NP-MRD: Showing NP-Card for LacCer(d18:1/24:1(15Z)) (NP0136229)

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Record Information

Version

2.0

Created at

2022-05-12 15:09:07 UTC

Updated at

2022-05-12 15:09:07 UTC

NP-MRD ID

NP0136229

Secondary Accession Numbers

None

Natural Product Identification

Common Name

LacCer(d18:1/24:1(15Z))

Description

LacCer(d18:1/24:1(15Z)), also known as laccer or lactosylceramide, belongs to the class of organic compounds known as glycosyl-n-acylsphingosines. Glycosyl-N-acylsphingosines are compounds containing a sphingosine linked to a simple glucosyl moiety. LacCer(d18:1/24:1(15Z)) was first documented in 2002 (PMID: 12417418). LacCer(d18:1/24:1(15Z)) is an extremely weak basic (essentially neutral) compound (based on its pKa) (PMID: 12566244) (PMID: 12486134) (PMID: 12070301).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652304062012582D          

 68 69  0  0  1  0            999 V2000
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  2  1  1  0  0  0  0
  3  1  1  0  0  0  0
  4  2  1  0  0  0  0
  5  3  1  0  0  0  0
  6  4  1  0  0  0  0
  6  5  1  0  0  0  0
  8  7  1  0  0  0  0
  9  7  1  0  0  0  0
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  8 17  1  6  0  0  0
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M  END

     RDKit          3D

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M  END


  Mrv1652304062012582D          

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 26 25  1  0  0  0  0
 27 26  1  0  0  0  0
 28 27  2  0  0  0  0
 29 28  1  0  0  0  0
 30 29  1  0  0  0  0
 31 30  1  0  0  0  0
 32 31  1  0  0  0  0
 33 32  1  0  0  0  0
 34 33  1  0  0  0  0
 35 34  1  0  0  0  0
 36 35  1  0  0  0  0
 37 36  1  0  0  0  0
 38 37  1  0  0  0  0
 39 38  1  0  0  0  0
 40 39  1  0  0  0  0
 26 41  1  1  0  0  0
 25 42  1  6  0  0  0
 44 43  2  0  0  0  0
 42 43  1  0  0  0  0
 45 43  1  0  0  0  0
 46 45  1  0  0  0  0
 47 46  1  0  0  0  0
 48 47  1  0  0  0  0
 49 48  1  0  0  0  0
 50 49  1  0  0  0  0
 51 50  1  0  0  0  0
 52 51  1  0  0  0  0
 53 52  1  0  0  0  0
 54 53  1  0  0  0  0
 55 54  1  0  0  0  0
 56 55  1  0  0  0  0
 58 57  1  0  0  0  0
 59 58  2  0  0  0  0
 60 59  1  0  0  0  0
 61 60  1  0  0  0  0
 62 61  1  0  0  0  0
 63 62  1  0  0  0  0
 64 63  1  0  0  0  0
 56 57  1  0  0  0  0
 65 40  1  0  0  0  0
 66 64  1  0  0  0  0
 67 66  1  0  0  0  0
 68 67  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0136229

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CCCCCCCCCCCCC\C=C\[C@@H](O)[C@H](CO[C@@H]1O[C@H](CO)[C@@H](O[C@@H]2O[C@H](CO)[C@H](O)[C@H](O)[C@H]2O)[C@H](O)C1O)NC(=O)CCCCCCCCCCCCC\C=C/CCCCCCCC

> <INCHI_IDENTIFIER>
InChI=1S/C54H101NO13/c1-3-5-7-9-11-13-15-17-18-19-20-21-22-23-24-26-28-30-32-34-36-38-46(59)55-42(43(58)37-35-33-31-29-27-25-16-14-12-10-8-6-4-2)41-65-53-51(64)49(62)52(45(40-57)67-53)68-54-50(63)48(61)47(60)44(39-56)66-54/h17-18,35,37,42-45,47-54,56-58,60-64H,3-16,19-34,36,38-41H2,1-2H3,(H,55,59)/b18-17-,37-35+/t42-,43+,44+,45+,47-,48-,49+,50+,51?,52+,53+,54-/m0/s1

