NP-MRD: Showing NP-Card for Pseudolaric acid B O-beta-D-glucopyranoside (NP0077028)

Jump To Section:

Identification Spectra BioTaxonomy ChemoTaxonomy Physical properties Links References XML

Record Information

Version

2.0

Created at

2022-04-28 22:12:03 UTC

Updated at

2022-04-28 22:12:03 UTC

NP-MRD ID

NP0077028

Secondary Accession Numbers

None

Natural Product Identification

Common Name

Pseudolaric acid B O-beta-D-glucopyranoside

Description

Methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0¹,⁷]Tridec-3-ene-4-carboxylate belongs to the class of organic compounds known as diterpene lactones. These are diterpenoids containing a lactone moiety. Pseudolaric acid B O-beta-D-glucopyranoside is found in Larix kaempferi and Pseudolarix kaempferi . Based on a literature review very few articles have been published on methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0¹,⁷]Tridec-3-ene-4-carboxylate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652304292200122D          

 42 45  0  0  1  0            999 V2000
    0.8721    0.9947    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9235    1.8721    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1694    0.5717    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1781   -0.2533    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.8284   -0.7608    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4316   -0.0199    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5901    0.7897    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3219    1.1706    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0760    0.8359    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2845    0.0377    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7904   -0.6230    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9658   -0.6486    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1675   -0.1317    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5352   -0.9090    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.9133    0.3278    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.7298    0.0831    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9809    0.1782    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6308   -0.5688    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6529    0.4812    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1626    1.3887    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4195    2.2390    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6526    1.7643    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1312   -1.1395    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2739   -2.0239    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0170   -2.4957    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0604   -3.3312    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7953   -3.7061    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8381   -4.5300    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4874   -3.2571    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2223   -3.6320    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.2651   -4.4559    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.0000   -4.8307    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.6921   -4.3817    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.6493   -3.5578    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.9144   -3.1830    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.3414   -3.1088    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0763   -3.4837    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.4270   -4.7566    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0428   -5.6546    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5730   -4.9049    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3682   -3.7802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7478   -0.3497    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  1  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  1  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
  6 12  1  0  0  0  0
 10 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
  7 17  1  1  0  0  0
 17 18  1  0  0  0  0
  5 18  1  1  0  0  0
  6 19  1  1  0  0  0
 19 20  1  0  0  0  0
 20 21  2  0  0  0  0
 20 22  1  0  0  0  0
  4 23  1  1  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
 27 29  1  0  0  0  0
 30 29  1  1  0  0  0
 30 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  0  0  0  0
 30 35  1  0  0  0  0
 34 36  1  1  0  0  0
 36 37  1  0  0  0  0
 33 38  1  1  0  0  0
 32 39  1  1  0  0  0
 31 40  1  6  0  0  0
 26 41  1  0  0  0  0
  4 42  1  6  0  0  0
M  END

