##TITLE=NP0023958, Submission ID 473, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/01/23 ##TIME=23:11:34 ##LONG DATE=2022/01/23 23:11:34 ##TITLE=Proline ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/01/23 ##TIME=23:11:34 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/01/23 23:11:34 ##MOLFORM=C5 H9 N O2 ##ATOMLIST= 1 O 0 2 C 0 3 O 0 4 C 0 5 C 0 6 C 0 7 C 0 8 N 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 ##BONDLIST= 1 2 D 2 3 S 2 4 S 4 5 S 5 6 S 6 7 S 7 8 S 8 4 S 3 9 S 4 10 S 5 11 S 5 12 S 6 13 S 6 14 S 7 15 S 7 16 S 8 17 S ##STEREOCENTER= 4 M 0 ##$MOLFILE= RDKit 3D 17 17 0 0 0 0 0 0 0 0999 V2000 2.5705 -0.8962 -0.4581 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9517 0.1175 -0.0611 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6681 1.1032 0.5890 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5173 0.2411 -0.2849 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.2327 0.2054 1.0544 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6531 0.0478 0.5674 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5054 -0.6704 -0.7297 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0830 -0.8583 -0.9702 N 0 0 0 0 0 0 0 0 0 0 0 0 3.6525 1.2695 0.4025 H 0 0 0 0 0 0 0 0 0 0 0 0 0.2954 1.1940 -0.8185 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0621 1.1065 1.6470 H 0 0 0 0 0 0 0 0 0 0 0 0 0.1214 -0.7341 1.5569 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0868 1.0624 0.4000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.2395 -0.5224 1.3245 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9532 -0.1101 -1.5582 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0486 -1.6449 -0.6572 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0876 -0.8503 -2.0039 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 2 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 4 1 0 3 9 1 0 4 10 1 6 5 11 1 0 5 12 1 0 6 13 1 0 6 14 1 0 7 15 1 0 7 16 1 0 8 17 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=22/01/23 ##TIME=23:11:34 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:11:34 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT 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-5715AJJJ%j%jj%%%J%Jjjj%%%J%j%jjj%j%JJJJJ%%jjjjj%j%J%JJ%%%%%J%j%%J%%%%%Jj%%%J%J% -5789AjJ%%%jjjj%J%%%%%%%JKJJjj%j%%%%%%%%%JKJ%%%jJ%%%%jj%%%%j%%%j%J%J%j%%%%j%%JJJ -5863C%jjjj%j%jj%%%JJKJ%%j%j%%%j%%j%%%%%JJ%JJ%%%%jjj%%J%JJ%%%%J%%%jkj%j%%%%JJJJ% -5937A%Jjjjj%J%%%j%j%j%%J%%JJ%%jj%%%%%%%%J%j%jJ%J%%%%%%j%JJJJJJ%%jj%%%jj%J%J%jJ% -6011A%%%j%J%jj%j%%%%%%J%J%%%%%J%J%%j%jj%%j%%%%%%J%%jJ%%%%%%%J%JJJ%%j%j%j%%JJ%%% -6085Bj%j%%%%%%%%Jjjjj%%%%%%%JJJ%%%%%%%%%%%j%%J%%jjj%%%J%%%%J%%%%j%JJ%%%%%%Jj%j% -6159aj%%JJ%%%%%jjj%JJJ%j%J%%%J%%%jjj%%%J%%j%J%j%%%J%J%J%J%%%%%j%%%%jj%%%%%J%j%% -6233aJ%%%%%j%jJ%J%%Jj%%%J%%%%j%%%%%%%j%%J%%J%J%%jj%%j%J%%j%J%J%%%%jj%%%%%jJ%J%J -6307A%JJ%JJ%%jj%%%J%%jj%%J%%%J%J%Jj%kjjj%%%%%j%%J%J%JJ%Jj%jj%%%j%%J%%%j%jJJ%Jj% -6381Aj%%%%%j%%J%%%%%%%jJ%J%%j%%%%%J%%%%%%%j%j%%J%%j%%J%%%%j%%J%%%%j%J%%%%%JJ%%% -6455Bj%%%j%j%%%J%%%%J%%%jj%%Jj%j%J%%%%j%%JJJ%J%%j%j%%J%%%%%%%j%jj%%%%%%%%%J%%J% -6529@%j%jJ%JJ%J%%j%j%%jJ%%J%%%%%%%%%j%j%%%%%%J%%Jj%j%%%%%%JJ%%j%j%%%J%J%%%%%%jj -6603aJJJ%%jj%j%%J%%%%%%J%%jj%%%%J%%%%J%J%%j%j%j%%J%%%%j%%% -6656a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/01/23 ##TIME=23:11:34 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:11:34 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=74 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (4.1309814453125, 1358.3312321360434) (4.1216888427734375, 1419.1828103060259) (4.118377685546875, 1424.983076772701) (4.1090850830078125, 1365.7660551349352) (2.3579101562499996, 245.23533196163882) (2.3570556640624996, 247.78867527943518) (2.3523559570312496, 251.39868444249578) (2.3515014648437496, 252.35440742418146) (2.3462142944335933, 256.1841708984232) (2.3453598022460933, 257.1098654608548) (2.340553283691406, 438.1025158177408) (2.3400192260742183, 507.6572031173596) (2.339431762695312, 434.08637206384435) (2.3346786499023433, 253.38073426957433) (2.3337707519531246, 254.69381169083363) (2.328536987304687, 248.72372819450513) (2.3276290893554683, 249.8512433990491) (2.322982788085937, 244.27335514362576) (2.3220748901367183, 243.7029225705941) (2.091842651367187, 340.8124195969644) (2.0814819335937496, 351.23094165288967) (2.0740051269531246, 988.9925890497864) (2.0637512207031246, 995.7510403151366) (2.0562744140624996, 994.9005361550899) (2.045913696289062, 983.8255884691945) (2.038436889648437, 350.52822385556607) (2.028182983398437, 342.4484064207344) (2.0167541503906246, 344.78911377228025) (2.0079956054687496, 369.7703693016747) (2.005111694335937, 380.56985063210163) (2.0013732910156246, 398.05343264375506) (1.999130249023437, 410.2307440516273) (1.996353149414062, 394.72989556210376) (1.9926147460937496, 417.94675892925494) (1.990371704101562, 571.7102066987765) (1.9896240234374996, 569.2121106231871) (1.987380981445312, 417.62602388960596) (1.9836425781249996, 394.21178075569117) (1.9808654785156246, 410.37767615591406) (1.9787292480468746, 401.1824709872602) (1.9748840332031246, 380.5237977361205) (1.972000122070312, 369.7856294251765) (1.963241577148437, 344.89910121350067) (2.0065002441406246, 485.56290393403964) (2.0056457519531246, 498.6818396794445) (2.000198364257812, 517.7087538074616) (1.999343872070312, 516.5118902315979) (1.9962463378906246, 519.4941462921049) (1.995285034179687, 513.9228202662019) (1.9909057617187496, 674.8077514515778) (1.9900512695312496, 