NP-MRD: Showing NP-Card for Oidiolactone C (NP0001807)

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Record Information

Version

1.0

Created at

2020-10-21 16:38:32 UTC

Updated at

2021-07-15 16:45:19 UTC

NP-MRD ID

NP0001807

Secondary Accession Numbers

None

Natural Product Identification

Common Name

Oidiolactone C

Provided By

NPAtlas

Description

(1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0²,⁴.0⁴,⁹.0¹⁴,¹⁷]Heptadec-8-ene-7,15-dione belongs to the class of organic compounds known as naphthopyrans. Naphthopyrans are compounds containing a pyran ring fused to a naphthalene moiety. Furan is a 6 membered-ring non-aromatic ring with five carbon and one oxygen atoms. Naphthalene is a polycyclic aromatic hydrocarbon made up of two fused benzene rings. Oidiolactone C is found in Oidiodendron and Oidiodendron truncata. It was first documented in 1999 (PMID: 10514300). Based on a literature review very few articles have been published on (1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0²,⁴.0⁴,⁹.0¹⁴,¹⁷]Heptadec-8-ene-7,15-dione.

Structure

MOL 3D MOL SDF 3D SDF PDB SMILES InChI


  Mrv1652306242117443D          

 39 43  0  0  0  0            999 V2000
   -2.9091    1.2821    0.8628 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0829    0.4209   -0.0938 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.6565   -0.9284   -0.2449 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.7519   -2.0790   -0.3732 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.3775   -1.9595    0.2015 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.1899   -0.6041   -0.1668 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2099   -0.4931   -1.6817 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -0.4035    0.2506 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4285   -1.4029    0.3626 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8243   -1.2168    0.7726 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6063   -2.1890    0.8743 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2409    0.1021    1.0454 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5469    1.1091    0.3152 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.0415    0.9709    0.5605 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5649    1.5961    1.7185 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1952    2.0558    0.4025 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2825    1.8349    0.2196 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7886    2.0629   -1.0504 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8772    1.2071   -1.3068 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4706    1.2217   -2.4171 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6746    0.4030    0.5064 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.9026    2.3493    0.5600 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4609    1.2626    1.8978 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9292    0.8928    0.9611 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3540   -0.9253   -1.1271 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3559   -1.0972    0.6279 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7163   -2.4343   -1.4469 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2194   -2.9704    0.1475 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4204   -2.0706    1.2898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2086   -2.8069   -0.2538 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6942   -0.8360   -2.1753 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5752    0.4705   -2.0395 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0089   -1.2342   -1.9961 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1502   -2.4270    0.1605 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7248    1.0110   -0.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8285    2.1153    0.6768 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5366    3.0685    0.2055 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8308    2.4782    0.9401 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7127    0.1635    1.5766 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  6  0  0  0
  6  8  1  0  0  0  0
  8  9  2  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  1  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 17 21  1  0  0  0  0
 19  2  1  0  0  0  0
 21  2  1  0  0  0  0
 21  6  1  0  0  0  0
 14  8  1  0  0  0  0
 16 14  1  0  0  0  0
  1 22  1  0  0  0  0
  1 23  1  0  0  0  0
  1 24  1  0  0  0  0
  3 25  1  0  0  0  0
  3 26  1  0  0  0  0
  4 27  1  0  0  0  0
  4 28  1  0  0  0  0
  5 29  1  0  0  0  0
  5 30  1  0  0  0  0
  7 31  1  0  0  0  0
  7 32  1  0  0  0  0
  7 33  1  0  0  0  0
  9 34  1  0  0  0  0
 13 35  1  0  0  0  0
 13 36  1  0  0  0  0
 16 37  1  6  0  0  0
 17 38  1  1  0  0  0
 21 39  1  1  0  0  0
M  END