     RDKit          3D

 80 83  0  0  0  0  0  0  0  0999 V2000
    9.7179    1.2944    1.4989 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.3245    1.1800    1.2058 O   0  0  0  0  0  0  0  0  0  0  0  0
    7.8354    0.0007    0.6925 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.6427   -0.9375    0.5005 O   0  0  0  0  0  0  0  0  0  0  0  0
    6.4039   -0.1834    0.3673 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.1136   -1.3732   -0.1139 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.8128   -1.9349   -0.5517 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.6854   -0.9885   -0.4196 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.4638   -1.6331   -1.1062 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5671   -0.4662   -1.4941 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.2233    0.7549   -0.8268 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.6944    0.3135   -1.0660 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.6520    0.2707   -2.4578 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.4351   -0.1744   -3.4210 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.0291   -0.0577   -4.8561 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.5028   -0.6865   -3.1240 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.6296    1.3425   -0.5258 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.4968    0.9398    0.6100 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7816    0.8043    0.5544 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.0179    2.1231    1.2712 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2668    0.7087    0.4796 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4292   -0.1349    1.1706 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8793   -0.1266    1.0084 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6486   -0.9607    1.6830 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.9869   -1.9070    2.6119 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.1117   -0.9438    1.5118 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8397   -1.7386    2.1551 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7274   -0.0608    0.6453 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1197   -0.0779    0.5124 C   0  0  2  0  0  0  0  0  0  0  0  0
   -6.4591   -0.3043   -0.8218 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.7946   -0.7444   -0.8217 C   0  0  2  0  0  0  0  0  0  0  0  0
   -8.0883   -1.2767   -2.2080 C   0  0  0  0  0  0  0  0  0  0  0  0
   -9.4071   -1.7142   -2.2184 O   0  0  0  0  0  0  0  0  0  0  0  0
   -8.6635    0.4323   -0.5196 C   0  0  2  0  0  0  0  0  0  0  0  0
   -8.5380    1.3720   -1.5574 O   0  0  0  0  0  0  0  0  0  0  0  0
   -8.2566    1.0676    0.7920 C   0  0  2  0  0  0  0  0  0  0  0  0
   -8.9179    2.2963    0.8792 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.7571    1.2381    0.9046 C   0  0  1  0  0  0  0  0  0  0  0  0
   -6.4674    1.6045    2.2095 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2251   -0.2077    1.3924 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.2957   -0.9801    1.0319 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9427   -1.6661    1.8711 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.1168    0.3677    1.9383 H   0  0  0  0  0  0  0  0  0  0  0  0
   10.2177    1.4665    0.5157 H   0  0  0  0  0  0  0  0  0  0  0  0
    9.9452    2.1318    2.1623 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.9321   -2.0664   -0.2155 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.6163   -2.7315    0.2608 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.8505   -2.5636   -1.4517 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.8358   -2.1858   -1.9838 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9591   -2.3416   -0.4394 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5725   -0.6723   -1.0687 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5784   -0.3855   -2.5819 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0012    1.6786   -1.3641 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.3102   -0.8983   -5.0492 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.8872   -0.0747   -5.5315 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.4203    0.8756   -4.9349 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.0337    2.2256   -0.2211 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.3197    1.7585   -1.3214 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.1643    1.8381    0.8067 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9429    0.8555    1.5921 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.1963    2.2321    2.0403 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.9343    2.1160    1.8957 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9216    2.9960    0.6152 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1986    1.4012   -0.1982 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0543   -0.8192    1.8428 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.3875    0.5529    0.3379 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2637   -1.4081    3.2876 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7776   -2.4507    3.1586 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4672   -2.6758    1.9842 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.5385   -0.8483    1.1666 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.8666   -1.5202   -0.0602 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.4370   -2.1710   -2.4043 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.8509   -0.5513   -2.9940 H   0  0  0  0  0  0  0  0  0  0  0  0
   -9.7718   -1.8456   -1.2999 H   0  0  0  0  0  0  0  0  0  0  0  0
   -9.7180    0.1294   -0.4295 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.5917    1.2873   -1.8838 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.6096    0.4276    1.6175 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.5889    2.9133    0.1761 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.4742    2.0474    0.1871 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.9366    2.4448    2.2053 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  3  4  2  0
  3  5  1  0
  5  6  2  0
  6  7  1  0
  8  7  1  1
  8  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 17  1  0
 17 18  1  0
 12 13  1  6
 13 14  1  0
 14 15  1  0
 14 16  2  0
 11 19  1  0
 19 20  1  1
 19 40  1  0
 40 41  1  0
 41 42  2  0
 19 21  1  0
 21 22  2  0
 22 23  1  0
 23 24  2  0
 24 25  1  0
 24 26  1  0
 26 27  2  0
 26 28  1  0
 28 29  1  0
 29 30  1  0
 30 31  1  0
 31 32  1  0
 32 33  1  0
 31 34  1  0
 34 35  1  0
 34 36  1  0
 36 37  1  0
 36 38  1  0
 38 39  1  0
 18  5  1  0
 38 29  1  0
 12  8  1  0
  8 41  1  0
  1 43  1  0
  1 44  1  0
  1 45  1  0
  6 46  1  0
  7 47  1  0
  7 48  1  0
  9 49  1  0
  9 50  1  0
 10 51  1  0
 10 52  1  0
 11 53  1  6
 17 57  1  0
 17 58  1  0
 18 59  1  0
 18 60  1  0
 15 54  1  0
 15 55  1  0
 15 56  1  0
 20 61  1  0
 20 62  1  0
 20 63  1  0
 21 64  1  0
 22 65  1  0
 23 66  1  0
 25 67  1  0
 25 68  1  0
 25 69  1  0
 29 70  1  1
 31 71  1  1
 32 72  1  0
 32 73  1  0
 33 74  1  0
 34 75  1  1
 35 76  1  0
 36 77  1  1
 37 78  1  0
 38 79  1  6
 39 80  1  0
M  END


