -1.7547    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.4404   -2.5616    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2250   -2.3067    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0096   -2.0518    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -6.9657   -0.9899    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.5680   -0.6928    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.2181   -0.1848    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1807    0.0357    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7834   -0.9477    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.1703   -0.3957    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3857   -0.6506    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4500   -4.7491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2750   -4.7491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0375   -5.4636    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
 10  5  1  6  0  0  0
 10 11  1  0  0  0  0
 11 12  1  6  0  0  0
 11 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  1  0  0  0
 14 16  1  0  0  0  0
 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 10 20  1  0  0  0  0
 14 20  1  0  0  0  0
 20 21  1  6  0  0  0
 17 22  1  0  0  0  0
 22 23  1  6  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  1  0  0  0
 26 28  1  0  0  0  0
 28 29  1  0  0  0  0
 28 30  1  0  0  0  0
 28 31  1  0  0  0  0
 22 31  1  0  0  0  0
 31 32  1  6  0  0  0
 32 33  1  0  0  0  0
 16 33  1  0  0  0  0
  2 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  1  0  0  0  0
M  END

     RDKit          3D

 88 91  0  0  0  0  0  0  0  0999 V2000
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    2.1714    0.5296    0.6528 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.9896    0.4246    2.1843 C   0  0  1  0  0  0  0  0  0  0  0  0
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    0.5165    0.6743    2.4048 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0351    0.0540    1.1840 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.1920   -1.4426    1.2613 C   0  0  0  0  0  0  0  0  0  0  0  0
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   -1.8565    0.0683   -0.3226 C   0  0  0  0  0  0  0  0  0  0  0  0
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    4.1521   -2.8982   -0.5785 C   0  0  0  0  0  0  0  0  0  0  0  0
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    4.6131    0.2511   -2.5440 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.2618   -0.4955   -1.5588 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.8933    1.9717   -0.8764 H   0  0  0  0  0  0  0  0  0  0  0  0
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    3.5126    5.1275    2.0450 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.3136    5.2236    1.6233 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5761   -0.4868    0.3517 H   0  0  0  0  0  0  0  0  0  0  0  0
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  9  8  1  0
  8  6  1  0
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  6  5  1  0
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  2  1  2  3
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 33 81  1  0
M  END


  Mrv1652309032200142D          

 36 39  0  0  1  0            999 V2000
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   -3.8273   -2.0096    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.6557   -2.8166    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8711   -3.0715    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2580   -2.5195    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.0031   -3.3041    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6119   -1.7547    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.4404   -2.5616    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2250   -2.3067    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0096   -2.0518    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1811   -1.2448    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -6.9657   -0.9899    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.5680   -0.6928    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.2181   -0.1848    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1807    0.0357    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7834   -0.9477    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.1703   -0.3957    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3857   -0.6506    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4500   -4.7491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2750   -4.7491    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0375   -5.4636    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  5  4  1  1  0  0  0
  5  6  1  0  0  0  0
  6  7  2  0  0  0  0
  6  8  1  0  0  0  0
  8  9  1  0  0  0  0
 10  5  1  6  0  0  0
 10 11  1  0  0  0  0
 11 12  1  6  0  0  0
 11 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  1  0  0  0
 14 16  1  0  0  0  0
 16 17  2  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 10 20  1  0  0  0  0
 14 20  1  0  0  0  0
 20 21  1  6  0  0  0
 17 22  1  0  0  0  0
 22 23  1  6  0  0  0
 22 24  1  0  0  0  0
 24 25  1  0  0  0  0
 25 26  1  0  0  0  0
 26 27  1  1  0  0  0
 26 28  1  0  0  0  0
 28 29  1  0  0  0  0
 28 30  1  0  0  0  0
 28 31  1  0  0  0  0
 22 31  1  0  0  0  0
 31 32  1  6  0  0  0
 32 33  1  0  0  0  0
 16 33  1  0  0  0  0
  2 34  1  0  0  0  0
 34 35  1  0  0  0  0
 34 36  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0163564