959.9682439058254) (1.989089965820312, 674.8346250802933) (1.9847106933593746, 514.6049602632053) (1.983749389648437, 517.6417450034486) (1.9806518554687496, 516.4761840330048) (1.9797973632812496, 517.6972353476234) (1.974349975585937, 498.70901655310337) (1.973495483398437, 485.5907891579849) (3.427520751953125, 688.225968115388) (3.42132568359375, 699.7779516693138) (3.4141693115234375, 771.2108655235027) (3.412139892578125, 788.3632792950975) (3.407867431640625, 788.2108275005249) (3.4058380126953125, 773.0009449500061) (3.398681640625, 699.8428809643934) (3.392486572265625, 688.2803158088507) (3.348907470703125, 684.4332478009353) (3.34014892578125, 707.1177557283083) (3.33544921875, 770.1768877837861) (3.33331298828125, 767.5798041792136) (3.326690673828125, 767.766283035946) (3.324554443359375, 770.8114508826739) (3.319854736328125, 707.1712231888886) (3.31109619140625, 684.486863587026) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=22/01/23 ##TIME=23:11:34 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:11:34 ##SOURCE REFERENCE=PMID 34732583 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=74 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (4.12,
, <10>) (4.12,
, <10>) (4.12,
, <10>) (4.12,
, <10>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) ##END= ##END= ##TITLE=NP0023958, Submission ID 473, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/01/23 ##TIME=23:12:05 ##LONG DATE=2022/01/23 23:12:05 ##TITLE=Proline ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/01/23 ##TIME=23:12:05 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/01/23 23:12:05 ##MOLFORM=C5 H9 N O2 ##ATOMLIST= 1 O 0 2 C 0 3 O 0 4 C 0 5 C 0 6 C 0 7 C 0 8 N 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 ##BONDLIST= 1 2 D 2 3 S 2 4 S 4 5 S 5 6 S 6 7 S 7 8 S 8 4 S 3 9 S 4 10 S 5 11 S 5 12 S 6 13 S 6 14 S 7 15 S 7 16 S 8 17 S ##STEREOCENTER= 4 M 0 ##$MOLFILE= RDKit 3D 17 17 0 0 0 0 0 0 0 0999 V2000 2.5705 -0.8962 -0.4581 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9517 0.1175 -0.0611 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6681 1.1032 0.5890 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5173 0.2411 -0.2849 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.2327 0.2054 1.0544 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6531 0.0478 0.5674 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5054 -0.6704 -0.7297 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0830 -0.8583 -0.9702 N 0 0 0 0 0 0 0 0 0 0 0 0 3.6525 1.2695 0.4025 H 0 0 0 0 0 0 0 0 0 0 0 0 0.2954 1.1940 -0.8185 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0621 1.1065 1.6470 H 0 0 0 0 0 0 0 0 0 0 0 0 0.1214 -0.7341 1.5569 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0868 