  Mrv1652304292200122D          

 42 45  0  0  1  0            999 V2000
    0.8721    0.9947    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9235    1.8721    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1694    0.5717    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1781   -0.2533    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.8284   -0.7608    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4316   -0.0199    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5901    0.7897    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    2.3219    1.1706    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.0760    0.8359    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.2845    0.0377    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.7904   -0.6230    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9658   -0.6486    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.1675   -0.1317    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.5352   -0.9090    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.9133    0.3278    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.7298    0.0831    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.9809    0.1782    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.6308   -0.5688    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6529    0.4812    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.1626    1.3887    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.4195    2.2390    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6526    1.7643    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1312   -1.1395    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2739   -2.0239    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0170   -2.4957    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0604   -3.3312    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7953   -3.7061    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8381   -4.5300    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4874   -3.2571    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2223   -3.6320    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.2651   -4.4559    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.0000   -4.8307    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.6921   -4.3817    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -4.6493   -3.5578    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.9144   -3.1830    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.3414   -3.1088    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0763   -3.4837    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.4270   -4.7566    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.0428   -5.6546    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5730   -4.9049    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3682   -3.7802    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7478   -0.3497    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  1  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  1  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
  6 12  1  0  0  0  0
 10 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
  7 17  1  1  0  0  0
 17 18  1  0  0  0  0
  5 18  1  1  0  0  0
  6 19  1  1  0  0  0
 19 20  1  0  0  0  0
 20 21  2  0  0  0  0
 20 22  1  0  0  0  0
  4 23  1  1  0  0  0
 23 24  2  0  0  0  0
 24 25  1  0  0  0  0
 25 26  2  0  0  0  0
 26 27  1  0  0  0  0
 27 28  2  0  0  0  0
 27 29  1  0  0  0  0
 30 29  1  1  0  0  0
 30 31  1  0  0  0  0
 31 32  1  0  0  0  0
 32 33  1  0  0  0  0
 33 34  1  0  0  0  0
 34 35  1  0  0  0  0
 30 35  1  0  0  0  0
 34 36  1  1  0  0  0
 36 37  1  0  0  0  0
 33 38  1  1  0  0  0
 32 39  1  1  0  0  0
 31 40  1  6  0  0  0
 26 41  1  0  0  0  0
  4 42  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0077028

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)C1=CC[C@]23CC[C@H]([C@]2(CC1)OC(C)=O)[C@](C)(OC3=O)\C=C\C=C(/C)C(=O)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C29H38O13/c1-15(23(35)40-25-22(34)21(33)20(32)18(14-30)39-25)6-5-10-27(3)19-9-12-28(26(37)42-27)11-7-17(24(36)38-4)8-13-29(19,28)41-16(2)31/h5-7,10,18-22,25,30,32-34H,8-9,11-14H2,1-4H3/b10-5+,15-6+/t18-,19+,20+,21+,22-,25+,27-,28-,29+/m1/s1

