##TITLE=NP0000012, Submission ID 683, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=23/04/28 ##TIME=18:14:11 ##LONG DATE=2023/04/28 18:14:11 ##TITLE=Allantoin ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=23/04/28 ##TIME=18:14:11 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2023/04/28 18:14:11 ##MOLFORM=C4 H6 N4 O3 ##ATOMLIST= 1 N 0 2 C 0 3 O 0 4 N 0 5 C 0 6 N 0 7 C 0 8 O 0 9 N 0 10 C 0 11 O 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 ##BONDLIST= 1 2 S 2 3 D 2 4 S 4 5 S 5 6 S 6 7 S 7 8 D 7 9 S 9 10 S 10 11 D 10 5 S 1 12 S 1 13 S 4 14 S 5 15 S 6 16 S 9 17 S ##STEREOCENTER= 5 M 0 ##$MOLFILE= RDKit 3D 17 17 0 0 0 0 0 0 0 0999 V2000 3.3891 -0.3512 0.3855 N 0 0 0 0 0 0 0 0 0 0 0 0 2.0846 -0.2844 -0.1895 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9394 -0.4535 -1.4317 O 0 0 0 0 0 0 0 0 0 0 0 0 0.9162 -0.0342 0.5651 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3881 0.0295 -0.0298 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.0856 1.2700 0.2607 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.4954 0.9790 0.1575 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4113 1.8168 -0.0605 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.6471 -0.4249 0.3483 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.3353 -0.9691 0.5641 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0787 -2.0446 1.1285 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1818 -0.0349 -0.2205 H 0 0 0 0 0 0 0 0 0 0 0 0 3.5649 -0.6931 1.3543 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0015 0.1100 1.5941 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.4014 -0.1305 -1.1078 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7102 2.2081 0.5005 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5244 -0.9928 0.3409 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 2 0 2 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 2 0 7 9 1 0 9 10 1 0 10 11 2 0 10 5 1 0 1 12 1 0 1 13 1 0 4 14 1 0 5 15 1 6 6 16 1 0 9 17 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=23/04/28 ##TIME=18:14:11 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 18:14:11 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235735.00,0 ##XUNITS=PPM ##FIRSTX=10.808592279664126 ##LASTX=-1.210822766756614 ##MINX=-1.210822766756614 ##MAXX=10.808592279664126 ##XFACTOR=4.585060461792523e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.018975592309826074 ##LASTY=0.005681970445084811 ##MINY=-69.0764977976354 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 235735@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235662@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235589@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235516@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235443@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235370@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235297@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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-26167@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26240@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26313@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26386@%%%%%%%%%%%%%%%%%%%%%% -26408@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=23/04/28 ##TIME=18:14:11 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 18:14:11 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=730 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.228417749701574, 0.09004970923944404) (9.173534575973624, 0.12439510132000162) (9.169224619139516, 0.12388310369372689) (9.082108470364995, 0.49519419883057664) (9.04868337959835, 0.27520085588259513) (9.044740227601189, 0.16476701778834557) (9.038963051419298, 43.73433066337996) (9.031993759517336, 0.1552569647566174) (9.030985046215736, 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(0.003642905362868376, 0.9241136929413393) (-0.003326386539093562, 0.9077532424467218) (0.00579788377992152, 0.8384705388139674) (0.006118838012248773, 0.5572696580192247) (0.006531493453811876, 0.39523178899589884) (-0.005802319188475735, 0.34120186753613474) (0.006852447686139129, 0.33017501288458234) (-0.006169124025420913, 0.29807836138669813) (0.007586057360029486, 0.2681129205634708) (0.007219252523084307, 0.26416784331450327) (-0.006535928862366092, 0.2371834337691172) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=23/04/28 ##TIME=18:14:11 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 18:14:11 ##SOURCE REFERENCE=PMID 31030325 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=1 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (5.38, , <15>) ##END= ##END=