NP-MRD: Showing NP-Card for (1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol (NP0157807)

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Record Information

Version

2.0

Created at

2022-09-02 15:17:10 UTC

Updated at

2022-09-02 15:17:10 UTC

NP-MRD ID

NP0157807

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol

Description

9Alpha,11alpha-epoxycholest-7-en-3beta,5alpha,6beta-triol, also known as 9α,11α-epoxycholest-7-en-3β,5α,6β-triol, belongs to the class of organic compounds known as cholesterols and derivatives. Cholesterols and derivatives are compounds containing a 3-hydroxylated cholestane core. Thus, 9alpha,11alpha-epoxycholest-7-en-3beta,5alpha,6beta-triol is considered to be a sterol. (1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol is found in Planaxis sulcatus. Based on a literature review very few articles have been published on 9alpha,11alpha-epoxycholest-7-en-3beta,5alpha,6beta-triol.

Structure

MOL 3D MOL SDF PDB SMILES InChI

  Mrv1652309022217172D          

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M  END

     RDKit          3D

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M  END

  Mrv1652309022217172D          

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 13 26  1  0  0  0  0
 26 27  1  6  0  0  0
 28 27  1  6  0  0  0
 26 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 12 30  1  0  0  0  0
  9 30  1  0  0  0  0
 30 31  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0157807

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2C3=C[C@@H](O)[C@@]4(O)C[C@@H](O)CC[C@]4(C)[C@]33O[C@@H]3C[C@]12C

> <INCHI_IDENTIFIER>
InChI=1S/C27H44O4/c1-16(2)7-6-8-17(3)19-9-10-20-21-13-22(29)26(30)14-18(28)11-12-25(26,5)27(21)23(31-27)15-24(19,20)4/h13,16-20,22-23,28-30H,6-12,14-15H2,1-5H3/t17-,18+,19-,20+,22-,23-,24-,25+,26+,27+/m1/s1

> <INCHI_KEY>
HJWIFUYWCCWKOA-QGRYAOFKSA-N

> <FORMULA>
C27H44O4

> <MOLECULAR_WEIGHT>
432.645

> <EXACT_MASS>
432.323959897

> <JCHEM_ACCEPTOR_COUNT>
4

> <JCHEM_ATOM_COUNT>
75

> <JCHEM_AVERAGE_POLARIZABILITY>
51.90776697617855

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
3

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(1R,2S,5S,7R,8R,11R,14R,15R,17R)-2,15-dimethyl-14-[(2R)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0^{1,17}.0^{2,7}.0^{11,15}]octadec-9-ene-5,7,8-triol

> <ALOGPS_LOGP>
4.22

> <JCHEM_LOGP>
4.0452067729999985

> <ALOGPS_LOGS>
-4.58

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.447583762935878

> <JCHEM_PKA_STRONGEST_ACIDIC>
13.063630254826919

> <JCHEM_PKA_STRONGEST_BASIC>
-2.7284295601408077

> <JCHEM_POLAR_SURFACE_AREA>
73.22

> <JCHEM_REFRACTIVITY>
122.53399999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
1.14e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(1R,2S,5S,7R,8R,11R,14R,15R,17R)-2,15-dimethyl-14-[(2R)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0^{1,17}.0^{2,7}.0^{11,15}]octadec-9-ene-5,7,8-triol

