##TITLE=NP0000786, Submission ID 586, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/06/02 ##TIME=16:07:34 ##LONG DATE=2022/06/02 16:07:34 ##TITLE=L-Proline ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/06/02 ##TIME=16:07:34 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/06/02 16:07:34 ##MOLFORM=C5 H9 N O2 ##ATOMLIST= 1 O 0 2 C 0 3 O 0 4 C 0 5 C 0 6 C 0 7 C 0 8 N 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 ##BONDLIST= 1 2 D 2 3 S 2 4 S 4 5 S 5 6 S 6 7 S 7 8 S 8 4 S 3 9 S 4 10 S 5 11 S 5 12 S 6 13 S 6 14 S 7 15 S 7 16 S 8 17 S ##STEREOCENTER= 4 M 0 ##$MOLFILE= RDKit 3D 17 17 0 0 0 0 0 0 0 0999 V2000 2.5705 -0.8962 -0.4581 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9517 0.1175 -0.0611 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6681 1.1032 0.5890 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5173 0.2411 -0.2849 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.2327 0.2054 1.0544 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6531 0.0478 0.5674 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5054 -0.6704 -0.7297 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0830 -0.8583 -0.9702 N 0 0 0 0 0 0 0 0 0 0 0 0 3.6525 1.2695 0.4025 H 0 0 0 0 0 0 0 0 0 0 0 0 0.2954 1.1940 -0.8185 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0621 1.1065 1.6470 H 0 0 0 0 0 0 0 0 0 0 0 0 0.1214 -0.7341 1.5569 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0868 1.0624 0.4000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.2395 -0.5224 1.3245 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9532 -0.1101 -1.5582 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0486 -1.6449 -0.6572 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0876 -0.8503 -2.0039 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 2 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 4 1 0 3 9 1 0 4 10 1 6 5 11 1 0 5 12 1 0 6 13 1 0 6 14 1 0 7 15 1 0 7 16 1 0 8 17 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=22/06/02 ##TIME=16:07:34 ##TEMPERATURE=NA ##LONG DATE=2022/06/02 16:07:34 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT 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-25429@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25502@%%%%%J%%j%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%J%j%%%%%%%%% -25575@%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25648@%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25721@%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25794@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25867@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%% -25940@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%%J%j%%%%%%%% -26013@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26086@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26159@%%J%j%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26232@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%j%%%%%%%%%% -26305@%j%J%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%j%%%%%J%%%%%%%%% -26378@%%%%%%%%%%%j%%%%%J%%%%%%%%%j%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26451@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26524@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26597@%%%%%%%%%%%%j%J%%%%%%%%%%%%%% -26626@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/06/02 ##TIME=16:07:34 ##TEMPERATURE=NA ##LONG DATE=2022/06/02 16:07:34 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=966 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.76996354411644, 1.1398067476371394) (9.767029105420876, 1.2757907507675166) (9.497840205707606, 1.095465216980042) (9.495043318825896, 1.1316040336169106) (9.038279595619695, 0.9048170548399931) (9.036812376271914, 123.81966659277015) (9.02690864567439, 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REFERENCE=PMID 35442417 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##END= ##END=