NP-MRD: Showing NP-Card for Sesamoside (NP0057586)

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Record Information

Version

2.0

Created at

2022-04-28 03:00:07 UTC

Updated at

2022-04-28 03:00:07 UTC

NP-MRD ID

NP0057586

Secondary Accession Numbers

None

Natural Product Identification

Common Name

Sesamoside

Description

Methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0²,⁴]Dec-7-ene-7-carboxylate belongs to the class of organic compounds known as o-glycosyl compounds. These are glycoside in which a sugar group is bonded through one carbon to another group via a O-glycosidic bond. Sesamoside is found in Lamium garganicum, Pedicularis muscicola, Phlomis mongolica, Phlomis muscicola and Sesamum angolense . Based on a literature review very few articles have been published on methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0²,⁴]Dec-7-ene-7-carboxylate.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652304282205002D          

 29 32  0  0  1  0            999 V2000
    0.7327   -1.5964    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.5364   -0.7950    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.2863   -0.7341    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.5986   -1.4977    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0312   -2.0306    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.0298   -2.8534    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1038   -0.8455    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3117    0.0906    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1323   -0.2244    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.9243   -0.4551    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1206   -1.2564    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5248   -1.8271    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7210   -2.6284    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1252   -3.1990    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5131   -2.8591    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.7093   -3.6604    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9360    0.5769    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5318    1.1475    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.3356    1.9488    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.9314    2.5194    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.7235    2.2887    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.9198    1.4874    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.3239    0.9168    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.5202    0.1155    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7119    1.2567    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.3194    2.8594    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7352    3.3208    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3310    3.8914    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8441   -2.4138    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  1  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  1  5  1  0  0  0  0
  5  6  1  6  0  0  0
  4  7  1  6  0  0  0
  3  7  1  0  0  0  0
  3  8  1  1  0  0  0
  2  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  2  0  0  0  0
  1 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
  9 17  1  6  0  0  0
 18 17  1  6  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 18 23  1  0  0  0  0
 23 24  1  6  0  0  0
 22 25  1  1  0  0  0
 21 26  1  1  0  0  0
 20 27  1  1  0  0  0
 27 28  1  0  0  0  0
  1 29  1  6  0  0  0
M  END