> <INCHI_KEY>
UUDZDKPKXAEKLA-MGCZPWRESA-N

> <FORMULA>
C29H38O13

> <MOLECULAR_WEIGHT>
594.61

> <EXACT_MASS>
594.231241284

> <JCHEM_ACCEPTOR_COUNT>
9

> <JCHEM_ATOM_COUNT>
80

> <JCHEM_AVERAGE_POLARIZABILITY>
60.99137341568312

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0^{1,7}]tridec-3-ene-4-carboxylate

> <ALOGPS_LOGP>
1.17

> <JCHEM_LOGP>
0.9128719793333326

> <ALOGPS_LOGS>
-3.25

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
13.194438899494454

> <JCHEM_PKA_STRONGEST_ACIDIC>
12.195723003645796

> <JCHEM_PKA_STRONGEST_BASIC>
-2.9810938228983064

> <JCHEM_POLAR_SURFACE_AREA>
195.34999999999997

> <JCHEM_REFRACTIVITY>
143.5627

> <JCHEM_ROTATABLE_BOND_COUNT>
10

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
3.35e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0^{1,7}]tridec-3-ene-4-carboxylate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 29-APR-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   29-APR-22         0                                  
HETATM    1  C   UNK     0       1.628   1.857   0.000  0.00  0.00           C+0
HETATM    2  O   UNK     0       1.724   3.495   0.000  0.00  0.00           O+0
HETATM    3  O   UNK     0       0.316   1.067   0.000  0.00  0.00           O+0
HETATM    4  C   UNK     0       0.332  -0.473   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       1.546  -1.420   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0       2.672  -0.037   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0       2.968   1.474   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       4.334   2.185   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       5.742   1.560   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       6.131   0.070   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       5.209  -1.163   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       3.669  -1.211   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       7.779  -0.246   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       8.466  -1.697   0.000  0.00  0.00           O+0
HETATM   15  O   UNK     0       9.171   0.612   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0      10.696   0.155   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0       3.698   0.333   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0       3.044  -1.062   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       1.219   0.898   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       0.303   2.592   0.000  0.00  0.00           C+0
HETATM   21  O   UNK     0       0.783   4.179   0.000  0.00  0.00           O+0
HETATM   22  C   UNK     0      -1.218   3.293   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      -0.245  -2.127   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0      -0.511  -3.778   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0      -1.898  -4.659   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      -1.979  -6.218   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      -3.351  -6.918   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      -3.431  -8.456   0.000  0.00  0.00           O+0
HETATM   29  O   UNK     0      -4.643  -6.080   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0      -6.015  -6.780   0.000  0.00  0.00           C+0
HETATM   31  C   UNK     0      -6.095  -8.318   0.000  0.00  0.00           C+0
HETATM   32  C   UNK     0      -7.467  -9.017   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0      -8.759  -8.179   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0      -8.679  -6.641   0.000  0.00  0.00           C+0
HETATM   35  O   UNK     0      -7.307  -5.942   0.000  0.00  0.00           O+0
HETATM   36  C   UNK     0      -9.971  -5.803   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0     -11.342  -6.503   0.000  0.00  0.00           O+0
HETATM   38  O   UNK     0     -10.130  -8.879   0.000  0.00  0.00           O+0
HETATM   39  O   UNK     0      -7.547 -10.555   0.000  0.00  0.00           O+0
HETATM   40  O   UNK     0      -4.803  -9.156   0.000  0.00  0.00           O+0
HETATM   41  C   UNK     0      -0.687  -7.056   0.000  0.00  0.00           C+0
HETATM   42  C   UNK     0      -1.396  -0.653   0.000  0.00  0.00           C+0
CONECT    1    2    3    7                                                  
CONECT    2    1                                                            
CONECT    3    1    4                                                       
CONECT    4    3    5   23   42                                             
CONECT    5    4    6   18                                                  
CONECT    6    5    7   12   19                                             
CONECT    7    6    1    8   17                                             
CONECT    8    7    9                                                       
CONECT    9    8   10                                                       
CONECT   10    9   11   13                                                  
CONECT   11   10   12                                                       
CONECT   12   11    6                                                       
CONECT   13   10   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16                                                       
CONECT   16   15                                                            
CONECT   17    7   18                                                       
CONECT   18   17    5                                                       
CONECT   19    6   20                                                       
CONECT   20   19   21   22                                                  
CONECT   21   20                                                            
CONECT   22   20                                                            
CONECT   23    4   24                                                       
CONECT   24   23   25                                                       
CONECT   25   24   26                                                       
CONECT   26   25   27   41                                                  
CONECT   27   26   28   29                                                  
CONECT   28   27                                                            
CONECT   29   27   30                                                       
CONECT   30   29   31   35                                                  
CONECT   31   30   32   40                                                  
CONECT   32   31   33   39                                                  
CONECT   33   32   34   38                                                  
CONECT   34   33   35   36                                                  
CONECT   35   34   30                                                       
CONECT   36   34   37                                                       
CONECT   37   36                                                            
CONECT   38   33                                                            
CONECT   39   32                                                            
CONECT   40   31                                                            
CONECT   41   26                                                            
CONECT   42    4                                                            
MASTER        0    0    0    0    0    0    0    0   42    0   90    0
END