     RDKit          3D

 39 43  0  0  0  0  0  0  0  0999 V2000
   -2.9091    1.2821    0.8628 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0829    0.4209   -0.0938 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.6565   -0.9284   -0.2449 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7519   -2.0790   -0.3732 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3775   -1.9595    0.2015 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1899   -0.6041   -0.1668 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2099   -0.4931   -1.6817 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -0.4035    0.2506 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4285   -1.4029    0.3626 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8243   -1.2168    0.7726 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6063   -2.1890    0.8743 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2409    0.1021    1.0454 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5469    1.1091    0.3152 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0415    0.9709    0.5605 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5649    1.5961    1.7185 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1952    2.0558    0.4025 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2825    1.8349    0.2196 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7886    2.0629   -1.0504 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8772    1.2071   -1.3068 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4706    1.2217   -2.4171 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6746    0.4030    0.5064 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.9026    2.3493    0.5600 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4609    1.2626    1.8978 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9292    0.8928    0.9611 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3540   -0.9253   -1.1271 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3559   -1.0972    0.6279 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7163   -2.4343   -1.4469 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2194   -2.9704    0.1475 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4204   -2.0706    1.2898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2086   -2.8069   -0.2538 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6942   -0.8360   -2.1753 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5752    0.4705   -2.0395 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0089   -1.2342   -1.9961 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1502   -2.4270    0.1605 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7248    1.0110   -0.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8285    2.1153    0.6768 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5366    3.0685    0.2055 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8308    2.4782    0.9401 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7127    0.1635    1.5766 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1
  2  3  1  0
  3  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  6
  6  8  1  0
  8  9  2  0
  9 10  1  0
 10 11  2  0
 10 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  1
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  2  0
 17 21  1  0
 19  2  1  0
 21  2  1  0
 21  6  1  0
 14  8  1  0
 16 14  1  0
  1 22  1  0
  1 23  1  0
  1 24  1  0
  3 25  1  0
  3 26  1  0
  4 27  1  0
  4 28  1  0
  5 29  1  0
  5 30  1  0
  7 31  1  0
  7 32  1  0
  7 33  1  0
  9 34  1  0
 13 35  1  0
 13 36  1  0
 16 37  1  6
 17 38  1  1
 21 39  1  1
M  END


  Mrv1652306242117443D          

 39 43  0  0  0  0            999 V2000
   -2.9091    1.2821    0.8628 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0829    0.4209   -0.0938 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.6565   -0.9284   -0.2449 C   0  0  2  0  0  0  0  0  0  0  0  0
   -1.7519   -2.0790   -0.3732 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.3775   -1.9595    0.2015 C   0  0  1  0  0  0  0  0  0  0  0  0
    0.1899   -0.6041   -0.1668 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2099   -0.4931   -1.6817 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -0.4035    0.2506 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4285   -1.4029    0.3626 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8243   -1.2168    0.7726 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6063   -2.1890    0.8743 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2409    0.1021    1.0454 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5469    1.1091    0.3152 C   0  0  2  0  0  0  0  0  0  0  0  0
    2.0415    0.9709    0.5605 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5649    1.5961    1.7185 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1952    2.0558    0.4025 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2825    1.8349    0.2196 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7886    2.0629   -1.0504 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8772    1.2071   -1.3068 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4706    1.2217   -2.4171 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6746    0.4030    0.5064 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.9026    2.3493    0.5600 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4609    1.2626    1.8978 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9292    0.8928    0.9611 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3540   -0.9253   -1.1271 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3559   -1.0972    0.6279 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7163   -2.4343   -1.4469 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2194   -2.9704    0.1475 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4204   -2.0706    1.2898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2086   -2.8069   -0.2538 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6942   -0.8360   -2.1753 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5752    0.4705   -2.0395 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0089   -1.2342   -1.9961 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1502   -2.4270    0.1605 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7248    1.0110   -0.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8285    2.1153    0.6768 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5366    3.0685    0.2055 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8308    2.4782    0.9401 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7127    0.1635    1.5766 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  6  0  0  0
  6  8  1  0  0  0  0
  8  9  2  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 10 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  1  0  0  0
 15 16  1  0  0  0  0
 16 17  1  0  0  0  0
 17 18  1  0  0  0  0
 18 19  1  0  0  0  0
 19 20  2  0  0  0  0
 17 21  1  0  0  0  0
 19  2  1  0  0  0  0
 21  2  1  0  0  0  0
 21  6  1  0  0  0  0
 14  8  1  0  0  0  0
 16 14  1  0  0  0  0
  1 22  1  0  0  0  0
  1 23  1  0  0  0  0
  1 24  1  0  0  0  0
  3 25  1  0  0  0  0
  3 26  1  0  0  0  0
  4 27  1  0  0  0  0
  4 28  1  0  0  0  0
  5 29  1  0  0  0  0
  5 30  1  0  0  0  0
  7 31  1  0  0  0  0
  7 32  1  0  0  0  0
  7 33  1  0  0  0  0
  9 34  1  0  0  0  0
 13 35  1  0  0  0  0
 13 36  1  0  0  0  0
 16 37  1  6  0  0  0
 17 38  1  1  0  0  0
 21 39  1  1  0  0  0
M  END
> <DATABASE_ID>
NP0001807

