NP-MRD: Showing NP-Card for (-)-Sinocrassoside A6 (NP0072312)

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Record Information

Version

2.0

Created at

2022-04-28 17:40:25 UTC

Updated at

2022-04-28 17:40:25 UTC

NP-MRD ID

NP0072312

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(-)-Sinocrassoside A6

Description

(2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate belongs to the class of organic compounds known as flavonoid-7-o-glycosides. (-)-Sinocrassoside A6 is found in Sinocrassula indica . These are phenolic compounds containing a flavonoid moiety which is O-glycosidically linked to carbohydrate moiety at the C7-position (2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate is an extremely weak basic (essentially neutral) compound (based on its pKa).

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309272006312D          

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M  END

     RDKit          3D

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M  END


  Mrv1652309272006312D          

 51 55  0  0  0  0            999 V2000
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10008.296410009.9076    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
10011.861710008.6669    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
10012.570610007.4218    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
10012.570610006.5942    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
10013.289210006.1805    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
10014.003610006.5942    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
10014.003610007.4218    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
10013.289210007.8360    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
10014.720710007.8354    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
10011.854110006.1801    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
10011.854510005.3524    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
10013.290310005.3528    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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10013.290310008.6635    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
10015.458110006.2903    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
10015.609610007.1021    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
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10006.153110011.1482    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
10006.870210012.3858    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
10006.155710012.7998    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
10007.586010012.7976    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
10008.300610012.3835    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  9 10  2  0  0  0  0
 10 11  1  0  0  0  0
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  9  2  1  0  0  0  0
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  1 30  2  0  0  0  0
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 43 45  1  0  0  0  0
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  5 46  1  0  0  0  0
 48 49  1  0  0  0  0
 48 50  1  0  0  0  0
 46 47  2  0  0  0  0
 50 51  1  0  0  0  0
 48 46  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0072312

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CC[C@H](C)C(=O)O[C@H]1[C@H](OC2=CC(O)=C3C(OC(C4=CC=C(O)C=C4)=C(O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](OC(C)=O)[C@H]4O)C3=O)=C2)O[C@@H](C)[C@H](O)[C@H]1O

> <INCHI_IDENTIFIER>
InChI=1S/C34H40O17/c1-5-13(2)32(44)50-31-26(42)23(39)14(3)45-34(31)47-18-10-19(38)22-20(11-18)48-28(16-6-8-17(37)9-7-16)30(25(22)41)51-33-27(43)29(46-15(4)36)24(40)21(12-35)49-33/h6-11,13-14,21,23-24,26-27,29,31,33-35,37-40,42-43H,5,12H2,1-4H3/t13-,14-,21+,23-,24+,26+,27+,29-,31+,33-,34-/m0/s1

> <INCHI_KEY>
YACMGOPITHMLRT-SVEZSJQKSA-N

> <FORMULA>
C34H40O17

> <MOLECULAR_WEIGHT>
720.677

> <EXACT_MASS>
720.226549828

> <JCHEM_ACCEPTOR_COUNT>
15

> <JCHEM_ATOM_COUNT>
91

> <JCHEM_AVERAGE_POLARIZABILITY>
71.8939146959311

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
7

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

> <ALOGPS_LOGP>
1.88

> <JCHEM_LOGP>
1.5079135100000005

> <ALOGPS_LOGS>
-3.06

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
8.556848281787117

> <JCHEM_PKA_STRONGEST_ACIDIC>
7.083311119406551

> <JCHEM_PKA_STRONGEST_BASIC>
-2.9811117404391227

> <JCHEM_POLAR_SURFACE_AREA>
257.42999999999995

> <JCHEM_REFRACTIVITY>
170.00070000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
12