     RDKit          3D

 53 56  0  0  0  0  0  0  0  0999 V2000
   -6.1756    2.8432    1.1338 C   0  0  0  0  0  0  0  0  0  0  0  0
   -4.8762    2.3279    1.1864 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.5126    1.0427    0.8482 C   0  0  0  0  0  0  0  0  0  0  0  0
   -5.4189    0.2706    0.4616 O   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1485    0.5970    0.9328 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2378    1.4881    1.3616 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.9446    1.0713    1.4434 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4144    0.3117    0.3399 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.8977    0.0531    0.7324 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.8751    0.5672   -0.0606 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.6125   -0.4737   -0.6206 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7150   -0.8260    0.1463 C   0  0  1  0  0  0  0  0  0  0  0  0
    4.3532   -2.0293   -0.5324 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.4751   -2.4757    0.1493 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.7813    0.2688    0.1404 C   0  0  1  0  0  0  0  0  0  0  0  0
    5.7378    0.0420   -0.8485 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.0936    1.5838   -0.1546 C   0  0  1  0  0  0  0  0  0  0  0  0
    3.8803    1.7485   -1.5090 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.7751    1.5655    0.6231 C   0  0  2  0  0  0  0  0  0  0  0  0
    3.0827    1.2238    1.9196 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.2604   -0.9047    0.2358 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.2685   -1.5325   -1.1307 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.1359   -1.3961   -2.0876 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7221   -2.9409   -0.9734 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5693   -1.9874   -1.4770 C   0  0  1  0  0  0  0  0  0  0  0  0
   -3.5254   -1.2601   -0.5723 C   0  0  1  0  0  0  0  0  0  0  0  0
   -4.5593   -2.1020   -0.1519 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6917   -0.7533    0.5931 C   0  0  2  0  0  0  0  0  0  0  0  0
   -3.0114   -1.5578    1.7232 O   0  0  0  0  0  0  0  0  0  0  0  0
   -6.7978    2.2977    1.8647 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.6076    2.8261    0.1063 H   0  0  0  0  0  0  0  0  0  0  0  0
   -6.1242    3.9029    1.4970 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.5772    2.4962    1.6222 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4743    0.8882   -0.5894 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.4102    1.1176   -0.9071 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.4727   -1.1024    1.1747 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6319   -2.8330   -0.7233 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.7205   -1.6608   -1.5284 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.5918   -1.9346    0.9664 H   0  0  0  0  0  0  0  0  0  0  0  0
    5.3278    0.2935    1.1110 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.2679    0.8780   -0.9137 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.7141    2.3912    0.2522 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.9962    2.1841   -1.6208 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.3517    2.5864    0.5237 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.7342    1.8508    2.5995 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8114   -1.6560    0.9527 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.7321   -2.0224   -1.8628 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.0711   -0.3361   -2.2376 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.5254   -1.7645   -3.0846 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8482   -2.1281   -2.5331 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9051   -0.3959   -1.1486 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.2421   -2.1339   -0.8644 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9158   -2.5106    1.4910 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  3  4  2  0
  3  5  1  0
  5  6  2  0
  6  7  1  0
  7  8  1  0
  8  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 12 13  1  0
 13 14  1  0
 12 15  1  0
 15 16  1  0
 15 17  1  0
 17 18  1  0
 17 19  1  0
 19 20  1  0
  8 21  1  0
 21 22  1  0
 22 23  1  6
 22 24  1  0
 24 25  1  0
 25 26  1  0
 26 27  1  0
 26 28  1  0
 28 29  1  1
 28  5  1  0
 19 10  1  0
 28 21  1  0
 25 22  1  0
  1 30  1  0
  1 31  1  0
  1 32  1  0
  6 33  1  0
  8 34  1  6
 10 35  1  6
 12 36  1  1
 13 37  1  0
 13 38  1  0
 14 39  1  0
 15 40  1  1
 16 41  1  0
 17 42  1  1
 18 43  1  0
 19 44  1  1
 20 45  1  0
 21 46  1  1
 23 47  1  0
 23 48  1  0
 23 49  1  0
 25 50  1  6
 26 51  1  6
 27 52  1  0
 29 53  1  0
M  END


  Mrv1652304282205002D          

 29 32  0  0  1  0            999 V2000
    0.7327   -1.5964    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.5364   -0.7950    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.2863   -0.7341    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.5986   -1.4977    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.0312   -2.0306    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.0298   -2.8534    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.1038   -0.8455    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3117    0.0906    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1323   -0.2244    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.9243   -0.4551    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.1206   -1.2564    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5248   -1.8271    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.7210   -2.6284    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.1252   -3.1990    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.5131   -2.8591    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.7093   -3.6604    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.9360    0.5769    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.5318    1.1475    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.3356    1.9488    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.9314    2.5194    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.7235    2.2887    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.9198    1.4874    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.3239    0.9168    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.5202    0.1155    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.7119    1.2567    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.3194    2.8594    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7352    3.3208    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.3310    3.8914    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.8441   -2.4138    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  1  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  1  5  1  0  0  0  0
  5  6  1  6  0  0  0
  4  7  1  6  0  0  0
  3  7  1  0  0  0  0
  3  8  1  1  0  0  0
  2  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
 11 12  2  0  0  0  0
  1 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  2  0  0  0  0
 13 15  1  0  0  0  0
 15 16  1  0  0  0  0
  9 17  1  6  0  0  0
 18 17  1  6  0  0  0
 18 19  1  0  0  0  0
 19 20  1  0  0  0  0
 20 21  1  0  0  0  0
 21 22  1  0  0  0  0
 22 23  1  0  0  0  0
 18 23  1  0  0  0  0
 23 24  1  6  0  0  0
 22 25  1  1  0  0  0
 21 26  1  1  0  0  0
 20 27  1  1  0  0  0
 27 28  1  0  0  0  0
  1 29  1  6  0  0  0
M  END
> <DATABASE_ID>
NP0057586

