Record Information |
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Version | 1.0 |
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Created at | 2021-06-21 00:59:32 UTC |
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Updated at | 2021-06-30 00:19:26 UTC |
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NP-MRD ID | NP0043644 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | klymollin Q |
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Provided By | JEOL Database![JEOL Logo](/attributions/jeol_logo.png) |
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Description | (1R,2R,3R,5S,7R,8R,10S,11S,14R)-14-(acetyloxy)-5,10-dihydroxy-10,14-dimethyl-6-methylidene-3-(propan-2-yl)-15-oxatricyclo[6.6.1.0²,⁷]Pentadecan-11-yl acetate belongs to the class of organic compounds known as eunicellane and asbestinane diterpenoids. These are diterpenoids with a structure based on either the eunicellane (5,14-cyclocembrane) or the asbestinane skeleton. klymollin Q is found in Klyxum molle. It was first documented in 2013 (Lin, M. -C., et al.). Based on a literature review very few articles have been published on (1R,2R,3R,5S,7R,8R,10S,11S,14R)-14-(acetyloxy)-5,10-dihydroxy-10,14-dimethyl-6-methylidene-3-(propan-2-yl)-15-oxatricyclo[6.6.1.0²,⁷]Pentadecan-11-yl acetate. |
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Structure | [H]O[C@]1([H])C(=C([H])[H])[C@]2([H])[C@]3([H])O[C@]([H])([C@]2([H])[C@]([H])(C1([H])[H])C([H])(C([H])([H])[H])C([H])([H])[H])[C@@](OC(=O)C([H])([H])[H])(C([H])([H])[H])C([H])([H])C([H])([H])[C@]([H])(OC(=O)C([H])([H])[H])[C@](O[H])(C([H])([H])[H])C3([H])[H] InChI=1S/C24H38O7/c1-12(2)16-10-17(27)13(3)20-18-11-23(6,28)19(29-14(4)25)8-9-24(7,31-15(5)26)22(30-18)21(16)20/h12,16-22,27-28H,3,8-11H2,1-2,4-7H3/t16-,17+,18-,19+,20-,21-,22-,23+,24-/m1/s1 |
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Synonyms | Value | Source |
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(1R,2R,3R,5S,7R,8R,10S,11S,14R)-14-(Acetyloxy)-5,10-dihydroxy-10,14-dimethyl-6-methylidene-3-(propan-2-yl)-15-oxatricyclo[6.6.1.0,]pentadecan-11-yl acetic acid | Generator |
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Chemical Formula | C24H38O7 |
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Average Mass | 438.5610 Da |
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Monoisotopic Mass | 438.26175 Da |
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IUPAC Name | (1R,2R,3R,5S,7R,8R,10S,11S,14R)-14-(acetyloxy)-5,10-dihydroxy-10,14-dimethyl-6-methylidene-3-(propan-2-yl)-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-11-yl acetate |
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Traditional Name | (1R,2R,3R,5S,7R,8R,10S,11S,14R)-14-(acetyloxy)-5,10-dihydroxy-3-isopropyl-10,14-dimethyl-6-methylidene-15-oxatricyclo[6.6.1.0^{2,7}]pentadecan-11-yl acetate |
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CAS Registry Number | Not Available |
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SMILES | [H]O[C@]1([H])C(=C([H])[H])[C@]2([H])[C@]3([H])O[C@]([H])([C@]2([H])[C@]([H])(C1([H])[H])C([H])(C([H])([H])[H])C([H])([H])[H])[C@@](OC(=O)C([H])([H])[H])(C([H])([H])[H])C([H])([H])C([H])([H])[C@]([H])(OC(=O)C([H])([H])[H])[C@](O[H])(C([H])([H])[H])C3([H])[H] |
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InChI Identifier | InChI=1S/C24H38O7/c1-12(2)16-10-17(27)13(3)20-18-11-23(6,28)19(29-14(4)25)8-9-24(7,31-15(5)26)22(30-18)21(16)20/h12,16-22,27-28H,3,8-11H2,1-2,4-7H3/t16-,17+,18-,19+,20-,21-,22-,23+,24-/m1/s1 |
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InChI Key | CTJSBYKSXKTLNF-RKWRRXNDSA-N |
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Experimental Spectra |
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| Spectrum Type | Description | Depositor Email | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 500 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 100 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 200 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 300 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 400 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 600 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 700 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 800 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 900 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 1000 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, CDCl3, simulated) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Predicted Spectra |
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| Not Available | Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | Species Name | Source | Reference |
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Klyxum molle | JEOL database | - Lin, M. -C., et al, J. Nat. Prod. 76, 1661 (2013)
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as eunicellane and asbestinane diterpenoids. These are diterpenoids with a structure based on either the eunicellane (5,14-cyclocembrane) or the asbestinane skeleton. |
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Kingdom | Organic compounds |
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Super Class | Lipids and lipid-like molecules |
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Class | Prenol lipids |
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Sub Class | Diterpenoids |
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Direct Parent | Eunicellane and asbestinane diterpenoids |
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Alternative Parents | |
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Substituents | - Cladiellane diterpenoid
- Eunicellane-type diterpenoid
- Dicarboxylic acid or derivatives
- Cyclic alcohol
- Tetrahydrofuran
- Tertiary alcohol
- Carboxylic acid ester
- Secondary alcohol
- Carboxylic acid derivative
- Dialkyl ether
- Ether
- Oxacycle
- Organoheterocyclic compound
- Organic oxide
- Hydrocarbon derivative
- Carbonyl group
- Alcohol
- Organooxygen compound
- Organic oxygen compound
- Aliphatic heteropolycyclic compound
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Molecular Framework | Aliphatic heteropolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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