> <INCHI_KEY>
MKOKWBRPIBQYJJ-LWQSSKHKSA-N

> <FORMULA>
C54H101NO13

> <MOLECULAR_WEIGHT>
972.3786

> <EXACT_MASS>
971.727292323

> <JCHEM_ACCEPTOR_COUNT>
13

> <JCHEM_ATOM_COUNT>
169

> <JCHEM_AVERAGE_POLARIZABILITY>
119.05134477500754

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
9

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(15Z)-N-[(2S,3R,4E)-1-{[(2R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxyoctadec-4-en-2-yl]tetracos-15-enamide

> <ALOGPS_LOGP>
7.41

> <JCHEM_LOGP>
10.518311515666667

> <ALOGPS_LOGS>
-5.63

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
2

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.442514639800741

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.920303071106915

> <JCHEM_PKA_STRONGEST_BASIC>
-2.9813779338405872

> <JCHEM_POLAR_SURFACE_AREA>
227.85999999999996

> <JCHEM_REFRACTIVITY>
268.5269

> <JCHEM_ROTATABLE_BOND_COUNT>
43

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
2.29e-03 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(15Z)-N-[(2S,3R,4E)-1-{[(2R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxyoctadec-4-en-2-yl]tetracos-15-enamide

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 06-APR-20   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   06-APR-20         0                                  
HETATM    1  C   UNK     0      12.132 -16.801   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      12.132 -18.341   0.000  0.00  0.00           C+0
HETATM    3  O   UNK     0      10.799 -16.031   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0      10.799 -19.111   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       9.465 -16.801   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       9.465 -18.341   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       6.586 -20.209   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       6.586 -21.749   0.000  0.00  0.00           C+0
HETATM    9  O   UNK     0       5.253 -19.439   0.000  0.00  0.00           O+0
HETATM   10  C   UNK     0       5.253 -22.519   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       3.919 -20.209   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       3.919 -21.749   0.000  0.00  0.00           C+0
HETATM   13  O   UNK     0       5.209 -23.848   0.000  0.00  0.00           O+0
HETATM   14  O   UNK     0       2.585 -22.519   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0       2.585 -19.439   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0       1.252 -20.209   0.000  0.00  0.00           O+0
HETATM   17  O   UNK     0       7.920 -22.519   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0       7.920 -19.439   0.000  0.00  0.00           O+0
HETATM   19  O   UNK     0      10.799 -20.280   0.000  0.00  0.00           O+0
HETATM   20  O   UNK     0      13.007 -16.235   0.000  0.00  0.00           O+0
HETATM   21  C   UNK     0       8.554 -15.994   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0       7.218 -16.625   0.000  0.00  0.00           O+0
HETATM   23  O   UNK     0      13.118 -18.833   0.000  0.00  0.00           O+0
HETATM   24  C   UNK     0      14.331 -17.021   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      15.674 -16.267   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      16.998 -17.052   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      18.341 -16.298   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0      19.666 -17.083   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0      21.008 -16.329   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0      22.333 -17.115   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      23.675 -16.361   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      25.000 -17.146   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      26.342 -16.392   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      27.667 -17.177   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0      29.010 -16.423   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0      30.334 -17.209   0.000  0.00  0.00           C+0
HETATM   37  C   UNK     0      31.677 -16.454   0.000  0.00  0.00           C+0
HETATM   38  C   UNK     0      33.001 -17.240   0.000  0.00  0.00           C+0
HETATM   39  C   UNK     0      34.344 -16.486   0.000  0.00  0.00           C+0
HETATM   40  C   UNK     0      35.669 -17.271   0.000  0.00  0.00           C+0
HETATM   41  O   UNK     0      16.980 -18.592   0.000  0.00  0.00           O+0
HETATM   42  N   UNK     0      15.692 -14.727   0.000  0.00  0.00           N+0
HETATM   43  C   UNK     0      17.035 -13.972   0.000  0.00  0.00           C+0
HETATM   44  O   UNK     0      17.053 -12.432   0.000  0.00  0.00           O+0
HETATM   45  C   UNK     0      18.359 -14.758   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0      19.702 -14.004   0.000  0.00  0.00           C+0
HETATM   47  C   UNK     0      21.026 -14.789   0.000  0.00  0.00           C+0
HETATM   48  C   UNK     0      22.369 -14.035   0.000  0.00  0.00           C+0
HETATM   49  C   UNK     0      23.694 -14.821   0.000  0.00  0.00           C+0
HETATM   50  C   UNK     0      25.036 -14.066   0.000  0.00  0.00           C+0
HETATM   51  C   UNK     0      26.361 -14.852   0.000  0.00  0.00           C+0
HETATM   52  C   UNK     0      27.703 -14.098   0.000  0.00  0.00           C+0
HETATM   53  C   UNK     0      29.028 -14.883   0.000  0.00  0.00           C+0
HETATM   54  C   UNK     0      30.370 -14.129   0.000  0.00  0.00           C+0
HETATM   55  C   UNK     0      31.695 -14.915   0.000  0.00  0.00           C+0
HETATM   56  C   UNK     0      33.038 -14.161   0.000  0.00  0.00           C+0
HETATM   57  C   UNK     0      34.362 -14.946   0.000  0.00  0.00           C+0
HETATM   58  C   UNK     0      35.705 -14.192   0.000  0.00  0.00           C+0
HETATM   59  C   UNK     0      37.030 -14.978   0.000  0.00  0.00           C+0