1.0624 0.4000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.2395 -0.5224 1.3245 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9532 -0.1101 -1.5582 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0486 -1.6449 -0.6572 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0876 -0.8503 -2.0039 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 2 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 4 1 0 3 9 1 0 4 10 1 6 5 11 1 0 5 12 1 0 6 13 1 0 6 14 1 0 7 15 1 0 7 16 1 0 8 17 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=22/01/23 ##TIME=23:12:05 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:12:05 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58879.00,0 ##XUNITS=PPM ##FIRSTX=10.798715772578866 ##LASTX=-1.2207451244464922 ##MINX=-1.2207451244464922 ##MAXX=10.798715772578866 ##XFACTOR=0.00018340521701354362 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.09525423911801797 ##LASTY=-0.42098101496819196 ##MINY=-20.826657043169273 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58879@%j%j%%%jj%jj%JJJ%%%j%%%%%%j%%JJ%%%j%J%%J%%%%%%%%%%%JJ%JJ%%%%%%%%j%%%%j%%J% 58805A%jj%j%%J%J%%j%jj%%j%%%%%%J%%J%%%J%J%J%J%%jj%%JJJ%%%JJJJ%j%jjjjj%j%jjj%%J%% 58731bJ%%J%%%%JJJJ%j%%%%J%%%%%%jkj%JJJ%%j%jjj%%%JJ%J%j%j%j%%%%%%JJ%J%%%%%%%%j%%% 58657Aj%%%jJ%%%%%%%JJ%jj%j%J%j%%jjJJ%J%%Jj%%%%%%J%%j%j%%JJ%%%j%j%%%%JJ%%J%%%%%%% 58583Bjj%%%%%J%%Jj%j%%%%%jj%j%%%%%%J%J%%%%%%J%%%%%jJ%%JJJ%%j%%j%j%%J%%%j%%j%%%%J 58509@%%%j%%JJ%%%%%%%Jjjj%jJJJJj%%jJj%%%%%%jj%JJ%Jj%j%%%J%%%j%%%%%%%JJKJ%J%jj%%% 58435CJ%%jjjkj%%J%%%%%J%JJJJ%%%%%%%jjj%%j%%%%%Jj%j%J%%j%J%%%%jjjjjJJK%JJJ%%%%%j% 58361A%%j%jj%j%%%J%JJJ%%%%jj%%J%%%%%%%J%%jjj%%J%%%J%J%j%j%%%%%J%J%%%%j%%%%%JJJ%j 58287B%j%%j%jJ%J%%%j%jj%%%JJ%jj%%J%JJ%Jj%jjjjjjjJ%J%J%%%j%%%%J%%%J%J%%%j%j%%JJJJ 58213AJ%%%%%jj%%J%%%%%J%J%jjkjj%%%%jkj%%J%J%%JJJJ%%jj%%%%jjj%%%%%%%%jj%%JJ%%%%JK 58139cK%%%%%jjj%jjjjJ%JJJ%%%%%%JJ%J%J%%%%j%%JJJJJJ%%j%%%j%%%%J%j%%%j%%%%%%%%j%%j 58065@%%j%%j%%j%JJ%J%%%j%j%JJJ%J%%j%%%%%j%%%Jj%%%J%%J%%J%%Jjjjj%j%%J%%%j%j%j%%%J 57991bJ%Jj%%%JJ%J%%jjjjj%j%%%%JJ%%J%J%jjjjJJ%J%%j%%%%%%J%JJ%%%%%%%%%J%%%%%%%%%%j 57917AjjJJ%Jj%%j%%%%%%%%jj%%%JJ%%JJJKJJJ%%kj%%%jj%%%JJJJ%%j%%JJJK%%j%jJ%%%j%jk%% 57843F%%%J%%jjjj%Jj%%J%%%%j%jjj%%%J%%jj%j%%%JKKJJ%%%%%KJJ%%%j%%%jjj%jjj%j%%%%%%j 57769@j%%j%j%%%JJJJ%%jjj%JJ%Jj%%%j%%JJJJJ%%%%jjkjj%JJ%%%jjjJJJ%%j%%%JKJ%%%%k%%%J 57695BJj%jj%%%J%%%%j%%j%jJ%%%j%%%%JJJJjjjj%%JJJ%%%%%J%%j%%J%%%%%%jj%J%%%%%%JJJ%% 57621Dj%jj%jkj%%KJK%%%jJ%%%%%j%%JJ%%%k%jJJ%J%%jjj%%%jj%jJJJJ%J%j%%%%J%%jJ%J%%j%j 57547A%jjk%%J%%%JJ%%%JJJJJJ%Jj%jj%%J%J%J%j%%%J%jjj%jjjkjjj%%J%%%Jj%%%%JJJ%jJ%%j% 57473a%%J%%j%j%JJ%J%J%J%%%%%%%jjjj%%%j%J%JJ%%jjj%%%%j%jJJJJJ%%Jj%%%j%jJ%j%j%%JJ% 57399@%%%kjk%J%J%%j%%JJ%J%%jjJ%JJJ%%%%%%%%%J%J%%kkj%%Jj%%%%%%%j%%%J%J%%%J%JJ%%jk 