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)[C@H](CCC(=C)C(C)C)[C@H]1[C@@H](O)C[C@@]2(C)C3=C(CC[C@]12C)[C@@]1(C)CC[C@@H](O)C(C)(C)[C@@H]1CC3

> <INCHI_IDENTIFIER>
InChI=1S/C32H52O4/c1-19(2)20(3)10-11-21(28(35)36-9)27-24(33)18-32(8)23-12-13-25-29(4,5)26(34)15-16-30(25,6)22(23)14-17-31(27,32)7/h19,21,24-27,33-34H,3,10-18H2,1-2,4-9H3/t21-,24+,25+,26-,27+,30-,31-,32+/m1/s1

> <INCHI_KEY>
RYYBRBMMLMLDEO-RGORDXKMSA-N

> <FORMULA>
C32H52O4

> <MOLECULAR_WEIGHT>
500.764

> <EXACT_MASS>
500.386560154

> <JCHEM_ACCEPTOR_COUNT>
3

> <JCHEM_ATOM_COUNT>
88

> <JCHEM_AVERAGE_POLARIZABILITY>
60.31886796735286

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate

> <ALOGPS_LOGP>
5.99

> <JCHEM_LOGP>
5.824479963666668

> <ALOGPS_LOGS>
-5.25

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
19.55378682596286

> <JCHEM_PKA_STRONGEST_ACIDIC>
14.873376208548969

> <JCHEM_PKA_STRONGEST_BASIC>
-0.8069734038560002

> <JCHEM_POLAR_SURFACE_AREA>
66.76

> <JCHEM_REFRACTIVITY>
146.07370000000006

> <JCHEM_ROTATABLE_BOND_COUNT>
7

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
2.80e-03 g/l

> <JCHEM_TRADITIONAL_IUPAC>
methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 03-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   03-SEP-22         0                                  
HETATM    1  C   UNK     0       2.707  -6.198   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       1.937  -7.531   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       0.397  -7.531   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -0.373  -6.198   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -1.913  -6.198   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -2.683  -7.531   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      -4.223  -7.531   0.000  0.00  0.00           O+0
HETATM    8  O   UNK     0      -1.913  -8.865   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0      -2.683 -10.199   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0      -2.683  -4.864   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0      -2.057  -3.457   0.000  0.00  0.00           C+0
HETATM   12  O   UNK     0      -0.551  -3.137   0.000  0.00  0.00           O+0
HETATM   13  C   UNK     0      -3.201  -2.427   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      -4.535  -3.197   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      -4.696  -1.665   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      -6.000  -2.721   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      -7.144  -3.751   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      -6.824  -5.258   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -5.359  -5.733   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -4.215  -4.703   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -3.739  -6.168   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      -8.609  -3.275   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -8.289  -4.782   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -9.753  -4.306   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0     -11.218  -3.830   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0     -11.538  -2.324   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0     -13.003  -1.848   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0     -10.394  -1.293   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0     -11.607  -0.345   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      -9.671   0.067   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -8.929  -1.769   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -7.785  -0.739   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -6.320  -1.214   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0       2.707  -8.865   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       4.247  -8.865   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       1.937 -10.199   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3   34                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6   10                                                  
CONECT    6    5    7    8                                                  
CONECT    7    6                                                            
CONECT    8    6    9                                                       
CONECT    9    8                                                            
CONECT   10    5   11   20                                                  
CONECT   11   10   12   13                                                  
CONECT   12   11                                                            
CONECT   13   11   14                                                       
CONECT   14   13   15   16   20                                             
CONECT   15   14                                                            
CONECT   16   14   17   33                                                  
CONECT   17   16   18   22                                                  
CONECT   18   17   19                                                       
CONECT   19   18   20                                                       
CONECT   20   19   10   14   21                                             
CONECT   21   20                                                            
CONECT   22   17   23   24   31                                             
CONECT   23   22                                                            
CONECT   24   22   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27   28                                                  
CONECT   27   26                                                            
CONECT   28   26   29   30   31                                             
CONECT   29   28                                                            
CONECT   30   28                                                            
CONECT   31   28   22   32                                                  
CONECT   32   31   33                                                       
CONECT   33   32   16                                                       
CONECT   34    2   35   36                                                  
CONECT   35   34                                                            
CONECT   36   34                                                            
MASTER        0    0    0    0    0    0    0    0   36    0   78    0
END