> <DATABASE_NAME>
NP-MRD

> <SMILES>
[H]C1=C2[C@@]3(O[C@]3([H])[C@@]3([H])OC(=O)[C@@]4(C([H])([H])[H])C([H])([H])C([H])([H])C([H])([H])[C@@]2(C([H])([H])[H])[C@@]34[H])C([H])([H])OC1=O

> <INCHI_IDENTIFIER>
InChI=1S/C16H18O5/c1-14-4-3-5-15(2)11(14)10(20-13(15)18)12-16(21-12)7-19-9(17)6-8(14)16/h6,10-12H,3-5,7H2,1-2H3/t10-,11+,12+,14+,15-,16-/m0/s1

> <INCHI_KEY>
AAHPRFOQTYCLDM-DIEKJCKJSA-N

> <FORMULA>
C16H18O5

> <MOLECULAR_WEIGHT>
290.315

> <EXACT_MASS>
290.11542368

> <JCHEM_ACCEPTOR_COUNT>
3

> <JCHEM_ATOM_COUNT>
39

> <JCHEM_AVERAGE_POLARIZABILITY>
28.67604035161694

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
0

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0^{2,4}.0^{4,9}.0^{14,17}]heptadec-8-ene-7,15-dione

> <ALOGPS_LOGP>
2.04

> <JCHEM_LOGP>
1.7661605123333324

> <ALOGPS_LOGS>
-2.65

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
5

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA_STRONGEST_BASIC>
-4.293240929869904

> <JCHEM_POLAR_SURFACE_AREA>
65.13

> <JCHEM_REFRACTIVITY>
70.80960000000002

> <JCHEM_ROTATABLE_BOND_COUNT>
0

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
6.49e-01 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0^{2,4}.0^{4,9}.0^{14,17}]heptadec-8-ene-7,15-dione

> <JCHEM_VEBER_RULE>
0

$$$$

     RDKit          3D

 39 43  0  0  0  0  0  0  0  0999 V2000
   -2.9091    1.2821    0.8628 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0829    0.4209   -0.0938 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.6565   -0.9284   -0.2449 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7519   -2.0790   -0.3732 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3775   -1.9595    0.2015 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1899   -0.6041   -0.1668 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2099   -0.4931   -1.6817 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -0.4035    0.2506 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4285   -1.4029    0.3626 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8243   -1.2168    0.7726 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6063   -2.1890    0.8743 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2409    0.1021    1.0454 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5469    1.1091    0.3152 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0415    0.9709    0.5605 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5649    1.5961    1.7185 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1952    2.0558    0.4025 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2825    1.8349    0.2196 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7886    2.0629   -1.0504 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8772    1.2071   -1.3068 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4706    1.2217   -2.4171 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6746    0.4030    0.5064 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.9026    2.3493    0.5600 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4609    1.2626    1.8978 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9292    0.8928    0.9611 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3540   -0.9253   -1.1271 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3559   -1.0972    0.6279 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7163   -2.4343   -1.4469 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2194   -2.9704    0.1475 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4204   -2.0706    1.2898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2086   -2.8069   -0.2538 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6942   -0.8360   -2.1753 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5752    0.4705   -2.0395 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0089   -1.2342   -1.9961 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1502   -2.4270    0.1605 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7248    1.0110   -0.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8285    2.1153    0.6768 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5366    3.0685    0.2055 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8308    2.4782    0.9401 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7127    0.1635    1.5766 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1
  2  3  1  0
  3  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  6
  6  8  1  0
  8  9  2  0
  9 10  1  0
 10 11  2  0
 10 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  1
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  2  0
 17 21  1  0
 19  2  1  0
 21  2  1  0
 21  6  1  0
 14  8  1  0
 16 14  1  0
  1 22  1  0
  1 23  1  0
  1 24  1  0
  3 25  1  0
  3 26  1  0
  4 27  1  0
  4 28  1  0
  5 29  1  0
  5 30  1  0
  7 31  1  0
  7 32  1  0
  7 33  1  0
  9 34  1  0
 13 35  1  0
 13 36  1  0
 16 37  1  6
 17 38  1  1
 21 39  1  1
M  END