View in JSmol

Synonyms

Value	Source
Methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0,]tridec-3-ene-4-carboxylic acid	Generator

Chemical Formula

C₂₉H₃₈O₁₃

Average Mass

594.6100 Da

Monoisotopic Mass

594.23124 Da

IUPAC Name

methyl (1R,7S,8S,9R)-7-(acetyloxy)-9-methyl-9-[(1E,3E)-4-methyl-5-oxo-5-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}penta-1,3-dien-1-yl]-11-oxo-10-oxatricyclo[6.3.2.0^{1,7}]tridec-3-ene-4-carboxylate

Traditional Name

CAS Registry Number

Not Available

SMILES

COC(=O)C1=CC[C@]23CC[C@H]([C@]2(CC1)OC(C)=O)[C@](C)(OC3=O)\C=C\C=C(/C)C(=O)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O

InChI Identifier

InChI=1S/C29H38O13/c1-15(23(35)40-25-22(34)21(33)20(32)18(14-30)39-25)6-5-10-27(3)19-9-12-28(26(37)42-27)11-7-17(24(36)38-4)8-13-29(19,28)41-16(2)31/h5-7,10,18-22,25,30,32-34H,8-9,11-14H2,1-4H3/b10-5+,15-6+/t18-,19+,20+,21+,22-,25+,27-,28-,29+/m1/s1

InChI Key

UUDZDKPKXAEKLA-MGCZPWRESA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Larix kaempferi	LOTUS Database	35616633
Pseudolarix amabilis	Plant	KNApSAcK

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as diterpene lactones. These are diterpenoids containing a lactone moiety.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Terpene lactones

Direct Parent

Diterpene lactones

Alternative Parents

Substituents

Prenyldaucane diterpenoid
Diterpenoid
Diterpene lactone
Tetracarboxylic acid or derivatives
Hexose monosaccharide
Caprolactone
Oxepane
Delta_valerolactone
Fatty acid ester
Delta valerolactone
Fatty acyl
Oxane
Monosaccharide
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Methyl ester
Secondary alcohol
Lactone
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Polyol
Carboxylic acid derivative
Acetal
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Primary alcohol
Organooxygen compound
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.17	ALOGPS
logP	0.91	ChemAxon
logS	-3.2	ALOGPS
pKa (Strongest Acidic)	12.2	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	195.35 Å²	ChemAxon
Rotatable Bond Count	10	ChemAxon
Refractivity	143.56 m³·mol⁻¹	ChemAxon
Polarizability	60.99 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162981580

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Not Available

Showing NP-Card for Pseudolaric acid B O-beta-D-glucopyranoside (NP0077028)

MOL for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

3D MOL for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

3D SDF for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

3D-SDF for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

PDB for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

3D PDB for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

SMILES for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

INCHI for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

Structure for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)

3D Structure for NP0077028 (Pseudolaric acid B O-beta-D-glucopyranoside)