NP-MRD: Showing NP-Card for Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside (NP0060197)

Jump To Section:

Identification Spectra BioTaxonomy ChemoTaxonomy Physical properties Links References XML

Record Information

Version

2.0

Created at

2022-04-28 05:17:48 UTC

Updated at

2022-04-28 05:17:48 UTC

NP-MRD ID

NP0060197

Secondary Accession Numbers

None

Natural Product Identification

Common Name

Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside

Description

(2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxo-4H-chromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate belongs to the class of organic compounds known as flavonoid-3-o-glycosides. These are phenolic compounds containing a flavonoid moiety which is O-glycosidically linked to carbohydrate moiety at the C3-position. Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside is found in Tordylium apulum . Based on a literature review very few articles have been published on (2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxo-4H-chromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652304282207172D          

 49 53  0  0  1  0            999 V2000
   -1.4289   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -2.8875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -2.8875    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    0.0000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    0.8250    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1434    1.2375    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1434    2.0625    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4289    2.4750    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7145    2.0625    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.7145    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.7145    4.5375    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.4289    4.9500    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.1434    4.5375    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.1434    3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4289    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579    3.3000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724    4.5375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724    3.7125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    5.7750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    5.7750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    7.0125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579    2.4750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  1  6  1  0  0  0  0
  5  7  1  0  0  0  0
  4  8  1  0  0  0  0
  2  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
  9 15  2  0  0  0  0
 15 16  1  0  0  0  0
 17 16  1  1  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 17 22  1  0  0  0  0
 21 23  1  1  0  0  0
 23 24  1  0  0  0  0
 25 24  1  1  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 25 30  1  0  0  0  0
 29 31  1  6  0  0  0
 28 32  1  1  0  0  0
 32 33  1  0  0  0  0
 33 34  2  0  0  0  0
 33 35  1  0  0  0  0
 27 36  1  1  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 37 39  1  0  0  0  0
 26 40  1  1  0  0  0
 20 41  1  6  0  0  0
 19 42  1  1  0  0  0
 18 43  1  6  0  0  0
 12 44  2  0  0  0  0
 44 45  1  0  0  0  0
 45 46  2  0  0  0  0
 46 47  1  0  0  0  0
 11 47  2  0  0  0  0
 46 48  1  0  0  0  0
 44 49  1  0  0  0  0
M  END