> <DATABASE_NAME>
NP-MRD

> <SMILES>
COC(=O)C1=CO[C@@H](O[C@@H]2O[C@@H](CO)[C@@H](O)[C@@H](O)[C@@H]2O)[C@@H]2[C@@]3(C)O[C@H]3[C@@H](O)[C@]12O

> <INCHI_IDENTIFIER>
InChI=1S/C17H24O12/c1-16-10-15(28-14-9(21)8(20)7(19)6(3-18)27-14)26-4-5(13(23)25-2)17(10,24)11(22)12(16)29-16/h4,6-12,14-15,18-22,24H,3H2,1-2H3/t6-,7+,8+,9-,10+,11+,12-,14-,15-,16+,17-/m0/s1

> <INCHI_KEY>
XZVXEPPPQBLGMQ-LHYBNYTGSA-N

> <FORMULA>
C17H24O12

> <MOLECULAR_WEIGHT>
420.367

> <EXACT_MASS>
420.126776213

> <JCHEM_ACCEPTOR_COUNT>
11

> <JCHEM_ATOM_COUNT>
53

> <JCHEM_AVERAGE_POLARIZABILITY>
38.66576381344138

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
6

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0^{2,4}]dec-7-ene-7-carboxylate

> <ALOGPS_LOGP>
-1.61

> <JCHEM_LOGP>
-3.8448984330000013

> <ALOGPS_LOGS>
-0.63

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
4

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
12.479642112136698

> <JCHEM_PKA_STRONGEST_ACIDIC>
11.934263565790657

> <JCHEM_PKA_STRONGEST_BASIC>
-2.981084760235243

> <JCHEM_POLAR_SURFACE_AREA>
187.89999999999998

> <JCHEM_REFRACTIVITY>
87.55919999999999

> <JCHEM_ROTATABLE_BOND_COUNT>
5

> <JCHEM_RULE_OF_FIVE>
0

> <ALOGPS_SOLUBILITY>
9.89e+01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0^{2,4}]dec-7-ene-7-carboxylate

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 28-APR-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   28-APR-22         0                                  
HETATM    1  C   UNK     0       1.368  -2.980   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0       1.001  -1.484   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -0.534  -1.370   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -1.117  -2.796   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0       0.058  -3.790   0.000  0.00  0.00           C+0
HETATM    6  O   UNK     0      -0.056  -5.326   0.000  0.00  0.00           O+0
HETATM    7  O   UNK     0      -2.060  -1.578   0.000  0.00  0.00           O+0
HETATM    8  C   UNK     0      -0.582   0.169   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.114  -0.419   0.000  0.00  0.00           C+0
HETATM   10  O   UNK     0       3.592  -0.850   0.000  0.00  0.00           O+0
HETATM   11  C   UNK     0       3.958  -2.345   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       2.846  -3.411   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       3.213  -4.906   0.000  0.00  0.00           C+0
HETATM   14  O   UNK     0       2.100  -5.971   0.000  0.00  0.00           O+0
HETATM   15  O   UNK     0       4.691  -5.337   0.000  0.00  0.00           O+0
HETATM   16  C   UNK     0       5.057  -6.833   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0       1.747   1.077   0.000  0.00  0.00           O+0
HETATM   18  C   UNK     0       2.859   2.142   0.000  0.00  0.00           C+0
HETATM   19  O   UNK     0       2.493   3.638   0.000  0.00  0.00           O+0
HETATM   20  C   UNK     0       3.605   4.703   0.000  0.00  0.00           C+0
HETATM   21  C   UNK     0       5.084   4.272   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0       5.450   2.777   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0       4.338   1.711   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0       4.704   0.216   0.000  0.00  0.00           O+0
HETATM   25  O   UNK     0       6.929   2.346   0.000  0.00  0.00           O+0
HETATM   26  O   UNK     0       6.196   5.337   0.000  0.00  0.00           O+0
HETATM   27  C   UNK     0       3.239   6.199   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0       4.351   7.264   0.000  0.00  0.00           O+0
HETATM   29  O   UNK     0       1.576  -4.506   0.000  0.00  0.00           O+0
CONECT    1    2    5   12   29                                             
CONECT    2    1    3    9                                                  
CONECT    3    2    4    7    8                                             
CONECT    4    3    5    7                                                  
CONECT    5    4    1    6                                                  
CONECT    6    5                                                            
CONECT    7    4    3                                                       
CONECT    8    3                                                            
CONECT    9    2   10   17                                                  
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11    1   13                                                  
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13   16                                                       
CONECT   16   15                                                            
CONECT   17    9   18                                                       
CONECT   18   17   19   23                                                  
CONECT   19   18   20                                                       
CONECT   20   19   21   27                                                  
CONECT   21   20   22   26                                                  
CONECT   22   21   23   25                                                  
CONECT   23   22   18   24                                                  
CONECT   24   23                                                            
CONECT   25   22                                                            
CONECT   26   21                                                            
CONECT   27   20   28                                                       
CONECT   28   27                                                            
CONECT   29    1                                                            
MASTER        0    0    0    0    0    0    0    0   29    0   64    0
END