View in JSmol

Synonyms

Value	Source
Methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0,.0,]heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoic acid	Generator

Chemical Formula

C₃₂H₅₂O₄

Average Mass

500.7640 Da

Monoisotopic Mass

500.38656 Da

IUPAC Name

methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate

Traditional Name

methyl (2R)-2-[(2S,5R,7R,11R,13S,14R,15R)-5,13-dihydroxy-2,6,6,11,15-pentamethyltetracyclo[8.7.0.0^{2,7}.0^{11,15}]heptadec-1(10)-en-14-yl]-6-methyl-5-methylideneheptanoate

CAS Registry Number

Not Available

SMILES

COC(=O)[C@H](CCC(=C)C(C)C)[C@H]1[C@@H](O)C[C@@]2(C)C3=C(CC[C@]12C)[C@@]1(C)CC[C@@H](O)C(C)(C)[C@@H]1CC3

InChI Identifier

InChI=1S/C32H52O4/c1-19(2)20(3)10-11-21(28(35)36-9)27-24(33)18-32(8)23-12-13-25-29(4,5)26(34)15-16-30(25,6)22(23)14-17-31(27,32)7/h19,21,24-27,33-34H,3,10-18H2,1-2,4-9H3/t21-,24+,25+,26-,27+,30-,31-,32+/m1/s1

InChI Key

RYYBRBMMLMLDEO-RGORDXKMSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as triterpenoids. These are terpene molecules containing six isoprene units.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Triterpenoids

Direct Parent

Triterpenoids

Alternative Parents

Substituents

Triterpenoid
Dihydroxy bile acid, alcohol, or derivatives
Hydroxy bile acid, alcohol, or derivatives
Bile acid, alcohol, or derivatives
3-hydroxysteroid
14-alpha-methylsteroid
3-alpha-hydroxysteroid
16-hydroxysteroid
16-beta-hydroxysteroid
Hydroxysteroid
Steroid
Cyclic alcohol
Methyl ester
Carboxylic acid ester
Secondary alcohol
Carboxylic acid derivative
Monocarboxylic acid or derivatives
Alcohol
Hydrocarbon derivative
Organic oxygen compound
Carbonyl group
Organic oxide
Organooxygen compound
Aliphatic homopolycyclic compound

Molecular Framework

Aliphatic homopolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.99	ALOGPS
logP	5.82	ChemAxon
logS	-5.2	ALOGPS
pKa (Strongest Acidic)	14.87	ChemAxon
pKa (Strongest Basic)	-0.81	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	3	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	66.76 Å²	ChemAxon
Rotatable Bond Count	7	ChemAxon
Refractivity	146.07 m³·mol⁻¹	ChemAxon
Polarizability	60.32 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162849936

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate (NP0163564)

MOL for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

3D MOL for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

3D SDF for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

3D-SDF for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

PDB for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

3D PDB for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

SMILES for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

INCHI for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

Structure for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)

3D Structure for NP0163564 (methyl (2r)-2-[(1r,2s,3ar,5ar,7r,9as,11ar)-2,7-dihydroxy-3a,6,6,9a,11a-pentamethyl-1h,2h,3h,4h,5h,5ah,7h,8h,9h,10h,11h-cyclopenta[a]phenanthren-1-yl]-6-methyl-5-methylideneheptanoate)