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 02-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   02-SEP-22         0                                  
HETATM    1  C   UNK     0      -5.686  -5.353   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -4.160  -5.563   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -3.580  -6.990   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -3.215  -4.347   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -1.690  -4.558   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -0.744  -3.342   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.781  -3.553   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       1.362  -4.979   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       1.726  -2.337   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       1.298  -0.858   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       2.573   0.006   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       3.789  -0.939   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       5.305  -0.668   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       5.828   0.781   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0       7.344   1.052   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       7.867   2.500   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0       8.337  -0.126   0.000  0.00  0.00           C+0
HETATM   18  O   UNK     0       8.860   1.323   0.000  0.00  0.00           O+0
HETATM   19  C   UNK     0       9.853   0.146   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      10.845  -1.032   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0      12.361  -0.761   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0      10.322  -2.480   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       8.806  -2.751   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       7.813  -1.574   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       8.241  -3.053   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       6.297  -1.845   0.000  0.00  0.00           C+0
HETATM   27  O   UNK     0       7.290  -3.022   0.000  0.00  0.00           O+0
HETATM   28  C   UNK     0       5.774  -3.293   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.258  -3.564   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       3.266  -2.387   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       2.594  -3.773   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3    4                                                  
CONECT    3    2                                                            
CONECT    4    2    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7   10   30                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13   30                                                  
CONECT   13   12   14   26                                                  
CONECT   14   13   15                                                       
CONECT   15   14   16   17                                                  
CONECT   16   15                                                            
CONECT   17   15   18   19   24                                             
CONECT   18   17                                                            
CONECT   19   17   20                                                       
CONECT   20   19   21   22                                                  
CONECT   21   20                                                            
CONECT   22   20   23                                                       
CONECT   23   22   24                                                       
CONECT   24   23   17   25   26                                             
CONECT   25   24                                                            
CONECT   26   24   13   27   28                                             
CONECT   27   26   28                                                       
CONECT   28   27   26   29                                                  
CONECT   29   28   30                                                       
CONECT   30   29   12    9   31                                             
CONECT   31   30                                                            
MASTER        0    0    0    0    0    0    0    0   31    0   70    0
END

View in JSmol

Synonyms

Value	Source
9a,11a-Epoxycholest-7-en-3b,5a,6b-triol	Generator
9Α,11α-epoxycholest-7-en-3β,5α,6β-triol	Generator

Chemical Formula

C₂₇H₄₄O₄

Average Mass

432.6450 Da

Monoisotopic Mass

432.32396 Da

IUPAC Name

Not Available

Traditional Name

Not Available

CAS Registry Number

Not Available

SMILES

CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2C3=C[C@@H](O)[C@@]4(O)C[C@@H](O)CC[C@]4(C)[C@]33O[C@@H]3C[C@]12C

InChI Identifier

InChI=1S/C27H44O4/c1-16(2)7-6-8-17(3)19-9-10-20-21-13-22(29)26(30)14-18(28)11-12-25(26,5)27(21)23(31-27)15-24(19,20)4/h13,16-20,22-23,28-30H,6-12,14-15H2,1-5H3/t17-,18+,19-,20+,22-,23-,24-,25+,26+,27+/m1/s1

InChI Key

HJWIFUYWCCWKOA-QGRYAOFKSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Planaxis sulcatus	LOTUS Database	35616633

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as cholesterols and derivatives. Cholesterols and derivatives are compounds containing a 3-hydroxylated cholestane core.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Steroids and steroid derivatives

Sub Class

Cholestane steroids

Direct Parent

Cholesterols and derivatives

Alternative Parents

Substituents

Cholesterol
Oxepane
Cyclic alcohol
Tertiary alcohol
Secondary alcohol
Dialkyl ether
Oxirane
Ether
Oxacycle
Polyol
Organoheterocyclic compound
Organic oxygen compound
Organooxygen compound
Hydrocarbon derivative
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Cholesterol and derivatives (LMST01010318 )

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

9502894

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

11327943

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol (NP0157807)

MOL for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

3D MOL for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

3D SDF for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

3D-SDF for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

PDB for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

3D PDB for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

SMILES for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

INCHI for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

Structure for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)

3D Structure for NP0157807 ((1r,2s,5s,7r,8r,11r,14r,15r,17r)-2,15-dimethyl-14-[(2r)-6-methylheptan-2-yl]-18-oxapentacyclo[8.8.0.0¹,¹⁷.0²,⁷.0¹¹,¹⁵]octadec-9-ene-5,7,8-triol)