Record Information |
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Version | 2.0 |
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Created at | 2005-11-16 15:48:42 UTC |
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Updated at | 2021-06-29 00:46:57 UTC |
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NP-MRD ID | NP0001444 |
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Secondary Accession Numbers | None |
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Natural Product Identification |
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Common Name | L-Sorbose |
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Description | L-Sorbose, also known as L-sorbinose or L-xylo-hexulose, belongs to the class of organic compounds known as monosaccharides. Monosaccharides are compounds containing one carbohydrate unit not glycosidically linked to another such unit, and no set of two or more glycosidically linked carbohydrate units. Monosaccharides have the general formula CnH2nOn. L-Sorbose exists in all living species, ranging from bacteria to humans. The commercial production of vitamin C (ascorbic acid) often begins with sorbose. L-Sorbose (CAS: 87-79-6) Is a ketose belonging to the group of sugars known as monosaccharides. Sorbose has been found to be a metabolite of Ketogulonicigenium (PMID: 15785002 ). |
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Structure | OC[C@@]1(O)OC[C@H](O)[C@@H](O)[C@@H]1O InChI=1S/C6H12O6/c7-2-6(11)5(10)4(9)3(8)1-12-6/h3-5,7-11H,1-2H2/t3-,4+,5-,6+/m0/s1 |
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Synonyms | Value | Source |
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alpha-L-Sorbopyranose | HMDB | Hex-2-ulose | HMDB | L(-) Sorbose for biochemistry | HMDB | L(-)-Sorbose | HMDB | L-(-)-Sorbose | HMDB | L-(-)-Sorbose 99% | HMDB | L-1,3,4,5,6-Pentahydroxyhexan-2-one | HMDB | L-Sorbinose | HMDB | L-Xylo-2-hexulose | HMDB | L-Xylo-hexulose | HMDB | Sorbin | HMDB | Sorbinose | HMDB | Sorbose | HMDB | Xylo-hexulose | HMDB | alpha-L-Xylo-hexopyranos-2-ulose | HMDB | Α-L-xylo-hexopyranos-2-ulose | HMDB | Α-L-sorbopyranose | HMDB | a-L-Sorbopyranose | HMDB |
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Chemical Formula | C6H12O6 |
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Average Mass | 180.1559 Da |
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Monoisotopic Mass | 180.06339 Da |
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IUPAC Name | (2R,3S,4R,5S)-2-(hydroxymethyl)oxane-2,3,4,5-tetrol |
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Traditional Name | α-L-sorbopyranose |
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CAS Registry Number | 87-79-6 |
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SMILES | OC[C@@]1(O)OC[C@H](O)[C@@H](O)[C@@H]1O |
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InChI Identifier | InChI=1S/C6H12O6/c7-2-6(11)5(10)4(9)3(8)1-12-6/h3-5,7-11H,1-2H2/t3-,4+,5-,6+/m0/s1 |
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InChI Key | LKDRXBCSQODPBY-BGPJRJDNSA-N |
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Experimental Spectra |
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| Spectrum Type | Description | Depositor Email | Depositor Organization | Depositor | Deposition Date | View |
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1D NMR | 1H NMR Spectrum (1D, 500 MHz, H2O, experimental) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum | 2D NMR | [1H, 13C]-HSQC NMR Spectrum (2D, 600 MHz, H2O, experimental) | Wishart Lab | Wishart Lab | David Wishart | 2021-06-20 | View Spectrum |
| Predicted Spectra |
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| Not Available | Chemical Shift Submissions |
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| Not Available | Species |
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Species of Origin | |
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Species Where Detected | |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as monosaccharides. Monosaccharides are compounds containing one carbohydrate unit not glycosidically linked to another such unit, and no set of two or more glycosidically linked carbohydrate units. Monosaccharides have the general formula CnH2nOn. |
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Kingdom | Organic compounds |
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Super Class | Organic oxygen compounds |
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Class | Organooxygen compounds |
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Sub Class | Carbohydrates and carbohydrate conjugates |
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Direct Parent | Monosaccharides |
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Alternative Parents | |
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Substituents | - Oxane
- Monosaccharide
- Secondary alcohol
- Hemiacetal
- Oxacycle
- Organoheterocyclic compound
- Polyol
- Hydrocarbon derivative
- Primary alcohol
- Alcohol
- Aliphatic heteromonocyclic compound
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Molecular Framework | Aliphatic heteromonocyclic compounds |
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External Descriptors | |
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Physical Properties |
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State | Solid |
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Experimental Properties | Property | Value | Reference |
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Melting Point | 165 °C | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | 360 mg/mL at 17 °C | Not Available | LogP | Not Available | Not Available |
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Predicted Properties | |
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General References | - Gross KC, Houghton MP, Senterfit LB: Presumptive speciation of Streptococcus bovis and other group D streptococci from human sources by using arginine and pyruvate tests. J Clin Microbiol. 1975 Jan;1(1):54-60. [PubMed:1176592 ]
- Abou El Fadil-Nicol F, Berger F, Descroix-Vagne M, Pansu D: Presence of sorbin in human digestive tract and endocrine digestive tumours. Gut. 2000 Feb;46(2):182-90. [PubMed:10644311 ]
- Sugisawa T, Miyazaki T, Hoshino T: Microbial production of L-ascorbic acid from D-sorbitol, L-sorbose, L-gulose, and L-sorbosone by Ketogulonicigenium vulgare DSM 4025. Biosci Biotechnol Biochem. 2005 Mar;69(3):659-62. doi: 10.1271/bbb.69.659. [PubMed:15785002 ]
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