##TITLE=NP0000288, Submission ID 584, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/05/31 ##TIME=20:37:40 ##LONG DATE=2022/05/31 20:37:40 ##TITLE=L-Phenylalanine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/05/31 ##TIME=20:37:40 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/05/31 20:37:40 ##MOLFORM=C9 H11 N O2 ##ATOMLIST= 1 N 0 2 C 0 3 C 0 4 C 0 5 C 0 6 C 0 7 C 0 8 C 0 9 C 0 10 C 0 11 O 0 12 O 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 D 5 6 S 6 7 D 7 8 S 8 9 D 2 10 S 10 11 D 10 12 S 9 4 S 1 13 S 1 14 S 2 15 S 3 16 S 3 17 S 5 18 S 6 19 S 7 20 S 8 21 S 9 22 S 12 23 S ##STEREOCENTER= 2 P 0 ##$MOLFILE= RDKit 3D 23 23 0 0 0 0 0 0 0 0999 V2000 -2.8643 -1.3405 -0.2175 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.6083 -0.7645 0.2556 C 0 0 1 0 0 0 0 0 0 0 0 0 -0.6206 -0.7576 -0.8603 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7023 -0.1951 -0.5180 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6962 -1.0143 -0.0046 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9375 -0.5216 0.3187 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2091 0.8164 0.1315 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2495 1.6511 -0.3735 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0119 1.1362 -0.6910 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9067 0.5886 0.7812 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0062 1.3051 1.2879 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.1929 1.1410 0.7447 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.7240 -2.0819 -0.9202 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.4665 -0.6078 -0.6586 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.2938 -1.3793 1.1270 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.0416 -0.1152 -1.6691 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5227 -1.7857 -1.2734 H 0 0 0 0 0 0 0 0 0 0 0 0 1.4666 -2.0710 0.1381 H 0 0 0 0 0 0 0 0 0 0 0 0 3.6806 -1.2205 0.7207 H 0 0 0 0 0 0 0 0 0 0 0 0 4.1829 1.2151 0.3826 H 0 0 0 0 0 0 0 0 0 0 0 0 2.4358 2.6919 -0.5277 H 0 0 0 0 0 0 0 0 0 0 0 0 0.2404 1.7842 -1.0959 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5653 1.5253 1.6049 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 5 6 1 0 6 7 2 0 7 8 1 0 8 9 2 0 2 10 1 0 10 11 2 0 10 12 1 0 9 4 1 0 1 13 1 0 1 14 1 0 2 15 1 1 3 16 1 0 3 17 1 0 5 18 1 0 6 19 1 0 7 20 1 0 8 21 1 0 9 22 1 0 12 23 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=22/05/31 ##TIME=20:37:40 ##TEMPERATURE=NA ##LONG DATE=2022/05/31 20:37:40 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235555.00,0 ##XUNITS=PPM ##FIRSTX=10.800380371014326 ##LASTX=-1.219080526011032 ##MINX=-1.219080526011032 ##MAXX=10.800380371014326 ##XFACTOR=4.585077952512506e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.009096126812273326 ##LASTY=-0.023574202087113312 ##MINY=-12.306503176436708 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 235555@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235482@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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-24044@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24117@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24190@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24263@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24336@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24409@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24482@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24555@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24628@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24701@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24774@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24847@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24920@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24993@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25066@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25139@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25212@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25285@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25358@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25431@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25504@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25577@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25650@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25723@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25796@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25869@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25942@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26015@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26088@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26161@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26234@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26307@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26380@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26453@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26526@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26588@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/05/31 ##TIME=20:37:40 ##TEMPERATURE=NA ##LONG DATE=2022/05/31 20:37:40 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=598 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.770027308113674, 0.19528780256612238) (9.76709286941811, 0.197883343307198) (9.49785811910022, 0.15711695367983042) (9.494969531009277, 0.1452285127855903) (9.171172561195766, 0.05622031501783892) (9.167000156175511, 0.056049065335508526) (9.046367215425109, 0.08756938268952721) (9.042240661009473, 0.07660720941335468) (9.036646887246057, 17.422565153592764) (9.029631744739477, 0.0664759192309006) (9.027018260276241, 0.09885527772815758) (8.996160803368213, 0.13949551879210892) (8.937701282480047, 0.175718142813458) (8.901662707250166, 0.07586598374478815) (8.897352750416058, 0.0670277703259422) (8.753244300101152, 0.0640547707392174) (8.751364425311808, 0.25364415624123654) (8.444165374370073, 0.0683421500365756) 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REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=22/05/31 ##TIME=20:37:40 ##TEMPERATURE=NA ##LONG DATE=2022/05/31 20:37:40 ##SOURCE REFERENCE=PMID 35403092 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=55 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.99,
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