HETATM   60  C   UNK     0      37.067 -15.868   0.000  0.00  0.00           C+0
HETATM   61  C   UNK     0      38.411 -16.881   0.000  0.00  0.00           C+0
HETATM   62  C   UNK     0      38.223 -18.409   0.000  0.00  0.00           C+0
HETATM   63  C   UNK     0      39.453 -19.336   0.000  0.00  0.00           C+0
HETATM   64  C   UNK     0      39.265 -20.865   0.000  0.00  0.00           C+0
HETATM   65  C   UNK     0      37.011 -16.517   0.000  0.00  0.00           C+0
HETATM   66  C   UNK     0      40.495 -21.791   0.000  0.00  0.00           C+0
HETATM   67  C   UNK     0      40.307 -23.320   0.000  0.00  0.00           C+0
HETATM   68  C   UNK     0      41.536 -24.247   0.000  0.00  0.00           C+0
CONECT    1    2    3   20                                                  
CONECT    2    1    4   23                                                  
CONECT    3    1    5                                                       
CONECT    4    2    6   19                                                  
CONECT    5    3    6   21                                                  
CONECT    6    4    5   18                                                  
CONECT    7    8    9   18                                                  
CONECT    8    7   10   17                                                  
CONECT    9    7   11                                                       
CONECT   10    8   12   13                                                  
CONECT   11    9   12   15                                                  
CONECT   12   10   11   14                                                  
CONECT   13   10                                                            
CONECT   14   12                                                            
CONECT   15   11   16                                                       
CONECT   16   15                                                            
CONECT   17    8                                                            
CONECT   18    7    6                                                       
CONECT   19    4                                                            
CONECT   20    1   24                                                       
CONECT   21    5   22                                                       
CONECT   22   21                                                            
CONECT   23    2                                                            
CONECT   24   20   25                                                       
CONECT   25   24   26   42                                                  
CONECT   26   25   27   41                                                  
CONECT   27   26   28                                                       
CONECT   28   27   29                                                       
CONECT   29   28   30                                                       
CONECT   30   29   31                                                       
CONECT   31   30   32                                                       
CONECT   32   31   33                                                       
CONECT   33   32   34                                                       
CONECT   34   33   35                                                       
CONECT   35   34   36                                                       
CONECT   36   35   37                                                       
CONECT   37   36   38                                                       
CONECT   38   37   39                                                       
CONECT   39   38   40                                                       
CONECT   40   39   65                                                       
CONECT   41   26                                                            
CONECT   42   25   43                                                       
CONECT   43   44   42   45                                                  
CONECT   44   43                                                            
CONECT   45   43   46                                                       
CONECT   46   45   47                                                       
CONECT   47   46   48                                                       
CONECT   48   47   49                                                       
CONECT   49   48   50                                                       
CONECT   50   49   51                                                       
CONECT   51   50   52                                                       
CONECT   52   51   53                                                       
CONECT   53   52   54                                                       
CONECT   54   53   55                                                       
CONECT   55   54   56                                                       
CONECT   56   55   57                                                       
CONECT   57   58   56                                                       
CONECT   58   57   59                                                       
CONECT   59   58   60                                                       
CONECT   60   59   61                                                       
CONECT   61   60   62                                                       
CONECT   62   61   63                                                       
CONECT   63   62   64                                                       
CONECT   64   63   66                                                       
CONECT   65   40                                                            
CONECT   66   64   67                                                       
CONECT   67   66   68                                                       
CONECT   68   67                                                            
MASTER        0    0    0    0    0    0    0    0   68    0  138    0
END

