Record Information |
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Version | 2.0 |
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Created at | 2021-01-05 22:49:12 UTC |
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Updated at | 2021-07-15 17:14:33 UTC |
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NP-MRD ID | NP0013465 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | (+)-cochlearol A |
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Provided By | NPAtlas |
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Description | (1S,10S,13R)-3,6-dihydroxy-8-oxo-14,16-dioxatetracyclo[11.2.1.0¹,¹⁰.0²,⁷]Hexadeca-2,4,6-triene-10-carboxylic acid belongs to the class of organic compounds known as naphthopyrans. Naphthopyrans are compounds containing a pyran ring fused to a naphthalene moiety. Furan is a 6 membered-ring non-aromatic ring with five carbon and one oxygen atoms. Naphthalene is a polycyclic aromatic hydrocarbon made up of two fused benzene rings. (+)-cochlearol A is found in Ganoderma. It was first documented in 2012 (PMID: 34383397). Based on a literature review very few articles have been published on (1S,10S,13R)-3,6-dihydroxy-8-oxo-14,16-dioxatetracyclo[11.2.1.0¹,¹⁰.0²,⁷]Hexadeca-2,4,6-triene-10-carboxylic acid (PMID: 25402560) (PMID: 34383398) (PMID: 33749282) (PMID: 31433660). |
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Structure | [H]OC(=O)[C@@]12C([H])([H])C(=O)C3=C(O[H])C([H])=C([H])C(O[H])=C3[C@]11O[C@@]([H])(OC1([H])[H])C([H])([H])C2([H])[H] InChI=1S/C15H14O7/c16-7-1-2-8(17)12-11(7)9(18)5-14(13(19)20)4-3-10-21-6-15(12,14)22-10/h1-2,10,16-17H,3-6H2,(H,19,20)/t10-,14-,15+/m1/s1 |
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Synonyms | Value | Source |
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(1S,10S,13R)-3,6-Dihydroxy-8-oxo-14,16-dioxatetracyclo[11.2.1.0,.0,]hexadeca-2,4,6-triene-10-carboxylate | Generator |
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Chemical Formula | C15H14O7 |
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Average Mass | 306.2700 Da |
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Monoisotopic Mass | 306.07395 Da |
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IUPAC Name | (1S,10S,13R)-3,6-dihydroxy-8-oxo-14,16-dioxatetracyclo[11.2.1.0^{1,10}.0^{2,7}]hexadeca-2,4,6-triene-10-carboxylic acid |
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Traditional Name | (1S,10S,13R)-3,6-dihydroxy-8-oxo-14,16-dioxatetracyclo[11.2.1.0^{1,10}.0^{2,7}]hexadeca-2,4,6-triene-10-carboxylic acid |
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CAS Registry Number | Not Available |
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SMILES | OC(=O)[C@]12CC[C@@H]3OC[C@]1(O3)C1=C(O)C=CC(O)=C1C(=O)C2 |
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InChI Identifier | InChI=1S/C15H14O7/c16-7-1-2-8(17)12-11(7)9(18)5-14(13(19)20)4-3-10-21-6-15(12,14)22-10/h1-2,10,16-17H,3-6H2,(H,19,20)/t10-,14-,15+/m1/s1 |
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InChI Key | APQUUNCMRUQJLX-KMUNFCNLSA-N |
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Experimental Spectra |
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| Not Available | Predicted Spectra |
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| Spectrum Type | Description | Depositor ID | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 13C NMR Spectrum (1D, 25 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 100 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 252 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 1000 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 50 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 200 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 75 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 300 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 101 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 400 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 126 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 500 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 151 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 600 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 176 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 700 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 201 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 800 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 13C NMR Spectrum (1D, 226 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 1D NMR | 1H NMR Spectrum (1D, 900 MHz, D2O, predicted) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as naphthopyrans. Naphthopyrans are compounds containing a pyran ring fused to a naphthalene moiety. Furan is a 6 membered-ring non-aromatic ring with five carbon and one oxygen atoms. Naphthalene is a polycyclic aromatic hydrocarbon made up of two fused benzene rings. |
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Kingdom | Organic compounds |
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Super Class | Organoheterocyclic compounds |
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Class | Naphthopyrans |
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Sub Class | Not Available |
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Direct Parent | Naphthopyrans |
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Alternative Parents | |
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Substituents | - Naphthopyran
- 2-naphthalenecarboxylic acid or derivatives
- 2-naphthalenecarboxylic acid
- Tetralin
- Naphthalene
- Aryl alkyl ketone
- Aryl ketone
- 1-hydroxy-2-unsubstituted benzenoid
- Oxepane
- Benzenoid
- Pyran
- Oxane
- Vinylogous acid
- Meta-dioxolane
- Ketone
- Oxacycle
- Monocarboxylic acid or derivatives
- Carboxylic acid
- Carboxylic acid derivative
- Acetal
- Organic oxygen compound
- Organic oxide
- Hydrocarbon derivative
- Organooxygen compound
- Carbonyl group
- Aromatic heteropolycyclic compound
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Molecular Framework | Aromatic heteropolycyclic compounds |
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External Descriptors | Not Available |
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Physical Properties |
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State | Not Available |
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Experimental Properties | Property | Value | Reference |
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Melting Point | Not Available | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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