     RDKit          3D

 83 87  0  0  0  0  0  0  0  0999 V2000
    8.1174   -3.4522    0.7454 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.9415   -2.7328    0.1954 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.8385   -2.7014   -1.0790 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.9846   -2.1170    0.9883 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.9195   -1.4677    0.3363 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.5785   -2.0828    0.7075 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.5901   -3.5562    0.4514 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5368   -1.4225    0.0949 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.9079   -0.4553   -0.7921 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.7128    0.2269   -1.1289 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4763    0.2641   -2.4832 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1451    1.0154   -2.6799 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.8804    0.3521   -2.0797 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0035    1.0979   -1.8928 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.2563    1.3743   -0.5130 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5457    1.1819    0.0175 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9274   -0.0482    0.4846 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1244   -1.2500    0.5217 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7779   -1.2816    0.4399 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0537   -2.4763    0.4183 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7150   -3.6762    0.4821 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.0518   -4.8879    0.4626 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.0959   -3.6769    0.5684 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7346   -4.9046    0.6327 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.7691   -2.4874    0.5870 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1855   -0.1326    0.9549 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.0157    0.8505    0.9908 C   0  0  0  0  0  0  0  0  0  0  0  0
   -7.2770    0.6144    1.5028 C   0  0  0  0  0  0  0  0  0  0  0  0
   -8.1781    1.6555    1.5500 C   0  0  0  0  0  0  0  0  0  0  0  0
   -9.4448    1.3715    2.0792 O   0  0  0  0  0  0  0  0  0  0  0  0
   -7.8550    2.9073    1.1049 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.5740    3.1676    0.5795 C   0  0  0  0  0  0  0  0  0  0  0  0
   -6.2790    4.4221    0.1437 O   0  0  0  0  0  0  0  0  0  0  0  0
   -5.6839    2.0968    0.5440 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.4188    2.2603    0.0482 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9884    3.3461   -0.3848 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0657    2.3129   -2.7854 C   0  0  2  0  0  0  0  0  0  0  0  0
   -2.0634    1.9120   -4.1446 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8983    3.2344   -2.5063 C   0  0  1  0  0  0  0  0  0  0  0  0
   -1.2434    4.2110   -1.5877 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.2972    2.3999   -2.0682 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5086    2.9839   -2.3652 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.8158    0.6187   -0.2528 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.1007    1.6620    0.3340 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8008   -0.0063    0.6986 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.2141    0.1348    2.0042 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.8451    0.8260    3.0158 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2462    0.9793    4.3724 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.9656    1.3377    2.7645 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.9665   -3.2679    0.0569 H   0  0  0  0  0  0  0  0  0  0  0  0
    7.9128   -4.5242    0.7825 H   0  0  0  0  0  0  0  0  0  0  0  0
    8.3782   -3.0431    1.7383 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9934   -1.5331   -0.7668 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.4740   -1.9310    1.8054 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.1120   -3.7109   -0.5325 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.1969   -4.1105    1.1921 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.5783   -3.9942    0.3635 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.3638   -0.8316   -1.7484 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.2838    0.8169   -2.9849 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.3854   -0.7584   -2.8982 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0524    1.1116   -3.7748 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8938    0.4740   -2.2272 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1736   -0.3946    0.4202 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0074   -2.4446    0.3513 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.0592   -4.9926    0.4024 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.7633   -4.9467    0.6965 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8478   -2.4966    0.6553 H   0  0  0  0  0  0  0  0  0  0  0  0
   -7.5037   -0.3769    1.8475 H   0  0  0  0  0  0  0  0  0  0  0  0
  -10.1655    1.0647    1.4621 H   0  0  0  0  0  0  0  0  0  0  0  0
   -8.5821    3.7050    1.1574 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.4816    4.7890   -0.2377 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9921    2.8420   -2.6493 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.7721    2.3308   -4.6637 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6226    3.7281   -3.4525 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4858    4.3887   -0.9452 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2198    2.2806   -0.9737 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.9768    3.3869   -1.5920 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.4230    1.0894   -1.0584 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.5052    1.8215    1.2037 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.7901    0.5077    0.6736 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.3042    0.4297    4.4663 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.0315    2.0511    4.6079 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9518    0.5380    5.1013 H   0  0  0  0  0  0  0  0  0  0  0  0
  7  6  1  0
  6  8  1  0
  8  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  0
 15 16  1  0
 16 17  2  0
 17 26  1  0
 26 27  1  0
 27 28  2  0
 28 29  1  0
 29 30  1  0
 29 31  2  0
 31 32  1  0
 32 33  1  0
 32 34  2  0
 34 35  1  0
 35 36  2  0
 17 18  1  0
 18 19  2  0
 19 20  1  0
 20 21  2  0
 21 22  1  0
 21 23  1  0
 23 24  1  0
 23 25  2  0
 14 37  1  0
 37 38  1  0
 37 39  1  0
 39 40  1  0
 39 41  1  0
 41 42  1  0
  9 43  1  0
 43 44  1  0
 43 45  1  0
 45 46  1  0
 46 47  1  0
 47 48  1  0
 47 49  2  0
 45  5  1  0
  5  4  1  0
  4  2  1  0
  2  1  1  0
  2  3  2  0
  5  6  1  0
 41 12  1  0
 35 16  1  0
 25 18  1  0
 34 27  1  0
  7 55  1  0
  7 56  1  0
  7 57  1  0
  6 54  1  1
  9 58  1  6
 11 59  1  0
 11 60  1  0
 12 61  1  6
 14 62  1  6
 28 68  1  0
 30 69  1  0
 31 70  1  0
 33 71  1  0
 19 63  1  0
 20 64  1  0
 22 65  1  0
 24 66  1  0
 25 67  1  0
 37 72  1  1
 38 73  1  0
 39 74  1  6
 40 75  1  0
 41 76  1  1
 42 77  1  0
 43 78  1  6
 44 79  1  0
 45 80  1  1
 48 81  1  0
 48 82  1  0
 48 83  1  0
  5 53  1  6
  1 50  1  0
  1 51  1  0
  1 52  1  0
M  END