HEADER    PROTEIN                                 24-JUN-21   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   24-JUN-21         0                                  
HETATM    1  C   UNK     0      -2.909   1.282   0.863  0.00  0.00           C+0
HETATM    2  C   UNK     0      -2.083   0.421  -0.094  0.00  0.00           C+0
HETATM    3  C   UNK     0      -2.656  -0.928  -0.245  0.00  0.00           C+0
HETATM    4  C   UNK     0      -1.752  -2.079  -0.373  0.00  0.00           C+0
HETATM    5  C   UNK     0      -0.378  -1.960   0.202  0.00  0.00           C+0
HETATM    6  C   UNK     0       0.190  -0.604  -0.167  0.00  0.00           C+0
HETATM    7  C   UNK     0       0.210  -0.493  -1.682  0.00  0.00           C+0
HETATM    8  C   UNK     0       1.587  -0.404   0.251  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.429  -1.403   0.363  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.824  -1.217   0.773  0.00  0.00           C+0
HETATM   11  O   UNK     0       4.606  -2.189   0.874  0.00  0.00           O+0
HETATM   12  O   UNK     0       4.241   0.102   1.045  0.00  0.00           O+0
HETATM   13  C   UNK     0       3.547   1.109   0.315  0.00  0.00           C+0
HETATM   14  C   UNK     0       2.042   0.971   0.561  0.00  0.00           C+0
HETATM   15  O   UNK     0       1.565   1.596   1.718  0.00  0.00           O+0
HETATM   16  C   UNK     0       1.195   2.056   0.403  0.00  0.00           C+0
HETATM   17  C   UNK     0      -0.283   1.835   0.220  0.00  0.00           C+0
HETATM   18  O   UNK     0      -0.789   2.063  -1.050  0.00  0.00           O+0
HETATM   19  C   UNK     0      -1.877   1.207  -1.307  0.00  0.00           C+0
HETATM   20  O   UNK     0      -2.471   1.222  -2.417  0.00  0.00           O+0
HETATM   21  C   UNK     0      -0.675   0.403   0.506  0.00  0.00           C+0
HETATM   22  H   UNK     0      -2.903   2.349   0.560  0.00  0.00           H+0
HETATM   23  H   UNK     0      -2.461   1.263   1.898  0.00  0.00           H+0
HETATM   24  H   UNK     0      -3.929   0.893   0.961  0.00  0.00           H+0
HETATM   25  H   UNK     0      -3.354  -0.925  -1.127  0.00  0.00           H+0
HETATM   26  H   UNK     0      -3.356  -1.097   0.628  0.00  0.00           H+0
HETATM   27  H   UNK     0      -1.716  -2.434  -1.447  0.00  0.00           H+0
HETATM   28  H   UNK     0      -2.219  -2.970   0.148  0.00  0.00           H+0
HETATM   29  H   UNK     0      -0.420  -2.071   1.290  0.00  0.00           H+0
HETATM   30  H   UNK     0       0.209  -2.807  -0.254  0.00  0.00           H+0
HETATM   31  H   UNK     0      -0.694  -0.836  -2.175  0.00  0.00           H+0
HETATM   32  H   UNK     0       0.575   0.471  -2.039  0.00  0.00           H+0
HETATM   33  H   UNK     0       1.009  -1.234  -1.996  0.00  0.00           H+0
HETATM   34  H   UNK     0       2.150  -2.427   0.161  0.00  0.00           H+0
HETATM   35  H   UNK     0       3.725   1.011  -0.763  0.00  0.00           H+0
HETATM   36  H   UNK     0       3.829   2.115   0.677  0.00  0.00           H+0
HETATM   37  H   UNK     0       1.537   3.068   0.206  0.00  0.00           H+0
HETATM   38  H   UNK     0      -0.831   2.478   0.940  0.00  0.00           H+0
HETATM   39  H   UNK     0      -0.713   0.164   1.577  0.00  0.00           H+0
CONECT    1    2   22   23   24                                             
CONECT    2    1    3   19   21                                             
CONECT    3    2    4   25   26                                             
CONECT    4    3    5   27   28                                             
CONECT    5    4    6   29   30                                             
CONECT    6    5    7    8   21                                             
CONECT    7    6   31   32   33                                             
CONECT    8    6    9   14                                                  
CONECT    9    8   10   34                                                  
CONECT   10    9   11   12                                                  
CONECT   11   10                                                            
CONECT   12   10   13                                                       
CONECT   13   12   14   35   36                                             
CONECT   14   13   15    8   16                                             
CONECT   15   14   16                                                       
CONECT   16   15   17   14   37                                             
CONECT   17   16   18   21   38                                             
CONECT   18   17   19                                                       
CONECT   19   18   20    2                                                  
CONECT   20   19                                                            
CONECT   21   17    2    6   39                                             
CONECT   22    1                                                            
CONECT   23    1                                                            
CONECT   24    1                                                            
CONECT   25    3                                                            
CONECT   26    3                                                            
CONECT   27    4                                                            
CONECT   28    4                                                            
CONECT   29    5                                                            
CONECT   30    5                                                            
CONECT   31    7                                                            
CONECT   32    7                                                            
CONECT   33    7                                                            
CONECT   34    9                                                            
CONECT   35   13                                                            
CONECT   36   13                                                            
CONECT   37   16                                                            
CONECT   38   17                                                            
CONECT   39   21                                                            
MASTER        0    0    0    0    0    0    0    0   39    0   86    0
END