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
6.24e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxochromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 27-SEP-20   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   27-SEP-20         0                                  
HETATM    1  O   UNK     0    8688.8118681.295   0.000  0.00  0.00           O+0
HETATM    2  O   UNK     0    8695.4748688.238   0.000  0.00  0.00           O+0
HETATM    3  O   UNK     0    8686.1488681.295   0.000  0.00  0.00           O+0
HETATM    4  O   UNK     0    8683.4858685.933   0.000  0.00  0.00           O+0
HETATM    5  O   UNK     0    8680.8228687.472   0.000  0.00  0.00           O+0
HETATM    6  O   UNK     0    8678.1528685.933   0.000  0.00  0.00           O+0
HETATM    7  C   UNK     0    8680.8228681.313   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0    8678.1528682.853   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0    8694.1438687.472   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0    8692.8098688.242   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0    8691.4768687.472   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0    8691.4768685.933   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0    8692.8098685.163   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0    8694.1438685.933   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0    8686.1488685.924   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0    8684.8148685.155   0.000  0.00  0.00           C+0
HETATM   17  C   UNK     0    8684.8148683.615   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0    8686.1478682.845   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0    8688.8108685.924   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0    8687.4768685.154   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0    8687.4768683.614   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0    8690.1438685.154   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0    8690.1438683.614   0.000  0.00  0.00           C+0
HETATM   24  C   UNK     0    8680.8208685.930   0.000  0.00  0.00           C+0
HETATM   25  C   UNK     0    8679.4878685.161   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0    8679.4878683.621   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0    8680.8208682.852   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0    8682.1538683.621   0.000  0.00  0.00           O+0
HETATM   29  C   UNK     0    8682.1538685.161   0.000  0.00  0.00           C+0
HETATM   30  C   UNK     0    8688.8088682.845   0.000  0.00  0.00           C+0
HETATM   31  O   UNK     0    8690.1328680.521   0.000  0.00  0.00           O+0
HETATM   32  C   UNK     0    8690.1328678.976   0.000  0.00  0.00           C+0
HETATM   33  C   UNK     0    8691.4738678.204   0.000  0.00  0.00           C+0
HETATM   34  C   UNK     0    8692.8078678.976   0.000  0.00  0.00           C+0
HETATM   35  C   UNK     0    8692.8078680.521   0.000  0.00  0.00           C+0
HETATM   36  C   UNK     0    8691.4738681.294   0.000  0.00  0.00           C+0
HETATM   37  O   UNK     0    8694.1458681.293   0.000  0.00  0.00           O+0
HETATM   38  C   UNK     0    8688.7948678.203   0.000  0.00  0.00           C+0
HETATM   39  O   UNK     0    8688.7958676.658   0.000  0.00  0.00           O+0
HETATM   40  O   UNK     0    8691.4758676.658   0.000  0.00  0.00           O+0
HETATM   41  O   UNK     0    8694.0688677.896   0.000  0.00  0.00           O+0
HETATM   42  O   UNK     0    8691.4758682.838   0.000  0.00  0.00           O+0
HETATM   43  C   UNK     0    8695.5228678.409   0.000  0.00  0.00           C+0
HETATM   44  O   UNK     0    8695.8058679.924   0.000  0.00  0.00           O+0
HETATM   45  C   UNK     0    8696.6938677.406   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0    8679.4898688.245   0.000  0.00  0.00           C+0
HETATM   47  O   UNK     0    8678.1538687.477   0.000  0.00  0.00           O+0
HETATM   48  C   UNK     0    8679.4918689.787   0.000  0.00  0.00           C+0
HETATM   49  C   UNK     0    8678.1578690.560   0.000  0.00  0.00           C+0
HETATM   50  C   UNK     0    8680.8278690.555   0.000  0.00  0.00           C+0
HETATM   51  C   UNK     0    8682.1618689.782   0.000  0.00  0.00           C+0
CONECT    1   30                                                            
CONECT    2    9                                                            
CONECT    3   18                                                            
CONECT    4   16   29                                                       
CONECT    5   24   46                                                       
CONECT    6   25                                                            
CONECT    7   27                                                            
CONECT    8   26                                                            
CONECT    9   10   14    2                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13   22                                                  
CONECT   13   12   14                                                       
CONECT   14   13    9                                                       
CONECT   15   16   20                                                       
CONECT   16   15   17    4                                                  
CONECT   17   16   18                                                       
CONECT   18   17   21    3                                                  
CONECT   19   20   22                                                       
CONECT   20   21   19   15                                                  
CONECT   21   20   18   30                                                  
CONECT   22   19   12   23                                                  
CONECT   23   22   30   42                                                  
CONECT   24   25   29    5                                                  
CONECT   25   24   26    6                                                  
CONECT   26   25   27    8                                                  
CONECT   27   26   28    7                                                  
CONECT   28   27   29                                                       
CONECT   29   24   28    4                                                  
CONECT   30   23   21    1                                                  
CONECT   31   36   32                                                       
CONECT   32   38   31   33                                                  
CONECT   33   40   32   34                                                  
CONECT   34   41   33   35                                                  
CONECT   35   36   37   34                                                  
CONECT   36   35   31   42                                                  
CONECT   37   35                                                            
CONECT   38   32   39                                                       
CONECT   39   38                                                            
CONECT   40   33                                                            
CONECT   41   34   43                                                       
CONECT   42   36   23                                                       
CONECT   43   41   45   44                                                  
CONECT   44   43                                                            
CONECT   45   43                                                            
CONECT   46    5   47   48                                                  
CONECT   47   46                                                            
CONECT   48   49   50   46                                                  
CONECT   49   48                                                            
CONECT   50   48   51                                                       
CONECT   51   50                                                            
MASTER        0    0    0    0    0    0    0    0   51    0  110    0
END