  Mrv1652304282207172D          

 49 53  0  0  1  0            999 V2000
   -1.4289   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1434   -2.8875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -2.8875    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5724   -1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000   -0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7145   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    0.0000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    0.8250    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1434    1.2375    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.1434    2.0625    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.4289    2.4750    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7145    2.0625    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.7145    1.2375    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    2.4750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.7145    4.5375    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.4289    4.9500    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.1434    4.5375    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.1434    3.7125    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.4289    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579    3.3000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724    4.5375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.2868    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5724    3.7125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    5.7750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    6.1875    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    5.7750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.7145    7.0125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.0000    4.9500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.4289    3.3000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579    2.4750    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -0.0000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -0.4125    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.1434   -1.2375    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289   -1.6500    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.8579   -1.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.4289    0.8250    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  2  0  0  0  0
  2  3  1  0  0  0  0
  3  4  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  2  0  0  0  0
  1  6  1  0  0  0  0
  5  7  1  0  0  0  0
  4  8  1  0  0  0  0
  2  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
  9 15  2  0  0  0  0
 15 16  1  0  0  0  0
 17 16  1  1  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 17 22  1  0  0  0  0
 21 23  1  1  0  0  0
 23 24  1  0  0  0  0
 25 24  1  1  0  0  0
 25 26  1  0  0  0  0
 26 27  1  0  0  0  0
 27 28  1  0  0  0  0
 28 29  1  0  0  0  0
 29 30  1  0  0  0  0
 25 30  1  0  0  0  0
 29 31  1  6  0  0  0
 28 32  1  1  0  0  0
 32 33  1  0  0  0  0
 33 34  2  0  0  0  0
 33 35  1  0  0  0  0
 27 36  1  1  0  0  0
 36 37  1  0  0  0  0
 37 38  2  0  0  0  0
 37 39  1  0  0  0  0
 26 40  1  1  0  0  0
 20 41  1  6  0  0  0
 19 42  1  1  0  0  0
 18 43  1  6  0  0  0
 12 44  2  0  0  0  0
 44 45  1  0  0  0  0
 45 46  2  0  0  0  0
 46 47  1  0  0  0  0
 11 47  2  0  0  0  0
 46 48  1  0  0  0  0
 44 49  1  0  0  0  0
M  END
> <DATABASE_ID>
NP0060197

> <DATABASE_NAME>
NP-MRD

> <SMILES>
C[C@@H]1O[C@@H](OC[C@H]2O[C@@H](OC3=C(OC4=CC(O)=CC(O)=C4C3=O)C3=CC=C(O)C(O)=C3)[C@H](O)[C@@H](O)[C@@H]2O)[C@@H](O)[C@@H](OC(C)=O)[C@H]1OC(C)=O

> <INCHI_IDENTIFIER>
InChI=1S/C31H34O18/c1-10-26(45-11(2)32)29(46-12(3)33)25(42)30(44-10)43-9-19-21(38)23(40)24(41)31(48-19)49-28-22(39)20-17(37)7-14(34)8-18(20)47-27(28)13-4-5-15(35)16(36)6-13/h4-8,10,19,21,23-26,29-31,34-38,40-42H,9H2,1-3H3/t10-,19+,21+,23-,24+,25-,26-,29+,30+,31-/m0/s1

> <INCHI_KEY>
OILJXSBGQQNYAQ-IVNGGYPISA-N

> <FORMULA>
C31H34O18

> <MOLECULAR_WEIGHT>
694.595

> <EXACT_MASS>
694.174514255

> <JCHEM_ACCEPTOR_COUNT>
16

> <JCHEM_ATOM_COUNT>
83

> <JCHEM_AVERAGE_POLARIZABILITY>
65.73865595874219

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
8

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxo-4H-chromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate

> <ALOGPS_LOGP>
1.54

> <JCHEM_LOGP>
0.013489845666668637

> <ALOGPS_LOGS>
-2.73

> <JCHEM_MDDR_LIKE_RULE>
1

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
7.8725065878766305

> <JCHEM_PKA_STRONGEST_ACIDIC>
6.372405065126655

> <JCHEM_PKA_STRONGEST_BASIC>
-3.648686043797283

> <JCHEM_POLAR_SURFACE_AREA>
277.65999999999997

> <JCHEM_REFRACTIVITY>
158.44810000000004

> <JCHEM_ROTATABLE_BOND_COUNT>
10

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
1.28e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxochromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 28-APR-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   28-APR-22         0                                  
HETATM    1  C   UNK     0      -2.667  -4.620   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -2.667  -3.080   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -4.001  -2.310   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -5.335  -3.080   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -5.335  -4.620   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -4.001  -5.390   0.000  0.00  0.00           C+0
HETATM    7  O   UNK     0      -6.668  -5.390   0.000  0.00  0.00           O+0
HETATM    8  O   UNK     0      -6.668  -2.310   0.000  0.00  0.00           O+0
HETATM    9  C   UNK     0      -1.334  -2.310   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0       0.000  -3.080   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0       1.334  -2.310   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       1.334  -0.770   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       0.000  -0.000   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       0.000   1.540   0.000  0.00  0.00           O+0
HETATM   15  C   UNK     0      -1.334  -0.770   0.000  0.00  0.00           C+0
HETATM   16  O   UNK     0      -2.667   0.000   0.000  0.00  0.00           O+0
HETATM   17  C   UNK     0      -2.667   1.540   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      -4.001   2.310   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      -4.001   3.850   0.000  0.00  0.00           C+0
HETATM   20  C   UNK     0      -2.667   4.620   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0      -1.334   3.850   0.000  0.00  0.00           C+0
HETATM   22  O   UNK     0      -1.334   2.310   0.000  0.00  0.00           O+0
HETATM   23  C   UNK     0       0.000   4.620   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       0.000   6.160   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0       1.334   6.930   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0       1.334   8.470   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0       2.667   9.240   0.000  0.00  0.00           C+0
HETATM   28  C   UNK     0       4.001   8.470   0.000  0.00  0.00           C+0
HETATM   29  C   UNK     0       4.001   6.930   0.000  0.00  0.00           C+0
HETATM   30  O   UNK     0       2.667   6.160   0.000  0.00  0.00           O+0
HETATM   31  C   UNK     0       5.335   6.160   0.000  0.00  0.00           C+0
HETATM   32  O   UNK     0       5.335   9.240   0.000  0.00  0.00           O+0
HETATM   33  C   UNK     0       6.668   8.470   0.000  0.00  0.00           C+0
HETATM   34  O   UNK     0       8.002   9.240   0.000  0.00  0.00           O+0
HETATM   35  C   UNK     0       6.668   6.930   0.000  0.00  0.00           C+0
HETATM   36  O   UNK     0       2.667  10.780   0.000  0.00  0.00           O+0
HETATM   37  C   UNK     0       1.334  11.550   0.000  0.00  0.00           C+0
HETATM   38  O   UNK     0       0.000  10.780   0.000  0.00  0.00           O+0
HETATM   39  C   UNK     0       1.334  13.090   0.000  0.00  0.00           C+0
HETATM   40  O   UNK     0       0.000   9.240   0.000  0.00  0.00           O+0
HETATM   41  O   UNK     0      -2.667   6.160   0.000  0.00  0.00           O+0
HETATM   42  O   UNK     0      -5.335   4.620   0.000  0.00  0.00           O+0
HETATM   43  O   UNK     0      -5.335   1.540   0.000  0.00  0.00           O+0
HETATM   44  C   UNK     0       2.667  -0.000   0.000  0.00  0.00           C+0
HETATM   45  C   UNK     0       4.001  -0.770   0.000  0.00  0.00           C+0
HETATM   46  C   UNK     0       4.001  -2.310   0.000  0.00  0.00           C+0
HETATM   47  C   UNK     0       2.667  -3.080   0.000  0.00  0.00           C+0
HETATM   48  O   UNK     0       5.335  -3.080   0.000  0.00  0.00           O+0
HETATM   49  O   UNK     0       2.667   1.540   0.000  0.00  0.00           O+0
CONECT    1    2    6                                                       
CONECT    2    1    3    9                                                  
CONECT    3    2    4                                                       
CONECT    4    3    5    8                                                  
CONECT    5    4    6    7                                                  
CONECT    6    5    1                                                       
CONECT    7    5                                                            
CONECT    8    4                                                            
CONECT    9    2   10   15                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12   47                                                  
CONECT   12   11   13   44                                                  
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13    9   16                                                  
CONECT   16   15   17                                                       
CONECT   17   16   18   22                                                  
CONECT   18   17   19   43                                                  
CONECT   19   18   20   42                                                  
CONECT   20   19   21   41                                                  
CONECT   21   20   22   23                                                  
CONECT   22   21   17                                                       
CONECT   23   21   24                                                       
CONECT   24   23   25                                                       
CONECT   25   24   26   30                                                  
CONECT   26   25   27   40                                                  
CONECT   27   26   28   36                                                  
CONECT   28   27   29   32                                                  
CONECT   29   28   30   31                                                  
CONECT   30   29   25                                                       
CONECT   31   29                                                            
CONECT   32   28   33                                                       
CONECT   33   32   34   35                                                  
CONECT   34   33                                                            
CONECT   35   33                                                            
CONECT   36   27   37                                                       
CONECT   37   36   38   39                                                  
CONECT   38   37                                                            
CONECT   39   37                                                            
CONECT   40   26                                                            
CONECT   41   20                                                            
CONECT   42   19                                                            
CONECT   43   18                                                            
CONECT   44   12   45   49                                                  
CONECT   45   44   46                                                       
CONECT   46   45   47   48                                                  
CONECT   47   46   11                                                       
CONECT   48   46                                                            
CONECT   49   44                                                            
MASTER        0    0    0    0    0    0    0    0   49    0  106    0
END