RDKit          3D

39 43  0  0  0  0  0  0  0  0999 V2000
   -2.9091    1.2821    0.8628 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0829    0.4209   -0.0938 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.6565   -0.9284   -0.2449 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7519   -2.0790   -0.3732 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.3775   -1.9595    0.2015 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.1899   -0.6041   -0.1668 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.2099   -0.4931   -1.6817 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.5871   -0.4035    0.2506 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.4285   -1.4029    0.3626 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8243   -1.2168    0.7726 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.6063   -2.1890    0.8743 O   0  0  0  0  0  0  0  0  0  0  0  0
    4.2409    0.1021    1.0454 O   0  0  0  0  0  0  0  0  0  0  0  0
    3.5469    1.1091    0.3152 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0415    0.9709    0.5605 C   0  0  2  0  0  0  0  0  0  0  0  0
    1.5649    1.5961    1.7185 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.1952    2.0558    0.4025 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.2825    1.8349    0.2196 C   0  0  1  0  0  0  0  0  0  0  0  0
   -0.7886    2.0629   -1.0504 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.8772    1.2071   -1.3068 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4706    1.2217   -2.4171 O   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6746    0.4030    0.5064 C   0  0  1  0  0  0  0  0  0  0  0  0
   -2.9026    2.3493    0.5600 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4609    1.2626    1.8978 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.9292    0.8928    0.9611 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3540   -0.9253   -1.1271 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3559   -1.0972    0.6279 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7163   -2.4343   -1.4469 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.2194   -2.9704    0.1475 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.4204   -2.0706    1.2898 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.2086   -2.8069   -0.2538 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6942   -0.8360   -2.1753 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5752    0.4705   -2.0395 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0089   -1.2342   -1.9961 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.1502   -2.4270    0.1605 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.7248    1.0110   -0.7629 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.8285    2.1153    0.6768 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5366    3.0685    0.2055 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8308    2.4782    0.9401 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.7127    0.1635    1.5766 H   0  0  0  0  0  0  0  0  0  0  0  0
  2  1  1  1
  2  3  1  0
  3  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  6
  6  8  1  0
  8  9  2  0
  9 10  1  0
 10 11  2  0
 10 12  1  0
 12 13  1  0
 13 14  1  0
 14 15  1  1
 15 16  1  0
 16 17  1  0
 17 18  1  0
 18 19  1  0
 19 20  2  0
 17 21  1  0
 19  2  1  0
 21  2  1  0
 21  6  1  0
 14  8  1  0
 16 14  1  0
  1 22  1  0
  1 23  1  0
  1 24  1  0
  3 25  1  0
  3 26  1  0
  4 27  1  0
  4 28  1  0
  5 29  1  0
  5 30  1  0
  7 31  1  0
  7 32  1  0
  7 33  1  0
  9 34  1  0
 13 35  1  0
 13 36  1  0
 16 37  1  6
 17 38  1  1
 21 39  1  1
M  END

