##TITLE=NP0000437, Submission ID 519, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/02/04 ##TIME=00:54:14 ##LONG DATE=2022/02/04 00:54:14 ##TITLE=L-Aspartic acid ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/02/04 ##TIME=00:54:14 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/02/04 00:54:14 ##MOLFORM=C4 H7 N O4 ##ATOMLIST= 1 N 0 2 C 0 3 C 0 4 C 0 5 O 0 6 O 0 7 C 0 8 O 0 9 O 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 D 4 6 S 2 7 S 7 8 D 7 9 S 1 10 S 1 11 S 2 12 S 3 13 S 3 14 S 6 15 S 9 16 S ##STEREOCENTER= 2 P 0 ##$MOLFILE= RDKit 3D 16 15 0 0 0 0 0 0 0 0999 V2000 -0.4809 -0.5185 -1.2327 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.2328 -0.5461 0.1924 C 0 0 1 0 0 0 0 0 0 0 0 0 0.6010 0.6571 0.6052 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9031 0.6798 -0.0799 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7298 1.5889 0.1259 O 0 0 0 0 0 0 0 0 0 0 0 0 2.2262 -0.3354 -0.9811 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5164 -0.5556 0.9340 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4826 -0.5792 2.1862 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.6932 -0.5381 0.2167 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.3669 -1.0238 -1.4581 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.4651 0.4572 -1.6086 H 0 0 0 0 0 0 0 0 0 0 0 0 0.3466 -1.4781 0.3889 H 0 0 0 0 0 0 0 0 0 0 0 0 0.8084 0.5432 1.7005 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0563 1.5988 0.4833 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9249 -0.1658 -1.7171 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3586 0.2156 0.2444 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 2 7 1 0 7 8 2 0 7 9 1 0 1 10 1 0 1 11 1 0 2 12 1 6 3 13 1 0 3 14 1 0 6 15 1 0 9 16 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=22/02/04 ##TIME=00:54:14 ##TEMPERATURE=NA ##LONG DATE=2022/02/04 00:54:14 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58891.00,0 ##XUNITS=PPM ##FIRSTX=10.800916635183036 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-5917Dj%j%%j%%Jj%%%%%%%%%%%%%j%j%%%j%jJ%%JJ%%%j%%%%%%%%%Jj%%%J%%%%%%j%%%%%j%%%%J -5991a%%%%%%%J%%%%%%%%%j%%%%J%J%%j%%%%%%%%J%%%j%%%%%J%%%j%%%j%%%%%%J%J%%j%j%%%J% -6065@J%%%j%%J%JJ%%j%%jJ%%%%%j%jj%%%%%%%J%%J%%%j%%%%%j%j%%%%%J%j%%%%%j%%J%%%J%%% -6139a%j%%%J%%J%%%%%%j%%%J%%%%%J%%%%%Jj%%j%%j%%J%%%%%j%%%%JJ%J%%%j%%j%%j%%%j%J%% -6213a%%%J%%J%%%jj%J%%%%%j%%%J%J%%%%%j%%j%%%%J%%%%%%%%%j%%J%%%%jJj%%%%J%%%%%%%%J -6287A%j%j%j%%%J%%%%J%%%J%%%%j%%%j%%J%%%%%%%%%%%%J%%%%%%j%%%%%%%j%J%JJ%%%j%%j%%% -6361@%%%%%J%%%%%%%%%%j%j%%J%%%%%%%j%J%J%%%%%%j%%%%%%j%%%J%%j%%%%J%%%%%%%%%%j%%% -6435aJ%%%%%%%%%%%%%%%%%%%%%%J%%%j%%%j%%%J%%J%%%%%%%j%%%%%%%j%%%%%J%%%%%%%%%%%%% -6509@%%%%%%j%%J%%J%%j%%%%%J%%%%j%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%J%%%%j%%%%%J%%% -6583A%J%%%%%%%%%%j%%%%j%%%%%%%%J%j%%%Jj%j%%J%%%%%%%%j%%J%%%J%j%%%% -6644@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/02/04 ##TIME=00:54:14 ##TEMPERATURE=NA ##LONG DATE=2022/02/04 00:54:14 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=12 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.89898681640625, 781.2231959122755) (3.8937530517578125, 784.5502818516939) (3.8862762451171875, 787.0207818770622) (3.88104248046875, 778.8795911667659) (2.8251037597656246, 776.2647567795076) (2.819869995117187, 779.2320023188498) (2.8001098632812496, 778.0058167401198) (2.794876098632812, 778.2400910135395) (2.678878784179687, 766.6272476941377) (2.6661682128906246, 768.9506703656446) (2.653884887695312, 768.1225142139806) (2.6411743164062496, 765.8565675645634) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=22/02/04 ##TIME=00:54:14 ##TEMPERATURE=NA ##LONG DATE=2022/02/04 00:54:14 ##SOURCE REFERENCE=PMID 34592595 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=12 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.89,
, <12>) (3.89,
, <12>) (3.89,
, <12>) (3.89,
, <12>) (2.81,
, <13>) (2.81,
, <13>) (2.81,
, <13>) (2.81,
, <13>) (2.66,
, <14>) (2.66,
, <14>) (2.66,
, <14>) (2.66,
, <14>) ##END= ##END=