View in JSmol

Synonyms

Value	Source
(2S,3S,4R,5S,6R)-3-(Acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxo-4H-chromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetic acid	Generator

Chemical Formula

C₃₁H₃₄O₁₈

Average Mass

694.5950 Da

Monoisotopic Mass

694.17451 Da

IUPAC Name

(2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxo-4H-chromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate

Traditional Name

(2S,3S,4R,5S,6R)-3-(acetyloxy)-6-{[(2R,3S,4S,5R,6S)-6-{[2-(3,4-dihydroxyphenyl)-5,7-dihydroxy-4-oxochromen-3-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methoxy}-5-hydroxy-2-methyloxan-4-yl acetate

CAS Registry Number

Not Available

SMILES

C[C@@H]1O[C@@H](OC[C@H]2O[C@@H](OC3=C(OC4=CC(O)=CC(O)=C4C3=O)C3=CC=C(O)C(O)=C3)[C@H](O)[C@@H](O)[C@@H]2O)[C@@H](O)[C@@H](OC(C)=O)[C@H]1OC(C)=O

InChI Identifier

InChI=1S/C31H34O18/c1-10-26(45-11(2)32)29(46-12(3)33)25(42)30(44-10)43-9-19-21(38)23(40)24(41)31(48-19)49-28-22(39)20-17(37)7-14(34)8-18(20)47-27(28)13-4-5-15(35)16(36)6-13/h4-8,10,19,21,23-26,29-31,34-38,40-42H,9H2,1-3H3/t10-,19+,21+,23-,24+,25-,26-,29+,30+,31-/m0/s1

InChI Key

OILJXSBGQQNYAQ-IVNGGYPISA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Tordylium apulum	Plant	KNApSAcK

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as flavonoid-3-o-glycosides. These are phenolic compounds containing a flavonoid moiety which is O-glycosidically linked to carbohydrate moiety at the C3-position.

Kingdom

Organic compounds

Super Class

Phenylpropanoids and polyketides

Class

Flavonoids

Sub Class

Flavonoid glycosides

Direct Parent

Flavonoid-3-O-glycosides

Alternative Parents

Substituents

Flavonoid-3-o-glycoside
Hydroxyflavonoid
Flavone
7-hydroxyflavonoid
5-hydroxyflavonoid
4'-hydroxyflavonoid
3'-hydroxyflavonoid
O-glycosyl compound
Glycosyl compound
Disaccharide
Chromone
1-benzopyran
Benzopyran
Catechol
1-hydroxy-4-unsubstituted benzenoid
1-hydroxy-2-unsubstituted benzenoid
Pyranone
Phenol
Benzenoid
Pyran
Oxane
Dicarboxylic acid or derivatives
Monocyclic benzene moiety
Heteroaromatic compound
Vinylogous acid
Secondary alcohol
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Polyol
Carboxylic acid derivative
Acetal
Organic oxygen compound
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Carbonyl group
Alcohol
Aromatic heteropolycyclic compound

Molecular Framework

Aromatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	1.54	ALOGPS
logP	0.013	ChemAxon
logS	-2.7	ALOGPS
pKa (Strongest Acidic)	6.37	ChemAxon
pKa (Strongest Basic)	-3.6	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	16	ChemAxon
Hydrogen Donor Count	8	ChemAxon
Polar Surface Area	277.66 Å²	ChemAxon
Rotatable Bond Count	10	ChemAxon
Refractivity	158.45 m³·mol⁻¹	ChemAxon
Polarizability	65.74 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162871306

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Not Available

Showing NP-Card for Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside (NP0060197)

MOL for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

3D MOL for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

3D SDF for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

3D-SDF for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

PDB for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

3D PDB for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

SMILES for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

INCHI for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

Structure for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)

3D Structure for NP0060197 (Quercetin 3-(3'',4''-diacetylrhamnosyl)-(1->6)-glucoside)