View in JSmol

Synonyms

Value	Source
(15Z)-N-[(2S,3R,4E)-1-{[(2R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxyoctadec-4-en-2-yl]tetracos-15-enimidate	HMDB
1-O-(4-O-b-D-Galactopyranosyl-b-D-glucopyranosyl)-ceramide	HMDB
1-O-(4-O-beta-D-Galactopyranosyl-beta-glucopyranosyl)ceramide	HMDB
1-O-(4-O-beta-delta-Galactopyranosyl-beta-delta-glucopyranosyl)-ceramide	HMDB
1-O-(4-O-beta-delta-Galactopyranosyl-beta-glucopyranosyl)ceramide	HMDB
1Ylce-O-(4-O-beta-delta-galactopyranosyl-beta-glucopyranosyl)ceramide	HMDB
beta-D-Galactosyl-1,4-beta-D-glucosylceramide	HMDB
beta-delta-Galactosyl-1,4-beta-delta-glucosramide	HMDB
beta-delta-Galactosyl-1,4-beta-delta-glucosylceramide	HMDB
CDH	HMDB
CDW17 Antigen	HMDB
Cytolipin H	HMDB
D-Galactosyl-1,4-beta-D-glucosylceramide	HMDB
delta-Galactosyl-1,4-beta-delta-glucosylceramide	HMDB
Gal-beta1->4GLC-beta1->1'cer	HMDB
Gal-beta1->4GLC-beta1->1'cer(D18:1/24:1	HMDB
LacCer	HMDB
LacCer(D18:1/24:1)	HMDB
Lactosyl ceramide (D18:1/24:1(15Z))	HMDB
Lactosyl ceramide (D18:1/24:1)	HMDB
Lactosyl-N-acylsphingosine	HMDB
Lactosylceramide	HMDB
N-Lignoceryl sphingosyl lactoside	HMDB
N-(15Z-Tetracosenoyl)-1-β-lactosyl-sphing-4-enine	MetBuilder
Lactosylceramide(D18:1/24:1(15Z))	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-sphingosine	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-D-erythro-sphingosine	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-4-sphingenine	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-D-sphingosine	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-sphingenine	MetBuilder
N-(15Z-Tetracosenoyl)-1-β-lactosyl-erythro-4-sphingenine	MetBuilder

Chemical Formula

C₅₄H₁₀₁NO₁₃

Average Mass

972.3786 Da

Monoisotopic Mass

971.72729 Da

IUPAC Name

(15Z)-N-[(2S,3R,4E)-1-{[(2R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}oxan-2-yl]oxy}-3-hydroxyoctadec-4-en-2-yl]tetracos-15-enamide

Traditional Name

CAS Registry Number

Not Available

SMILES

CCCCCCCCCCCCC\C=C\[C@@H](O)[C@H](CO[C@@H]1O[C@H](CO)[C@@H](O[C@@H]2O[C@H](CO)[C@H](O)[C@H](O)[C@H]2O)[C@H](O)C1O)NC(=O)CCCCCCCCCCCCC\C=C/CCCCCCCC

InChI Identifier

InChI=1S/C54H101NO13/c1-3-5-7-9-11-13-15-17-18-19-20-21-22-23-24-26-28-30-32-34-36-38-46(59)55-42(43(58)37-35-33-31-29-27-25-16-14-12-10-8-6-4-2)41-65-53-51(64)49(62)52(45(40-57)67-53)68-54-50(63)48(61)47(60)44(39-56)66-54/h17-18,35,37,42-45,47-54,56-58,60-64H,3-16,19-34,36,38-41H2,1-2H3,(H,55,59)/b18-17-,37-35+/t42-,43+,44+,45+,47-,48-,49+,50+,51?,52+,53+,54-/m0/s1

