NP-MRD: Showing NP-Card for (6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione (NP0144091)

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Record Information

Version

2.0

Created at

2022-09-01 22:58:23 UTC

Updated at

2022-09-01 22:58:23 UTC

NP-MRD ID

NP0144091

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione

Description

97877-69-5 Belongs to the class of organic compounds known as azaspirodecane derivatives. These are organic compounds containing a spirodecane moiety with at least one nitrogen atom. Based on a literature review very few articles have been published on 97877-69-5.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309022200582D          

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M  END

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M  END


  Mrv1652309022200582D          

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    1.9416   -6.9770    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8374   -5.9049    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.1277   -5.1327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.3644   -5.7048    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.6560   -6.1276    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.8325   -4.0149    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  3  4  1  0  0  0  0
  4  5  2  0  0  0  0
  6  4  1  6  0  0  0
  6  7  1  0  0  0  0
  7  8  1  1  0  0  0
  2  8  1  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
 15 16  1  0  0  0  0
 16 17  1  6  0  0  0
 16 18  1  0  0  0  0
 18 19  1  0  0  0  0
 12 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 11 22  1  0  0  0  0
 22 23  1  6  0  0  0
 22 24  1  0  0  0  0
 24 25  1  6  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
 27 29  1  0  0  0  0
 24 29  1  0  0  0  0
 30 24  1  1  0  0  0
  9 30  1  0  0  0  0
 30 31  1  0  0  0  0
 31 32  1  1  0  0  0
 31 33  1  0  0  0  0
 33 34  1  0  0  0  0
  9 34  1  0  0  0  0
 31 35  1  0  0  0  0
  6 35  1  0  0  0  0
 35 36  1  6  0  0  0
 19 37  1  0  0  0  0
 14 37  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0144091

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@H]1C[C@H]2CN3C4=CC56CO[C@@](O)([C@@H]5[C@@]5(COC(=O)C5)[C@]4(C)CCC3(C1)O2)[C@H](C)[C@H]1[C@H]6CC(C)=CC1=O

> <INCHI_IDENTIFIER>
InChI=1S/C30H39NO6/c1-16-8-20-24(21(32)9-16)18(3)30(34)25-27(20,14-36-30)11-22-26(4,28(25)12-23(33)35-15-28)5-6-29-10-17(2)7-19(37-29)13-31(22)29/h9,11,17-20,24-25,34H,5-8,10,12-15H2,1-4H3/t17-,18+,19-,20+,24-,25-,26+,27?,28+,29?,30+/m0/s1

> <INCHI_KEY>
ACDRDEOVULSAPQ-NUMHYOOVSA-N

> <FORMULA>
C30H39NO6

> <MOLECULAR_WEIGHT>
509.643

> <EXACT_MASS>
509.27773798

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
76

> <JCHEM_AVERAGE_POLARIZABILITY>
54.410806556163955

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
1

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(6S,8S,13S,14R,15S,16R,17R,18R,23R)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1^{6,10}.0^{1,15}.0^{3,13}.0^{4,10}.0^{18,23}]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione

> <ALOGPS_LOGP>
2.76

> <JCHEM_LOGP>
2.6833554070000005

> <ALOGPS_LOGS>
-3.79

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
8

> <JCHEM_PHYSIOLOGICAL_CHARGE>
1

> <JCHEM_PKA>
17.668210259557444

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.596703940389833

> <JCHEM_PKA_STRONGEST_BASIC>
7.714793008803112

> <JCHEM_POLAR_SURFACE_AREA>
85.30000000000001

> <JCHEM_REFRACTIVITY>
137.72680000000003

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
8.18e-02 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(6S,8S,13S,14R,15S,16R,17R,18R,23R)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1^{6,10}.0^{1,15}.0^{3,13}.0^{4,10}.0^{18,23}]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 02-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   02-SEP-22         0                                  
HETATM    1  C   UNK     0       1.316  -4.626   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       1.681  -6.123   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0       0.567  -7.186   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0       0.931  -8.683   0.000  0.00  0.00           C+0
HETATM    5  O   UNK     0      -0.182  -9.746   0.000  0.00  0.00           O+0
HETATM    6  C   UNK     0       2.409  -9.115   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       3.523  -8.051   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       3.159  -6.555   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       5.049  -8.259   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       6.462  -7.646   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       7.699  -8.563   0.000  0.00  0.00           C+0
HETATM   12  N   UNK     0       9.121  -7.960   0.000  0.00  0.00           N+0
HETATM   13  C   UNK     0       9.401  -6.361   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0      11.014  -6.135   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0      12.633  -6.377   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0      13.283  -7.845   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0      14.803  -8.094   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      12.189  -9.036   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      10.517  -8.826   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      10.193 -10.415   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       8.755 -11.038   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       7.523 -10.093   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       7.816 -11.605   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0       6.110 -10.706   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0       7.244 -11.747   0.000  0.00  0.00           C+0
HETATM   26  O   UNK     0       6.604 -13.148   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       5.074 -12.972   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0       4.033 -14.107   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0       4.769 -11.463   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0       4.845 -10.030   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0       3.832 -11.498   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       3.624 -13.024   0.000  0.00  0.00           O+0
HETATM   33  O   UNK     0       5.297 -11.023   0.000  0.00  0.00           O+0
HETATM   34  C   UNK     0       5.838  -9.581   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0       2.547 -10.649   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0       1.224 -11.438   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0      10.887  -7.495   0.000  0.00  0.00           O+0
CONECT    1    2                                                            
CONECT    2    1    3    8                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    6                                                  
CONECT    5    4                                                            
CONECT    6    4    7   35                                                  
CONECT    7    6    8    9                                                  
CONECT    8    7    2                                                       
CONECT    9    7   10   30   34                                             
CONECT   10    9   11                                                       
CONECT   11   10   12   22                                                  
CONECT   12   11   13   19                                                  
CONECT   13   12   14                                                       
CONECT   14   13   15   37                                                  
CONECT   15   14   16                                                       
CONECT   16   15   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16   19                                                       
CONECT   19   18   12   20   37                                             
CONECT   20   19   21                                                       
CONECT   21   20   22                                                       
CONECT   22   21   11   23   24                                             
CONECT   23   22                                                            
CONECT   24   22   25   29   30                                             
CONECT   25   24   26                                                       
CONECT   26   25   27                                                       
CONECT   27   26   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   24                                                       
CONECT   30   24    9   31                                                  
CONECT   31   30   32   33   35                                             
CONECT   32   31                                                            
CONECT   33   31   34                                                       
CONECT   34   33    9                                                       
CONECT   35   31    6   36                                                  
CONECT   36   35                                                            
CONECT   37   19   14                                                       
MASTER        0    0    0    0    0    0    0    0   37    0   88    0
END

View in JSmol

Synonyms

Not Available

Chemical Formula

C₃₀H₃₉NO₆

Average Mass

509.6430 Da

Monoisotopic Mass

509.27774 Da

IUPAC Name

(6S,8S,13S,14R,15S,16R,17R,18R,23R)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1^{6,10}.0^{1,15}.0^{3,13}.0^{4,10}.0^{18,23}]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione

Traditional Name

CAS Registry Number

Not Available

SMILES

C[C@H]1C[C@H]2CN3C4=CC56CO[C@@](O)([C@@H]5[C@@]5(COC(=O)C5)[C@]4(C)CCC3(C1)O2)[C@H](C)[C@H]1[C@H]6CC(C)=CC1=O

InChI Identifier

InChI=1S/C30H39NO6/c1-16-8-20-24(21(32)9-16)18(3)30(34)25-27(20,14-36-30)11-22-26(4,28(25)12-23(33)35-15-28)5-6-29-10-17(2)7-19(37-29)13-31(22)29/h9,11,17-20,24-25,34H,5-8,10,12-15H2,1-4H3/t17-,18+,19-,20+,24-,25-,26+,27?,28+,29?,30+/m0/s1

InChI Key

ACDRDEOVULSAPQ-NUMHYOOVSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as azaspirodecane derivatives. These are organic compounds containing a spirodecane moiety with at least one nitrogen atom.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Azaspirodecane derivatives

Sub Class

Not Available

Direct Parent

Azaspirodecane derivatives

Alternative Parents

Substituents

Azaspirodecane
Cyclohexenone
Oxepane
Azepane
Piperidine
Oxane
Gamma butyrolactone
Tetrahydrofuran
Oxazolidine
Cyclic alcohol
Lactone
Ketone
Hemiacetal
Carboxylic acid ester
Oxacycle
Azacycle
Monocarboxylic acid or derivatives
Enamine
Carboxylic acid derivative
Organic nitrogen compound
Organic oxygen compound
Organopnictogen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Organonitrogen compound
Carbonyl group
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.76	ALOGPS
logP	2.68	ChemAxon
logS	-3.8	ALOGPS
pKa (Strongest Acidic)	11.6	ChemAxon
pKa (Strongest Basic)	7.71	ChemAxon
Physiological Charge	1	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	1	ChemAxon
Polar Surface Area	85.3 Å²	ChemAxon
Rotatable Bond Count	0	ChemAxon
Refractivity	137.73 m³·mol⁻¹	ChemAxon
Polarizability	54.41 Å³	ChemAxon
Number of Rings	8	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

95600530

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

178996

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione (NP0144091)

MOL for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

3D MOL for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

3D SDF for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

3D-SDF for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

PDB for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

3D PDB for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

SMILES for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

INCHI for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

Structure for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)

3D Structure for NP0144091 ((6s,8s,13s,14r,15s,16r,17r,18r,23r)-16-hydroxy-8,13,17,21-tetramethyl-25,26-dioxa-4-azaspiro[heptacyclo[14.7.2.1⁶,¹⁰.0¹,¹⁵.0³,¹³.0⁴,¹⁰.0¹⁸,²³]hexacosane-14,3'-oxolane]-2,20-diene-5',19-dione)