View in JSmol

Synonyms

Value	Source
Methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0,]dec-7-ene-7-carboxylic acid	Generator

Chemical Formula

C₁₇H₂₄O₁₂

Average Mass

420.3670 Da

Monoisotopic Mass

420.12678 Da

IUPAC Name

methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0^{2,4}]dec-7-ene-7-carboxylate

Traditional Name

methyl (1S,2R,4S,5R,6R,10S)-5,6-dihydroxy-2-methyl-10-{[(2S,3S,4R,5S,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-3,9-dioxatricyclo[4.4.0.0^{2,4}]dec-7-ene-7-carboxylate

CAS Registry Number

Not Available

SMILES

COC(=O)C1=CO[C@@H](O[C@@H]2O[C@@H](CO)[C@@H](O)[C@@H](O)[C@@H]2O)[C@@H]2[C@@]3(C)O[C@H]3[C@@H](O)[C@]12O

InChI Identifier

InChI=1S/C17H24O12/c1-16-10-15(28-14-9(21)8(20)7(19)6(3-18)27-14)26-4-5(13(23)25-2)17(10,24)11(22)12(16)29-16/h4,6-12,14-15,18-22,24H,3H2,1-2H3/t6-,7+,8+,9-,10+,11+,12-,14-,15-,16+,17-/m0/s1

InChI Key

XZVXEPPPQBLGMQ-LHYBNYTGSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Lamium garganicum	Plant	KNApSAcK
Pedicularis muscicola	Plant	KNApSAcK
Phlomis mongolica	Plant	KNApSAcK
Phlomis muscicola	Plant	KNApSAcK
Sesamum angolense	Plant	KNApSAcK

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as o-glycosyl compounds. These are glycoside in which a sugar group is bonded through one carbon to another group via a O-glycosidic bond.

Kingdom

Organic compounds

Super Class

Organic oxygen compounds

Class

Organooxygen compounds

Sub Class

Carbohydrates and carbohydrate conjugates

Direct Parent

O-glycosyl compounds

Alternative Parents

Substituents

Hexose monosaccharide
O-glycosyl compound
Oxane
Monosaccharide
Vinylogous ester
Alpha,beta-unsaturated carboxylic ester
Enoate ester
Methyl ester
Tertiary alcohol
Cyclic alcohol
Secondary alcohol
Carboxylic acid ester
Oxacycle
Organoheterocyclic compound
Polyol
Monocarboxylic acid or derivatives
Ether
Oxirane
Dialkyl ether
Carboxylic acid derivative
Acetal
Organic oxide
Hydrocarbon derivative
Primary alcohol
Carbonyl group
Alcohol
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	-1.6	ALOGPS
logP	-3.8	ChemAxon
logS	-0.63	ALOGPS
pKa (Strongest Acidic)	11.93	ChemAxon
pKa (Strongest Basic)	-3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	11	ChemAxon
Hydrogen Donor Count	6	ChemAxon
Polar Surface Area	187.9 Å²	ChemAxon
Rotatable Bond Count	5	ChemAxon
Refractivity	87.56 m³·mol⁻¹	ChemAxon
Polarizability	38.67 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

162873204

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

Not Available

Showing NP-Card for Sesamoside (NP0057586)

MOL for NP0057586 (Sesamoside)

3D MOL for NP0057586 (Sesamoside)

3D SDF for NP0057586 (Sesamoside)

3D-SDF for NP0057586 (Sesamoside)

PDB for NP0057586 (Sesamoside)

3D PDB for NP0057586 (Sesamoside)

SMILES for NP0057586 (Sesamoside)

INCHI for NP0057586 (Sesamoside)

Structure for NP0057586 (Sesamoside)

3D Structure for NP0057586 (Sesamoside)