InChI Key

MKOKWBRPIBQYJJ-LWQSSKHKSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as glycosyl-n-acylsphingosines. Glycosyl-N-acylsphingosines are compounds containing a sphingosine linked to a simple glucosyl moiety.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Sphingolipids

Sub Class

Glycosphingolipids

Direct Parent

Glycosyl-N-acylsphingosines

Alternative Parents

Substituents

Glycosyl-n-acylsphingosine
Fatty acyl glycoside
Fatty acyl glycoside of mono- or disaccharide
Alkyl glycoside
Disaccharide
Glycosyl compound
O-glycosyl compound
Fatty amide
N-acyl-amine
Oxane
Fatty acyl
Secondary carboxylic acid amide
Secondary alcohol
Carboxamide group
Organoheterocyclic compound
Polyol
Oxacycle
Carboxylic acid derivative
Acetal
Organic nitrogen compound
Hydrocarbon derivative
Organic oxide
Organopnictogen compound
Organic oxygen compound
Alcohol
Organonitrogen compound
Carbonyl group
Organooxygen compound
Primary alcohol
Aliphatic heteromonocyclic compound

Molecular Framework

Aliphatic heteromonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	7.41	ALOGPS
logP	10.52	ChemAxon
logS	-5.6	ALOGPS
pKa (Strongest Acidic)	11.92	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	13	ChemAxon
Hydrogen Donor Count	9	ChemAxon
Polar Surface Area	227.86 Å²	ChemAxon
Rotatable Bond Count	43	ChemAxon
Refractivity	268.53 m³·mol⁻¹	ChemAxon
Polarizability	119.05 Å³	ChemAxon
Number of Rings	2	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

HMDB0004872

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

FDB023466

KNApSAcK ID

Not Available

Chemspider ID

16744886

KEGG Compound ID

C01290

BioCyc ID

CYTOLIPIN_H

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

7129

PubChem Compound

20057309

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Moore RM, Silver RJ, Moore JJ: Physiological apoptotic agents have different effects upon human amnion epithelial and mesenchymal cells. Placenta. 2003 Feb-Mar;24(2-3):173-80. doi: 10.1053/plac.2002.0886. [PubMed:12566244 ]
Prinetti A, Basso L, Appierto V, Villani MG, Valsecchi M, Loberto N, Prioni S, Chigorno V, Cavadini E, Formelli F, Sonnino S: Altered sphingolipid metabolism in N-(4-hydroxyphenyl)-retinamide-resistant A2780 human ovarian carcinoma cells. J Biol Chem. 2003 Feb 21;278(8):5574-83. doi: 10.1074/jbc.M207269200. Epub 2002 Dec 16. [PubMed:12486134 ]
Furukawa K, Takamiya K, Furukawa K: Beta1,4-N-acetylgalactosaminyltransferase--GM2/GD2 synthase: a key enzyme to control the synthesis of brain-enriched complex gangliosides. Biochim Biophys Acta. 2002 Dec 19;1573(3):356-62. doi: 10.1016/s0304-4165(02)00403-8. [PubMed:12417418 ]
Choudhury A, Dominguez M, Puri V, Sharma DK, Narita K, Wheatley CL, Marks DL, Pagano RE: Rab proteins mediate Golgi transport of caveola-internalized glycosphingolipids and correct lipid trafficking in Niemann-Pick C cells. J Clin Invest. 2002 Jun;109(12):1541-50. doi: 10.1172/JCI15420. [PubMed:12070301 ]

Showing NP-Card for LacCer(d18:1/24:1(15Z)) (NP0136229)

MOL for NP0136229 (LacCer(d18:1/24:1(15Z)))

3D MOL for NP0136229 (LacCer(d18:1/24:1(15Z)))

3D SDF for NP0136229 (LacCer(d18:1/24:1(15Z)))

3D-SDF for NP0136229 (LacCer(d18:1/24:1(15Z)))

PDB for NP0136229 (LacCer(d18:1/24:1(15Z)))

3D PDB for NP0136229 (LacCer(d18:1/24:1(15Z)))

SMILES for NP0136229 (LacCer(d18:1/24:1(15Z)))

INCHI for NP0136229 (LacCer(d18:1/24:1(15Z)))

Structure for NP0136229 (LacCer(d18:1/24:1(15Z)))

3D Structure for NP0136229 (LacCer(d18:1/24:1(15Z)))