View in JSmol View NMR Assignments

Synonyms

Not Available

Chemical Formula

C₁₆H₁₈O₅

Average Mass

290.3150 Da

Monoisotopic Mass

290.11542 Da

IUPAC Name

(1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0^{2,4}.0^{4,9}.0^{14,17}]heptadec-8-ene-7,15-dione

Traditional Name

(1S,2R,4R,10S,14S,17R)-10,14-dimethyl-3,6,16-trioxapentacyclo[8.6.1.0^{2,4}.0^{4,9}.0^{14,17}]heptadec-8-ene-7,15-dione

CAS Registry Number

Not Available

SMILES

C[C@]12CCC[C@@]3(C)[C@H]1[C@H](OC2=O)[C@H]1O[C@]11COC(=O)C=C31

InChI Identifier

InChI=1S/C16H18O5/c1-14-4-3-5-15(2)11(14)10(20-13(15)18)12-16(21-12)7-19-9(17)6-8(14)16/h6,10-12H,3-5,7H2,1-2H3/t10-,11+,12+,14+,15-,16-/m0/s1

InChI Key

AAHPRFOQTYCLDM-DIEKJCKJSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Species Name	Source	Reference
Oidiodendron	NPAtlas	10514300
Oidiodendron truncata	Fungi	KNApSAcK

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as naphthopyrans. Naphthopyrans are compounds containing a pyran ring fused to a naphthalene moiety. Furan is a 6 membered-ring non-aromatic ring with five carbon and one oxygen atoms. Naphthalene is a polycyclic aromatic hydrocarbon made up of two fused benzene rings.

Kingdom

Organic compounds

Super Class

Organoheterocyclic compounds

Class

Naphthopyrans

Sub Class

Not Available

Direct Parent

Naphthopyrans

Alternative Parents

Substituents

Naphthopyran
Naphthalene
Dihydropyranone
Oxepane
Dicarboxylic acid or derivatives
Gamma butyrolactone
Pyran
Oxolane
Enoate ester
Alpha,beta-unsaturated carboxylic ester
Lactone
Carboxylic acid ester
Oxacycle
Ether
Oxirane
Dialkyl ether
Carboxylic acid derivative
Organooxygen compound
Hydrocarbon derivative
Organic oxide
Carbonyl group
Organic oxygen compound
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	2.04	ALOGPS
logP	1.77	ChemAxon
logS	-2.6	ALOGPS
pKa (Strongest Basic)	-4.3	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	3	ChemAxon
Hydrogen Donor Count	0	ChemAxon
Polar Surface Area	65.13 Å²	ChemAxon
Rotatable Bond Count	0	ChemAxon
Refractivity	70.81 m³·mol⁻¹	ChemAxon
Polarizability	28.68 Å³	ChemAxon
Number of Rings	5	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

NPAtlas ID

NPA016076

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

8036489

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

9860790

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

John M, Krohn K, Florke U, Aust HJ, Draeger S, Schulz B: Biologically active secondary metabolites from fungi. 12.(1) oidiolactones A-F, labdane diterpene derivatives isolated from oidiodendron truncata J Nat Prod. 1999 Sep;62(9):1218-21. doi: 10.1021/np9804987. [PubMed:10514300 ]

Showing NP-Card for Oidiolactone C (NP0001807)

MOL for NP0001807 (Oidiolactone C)

3D MOL for NP0001807 (Oidiolactone C)

3D SDF for NP0001807 (Oidiolactone C)

3D-SDF for NP0001807 (Oidiolactone C)

PDB for NP0001807 (Oidiolactone C)

3D PDB for NP0001807 (Oidiolactone C)

SMILES for NP0001807 (Oidiolactone C)

INCHI for NP0001807 (Oidiolactone C)

Structure for NP0001807 (Oidiolactone C)

3D Structure for NP0001807 (Oidiolactone C)