View in JSmol

Synonyms

Value	Source
(2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoic acid	Generator

Chemical Formula

C₃₄H₄₀O₁₇

Average Mass

720.6770 Da

Monoisotopic Mass

720.22655 Da

IUPAC Name

Traditional Name

(2S,3R,4R,5R,6S)-2-[(3-{[(2S,3R,4S,5R,6R)-4-(acetyloxy)-3,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxochromen-7-yl)oxy]-4,5-dihydroxy-6-methyloxan-3-yl (2S)-2-methylbutanoate

CAS Registry Number

Not Available

SMILES

CC[C@H](C)C(=O)O[C@H]1[C@H](OC2=CC(O)=C3C(OC(C4=CC=C(O)C=C4)=C(O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](OC(C)=O)[C@H]4O)C3=O)=C2)O[C@@H](C)[C@H](O)[C@H]1O

InChI Identifier

InChI=1S/C34H40O17/c1-5-13(2)32(44)50-31-26(42)23(39)14(3)45-34(31)47-18-10-19(38)22-20(11-18)48-28(16-6-8-17(37)9-7-16)30(25(22)41)51-33-27(43)29(46-15(4)36)24(40)21(12-35)49-33/h6-11,13-14,21,23-24,26-27,29,31,33-35,37-40,42-43H,5,12H2,1-4H3/t13-,14-,21+,23-,24+,26+,27+,29-,31+,33-,34-/m0/s1

InChI Key

YACMGOPITHMLRT-SVEZSJQKSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Sinocrassula indica	Plant	KNApSAcK

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as flavonoid-7-o-glycosides. These are phenolic compounds containing a flavonoid moiety which is O-glycosidically linked to carbohydrate moiety at the C7-position.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Flavonoids

Sub Class

Flavonoid glycosides

Direct Parent

Flavonoid-7-O-glycosides

Alternative Parents

Substituents

Flavonoid-3-o-glycoside
Flavonoid-7-o-glycoside
4'-hydroxyflavonoid
5-hydroxyflavonoid
Flavone
Hydroxyflavonoid
Phenolic glycoside
Chromone
Glycosyl compound
O-glycosyl compound
Benzopyran
1-benzopyran
1-hydroxy-4-unsubstituted benzenoid
1-hydroxy-2-unsubstituted benzenoid
Fatty acid ester
Phenol
Pyranone
Benzenoid
Pyran
Monocyclic benzene moiety
Dicarboxylic acid or derivatives
Monosaccharide
Fatty acyl
Oxane
Heteroaromatic compound
Vinylogous acid
Secondary alcohol
Carboxylic acid ester
Oxacycle
Acetal
Carboxylic acid derivative
Organoheterocyclic compound
Hydrocarbon derivative
Organic oxide
Carbonyl group
Organooxygen compound
Organic oxygen compound
Alcohol
Primary alcohol
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.88	ALOGPS
logP	1.51	ChemAxon
logS	-3.1	ALOGPS
pKa (Strongest Acidic)	7.08	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	15	ChemAxon
Hydrogen Donor Count	7	ChemAxon
Polar Surface Area	257.43 Å²	ChemAxon
Rotatable Bond Count	12	ChemAxon
Refractivity	170 m³·mol⁻¹	ChemAxon
Polarizability	71.89 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Not Available

Showing NP-Card for (-)-Sinocrassoside A6 (NP0072312)

MOL for NP0072312 ((-)-Sinocrassoside A6)

3D MOL for NP0072312 ((-)-Sinocrassoside A6)

3D SDF for NP0072312 ((-)-Sinocrassoside A6)

3D-SDF for NP0072312 ((-)-Sinocrassoside A6)

PDB for NP0072312 ((-)-Sinocrassoside A6)

3D PDB for NP0072312 ((-)-Sinocrassoside A6)

SMILES for NP0072312 ((-)-Sinocrassoside A6)

INCHI for NP0072312 ((-)-Sinocrassoside A6)

Structure for NP0072312 ((-)-Sinocrassoside A6)

3D Structure for NP0072312 ((-)-Sinocrassoside A6)