Record Information |
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Version | 1.0 |
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Created at | 2022-04-28 23:20:28 UTC |
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Updated at | 2022-04-28 23:20:28 UTC |
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NP-MRD ID | NP0078235 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | (-)-5,5''-bis- [2,3-dicarboxy-6,7-dihydroxy-1-(3',4'-dihydroxyphenyl)-1,2-dihydronaphthalene] |
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Description | (1R,1'S)-1,1',2,2'-Tetrahydro-1beta,1'alpha-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2alpha,2'beta,3,3'-tetracarboxylic acid belongs to the class of organic compounds known as aryltetralin lignans. These are lignans with a structure based on the 1-phenyltetralin skeleton. (-)-5,5''-bis- [2,3-dicarboxy-6,7-dihydroxy-1-(3',4'-dihydroxyphenyl)-1,2-dihydronaphthalene] is found in Bazzania trilobata. Based on a literature review very few articles have been published on (1R,1'S)-1,1',2,2'-Tetrahydro-1beta,1'alpha-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2alpha,2'beta,3,3'-tetracarboxylic acid. |
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Structure | OC(=O)[C@@H]1[C@@H](C2=CC(O)=C(O)C=C2)C2=C(C=C1C(O)=O)C(=C(O)C(O)=C2)C1=C(O)C(O)=CC2=C1C=C([C@H]([C@@H]2C1=CC(O)=C(O)C=C1)C(O)=O)C(O)=O InChI=1S/C36H26O16/c37-19-3-1-11(5-21(19)39)25-15-9-23(41)31(43)27(13(15)7-17(33(45)46)29(25)35(49)50)28-14-8-18(34(47)48)30(36(51)52)26(16(14)10-24(42)32(28)44)12-2-4-20(38)22(40)6-12/h1-10,25-26,29-30,37-44H,(H,45,46)(H,47,48)(H,49,50)(H,51,52)/t25-,26+,29-,30+ |
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Synonyms | Value | Source |
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(1R,1's)-1,1',2,2'-Tetrahydro-1b,1'a-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2a,2'b,3,3'-tetracarboxylate | Generator | (1R,1's)-1,1',2,2'-Tetrahydro-1b,1'a-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2a,2'b,3,3'-tetracarboxylic acid | Generator | (1R,1's)-1,1',2,2'-Tetrahydro-1beta,1'alpha-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2alpha,2'beta,3,3'-tetracarboxylate | Generator | (1R,1's)-1,1',2,2'-Tetrahydro-1β,1'α-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2α,2'β,3,3'-tetracarboxylate | Generator | (1R,1's)-1,1',2,2'-Tetrahydro-1β,1'α-bis(3,4-dihydroxyphenyl)-6,6',7,7'-tetrahydroxy-5,5'-bi[naphthalene]-2α,2'β,3,3'-tetracarboxylic acid | Generator |
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Chemical Formula | C36H26O16 |
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Average Mass | 714.5880 Da |
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Monoisotopic Mass | 714.12208 Da |
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IUPAC Name | (5R,5'S,6S,6'R)-5,5'-bis(3,4-dihydroxyphenyl)-2,2',3,3'-tetrahydroxy-5H,5'H,6H,6'H-[1,1'-binaphthalene]-6,6',7,7'-tetracarboxylic acid |
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Traditional Name | (5R,5'S,6S,6'R)-5,5'-bis(3,4-dihydroxyphenyl)-2,2',3,3'-tetrahydroxy-5H,5'H,6H,6'H-[1,1'-binaphthalene]-6,6',7,7'-tetracarboxylic acid |
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CAS Registry Number | Not Available |
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SMILES | OC(=O)[C@@H]1[C@@H](C2=CC(O)=C(O)C=C2)C2=C(C=C1C(O)=O)C(=C(O)C(O)=C2)C1=C(O)C(O)=CC2=C1C=C([C@H]([C@@H]2C1=CC(O)=C(O)C=C1)C(O)=O)C(O)=O |
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InChI Identifier | InChI=1S/C36H26O16/c37-19-3-1-11(5-21(19)39)25-15-9-23(41)31(43)27(13(15)7-17(33(45)46)29(25)35(49)50)28-14-8-18(34(47)48)30(36(51)52)26(16(14)10-24(42)32(28)44)12-2-4-20(38)22(40)6-12/h1-10,25-26,29-30,37-44H,(H,45,46)(H,47,48)(H,49,50)(H,51,52)/t25-,26+,29-,30+ |
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InChI Key | XEIDYNIZTOEXSR-JXALSKIBSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Spectrum Type | Description | Depositor ID | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 25 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 252 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 50 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 75 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 101 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 126 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 151 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 176 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 201 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 226 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as aryltetralin lignans. These are lignans with a structure based on the 1-phenyltetralin skeleton. |
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Kingdom | Organic compounds |
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Super Class | Lignans, neolignans and related compounds |
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Class | Aryltetralin lignans |
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Sub Class | Not Available |
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Direct Parent | Aryltetralin lignans |
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Alternative Parents | |
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Substituents | - 1-aryltetralin lignan
- Biphenol
- 2-naphthalenecarboxylic acid
- 2-naphthalenecarboxylic acid or derivatives
- Tetracarboxylic acid or derivatives
- 2-naphthol
- Naphthalene
- Catechol
- 1-hydroxy-4-unsubstituted benzenoid
- 1-hydroxy-2-unsubstituted benzenoid
- Phenol
- Monocyclic benzene moiety
- Benzenoid
- Carboxylic acid
- Carboxylic acid derivative
- Hydrocarbon derivative
- Organic oxide
- Carbonyl group
- Organic oxygen compound
- Organooxygen compound
- Aromatic homopolycyclic compound
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Molecular Framework | Aromatic homopolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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