57325ajk%j%%J%J%%%j%JJ%JKJJJ%J%j%%%%%jj%%J%%%%j%j%Jj%j%%J%JJ%jjj%j%%j%%%%%%j%J%% 57251bj%%%%J%J%j%JJ%%%j%%%JJJJJJ%%%%j%jj%jjjj%%JJ%%jjjjj%%J%J%J%%%%j%%%j%JJJJ%%% 57177@%J%J%J%J%jjj%%%%j%j%j%%%JJ%%J%J%%j%jJ%%%%%%%%%%jjj%%JJKJJJ%%%jjjj%J%%j%j%J 57103AJJ%%%J%j%%%%jj%%jjj%%JJ%J%JJ%%jj%j%%JJ%jkjj%%J%J%%j%j%j%j%jJJJ%JJ%JJ%%j%J% 57029Ajj%%%%JJJ%%%%jJ%JJ%jj%j%%%j%JJ%%%jj%j%j%j%%%%%%K%J%%%%%J%J%%%j%%%jjk%%%JJJ 56955@J%%%%%%J%j%j%%%JJ%%kj%%j%jj%%%KJJJ%jkjk%j%J%J%j%%%KJ%%%jJ%%JJ%%%%JJJJJjj%% 56881CJ%%%%jjj%j%%J%%jjj%%%JJJ%J%JJKJ%%jkjj%%%%jjj%jJ%%j%j%%%J%%%%%jj%%%J%J%%J%% 56807aj%%j%%%JJ%%J%%j%%%j%J%J%j%%%%J%%j%J%J%K%J%j%j%%%%j%%%jj%j%%%%%JJj%kjj%j%j% 56733gj%%J%KJ%%%%%KJJJjj%j%j%%j%%J%JJ%%%%%j%%%jjjj%J%%JJJ%%%%%J%%%J%%%%j%%%J%JJ% 56659Bj%%%J%j%j%%%%%J%j%%j%%%%j%%%%J%J%J%j%jJ%J%%k%%%JJ%J%%%JJ%jjkj%%j%j%%%%J%%% 56585bjjjJ%JJJ%j%%J%J%j%%j%%%%%JJJ%j%%%%J%J%%jjjj%j%J%%%%j%J%J%%jJ%%%%J%%%%%%j%% 56511aJJ%%%%%J%jj%jjj%jJ%J%%%%j%J%J%%%%%%%%%%JJ%%jj%j%%jj%%JK%J%j%jjJ%J%j%%%j%%% 56437c%j%j%%JJJJJ%%j%J%J%%%jj%%%j%J%J%JJJ%%%jjjjj%J%%%%%%%JJJ%%%%%%J%%%%j%jj%JJ% 56363B%%%%%%jjj%j%%J%%%%Jj%%%%%%%%%%%%%J%J%%%jjjj%%JJJ%J%j%%%J%%jjj%j%%J%j%%J%J% 56289a%%%j%%J%%%JJ%J%%%%j%J%%%j%j%%%%%%jjjjjj%%j%J%JJ%JJJJJJ%j%jj%KJJ%%j%j%J%%Jj 56215B%j%%%%jjjjj%%JJ%JJJ%%j%j%jjkjj%j%%J%%%%%%%%j%%J%JJJ%%%%j%%%JKJ%JJ%%%J%%jjj 56141a%%%J%%J%%%%%j%jj%%%%%%%jj%J%%JJJJJJ%%%%j%j%%j%%%%JJJjj%%%%%%jj%%%JJ%%jj%%% 56067aJ%J%%%j%%%Jj%%%J%J%j%j%j%%%J%J%j%j%%%%%%%J%%j%J%%%%%%j%j%%J%%%%%%%%%J%JKJJ 55993E%jjjkjjj%JJ%%%j%J%%J%%%%%j%%jjj%j%j%JJJ%%j%JJJ%%%jjJJJJJJ%J%%%%%jjjj%%%J%J 55919B%%%%j%%J%%J%J%%%%J%jjjj%%%JKJ%%%j%%%%j%j%%%j%%%j%%%%%%%j%J%j%jj%%J%J%%%%%% 55845a%%JJ%j%j%JJJJj%j%%%%%JJ%J%jjkkjj%%%J%jj%j%%JJJ%j%J%%%j%j%J%J%j%%%%JJJ%%%j% 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-5641@%jJ%%%%JJJ%jj%JJ%Jjjkj%%%%JJ%%%%%J%%%%%%J%J%%%%%%%%%j%%jjjjj%%J%Jj%j%J%%JJ -5715AJJJ%j%jj%%%J%Jjjj%%%J%j%jjj%j%JJJJJ%%jjjjj%j%J%JJ%%%%%J%j%%J%%%%%Jj%%%J%J% -5789AjJ%%%jjjj%J%%%%%%%JKJJjj%j%%%%%%%%%JKJ%%%jJ%%%%jj%%%%j%%%j%J%J%j%%%%j%%JJJ -5863C%jjjj%j%jj%%%JJKJ%%j%j%%%j%%j%%%%%JJ%JJ%%%%jjj%%J%JJ%%%%J%%%jkj%j%%%%JJJJ% -5937A%Jjjjj%J%%%j%j%j%%J%%JJ%%jj%%%%%%%%J%j%jJ%J%%%%%%j%JJJJJJ%%jj%%%jj%J%J%jJ% -6011A%%%j%J%jj%j%%%%%%J%J%%%%%J%J%%j%jj%%j%%%%%%J%%jJ%%%%%%%J%JJJ%%j%j%j%%JJ%%% -6085Bj%j%%%%%%%%Jjjjj%%%%%%%JJJ%%%%%%%%%%%j%%J%%jjj%%%J%%%%J%%%%j%JJ%%%%%%Jj%j% -6159aj%%JJ%%%%%jjj%JJJ%j%J%%%J%%%jjj%%%J%%j%J%j%%%J%J%J%J%%%%%j%%%%jj%%%%%J%j%% -6233aJ%%%%%j%jJ%J%%Jj%%%J%%%%j%%%%%%%j%%J%%J%J%%jj%%j%J%%j%J%J%%%%jj%%%%%jJ%J%J -6307A%JJ%JJ%%jj%%%J%%jj%%J%%%J%J%Jj%kjjj%%%%%j%%J%J%JJ%Jj%jj%%%j%%J%%%j%jJJ%Jj% -6381Aj%%%%%j%%J%%%%%%%jJ%J%%j%%%%%J%%%%%%%j%j%%J%%j%%J%%%%j%%J%%%%j%J%%%%%JJ%%% -6455Bj%%%j%j%%%J%%%%J%%%jj%%Jj%j%J%%%%j%%JJJ%J%%j%j%%J%%%%%%%j%jj%%%%%%%%%J%%J% -6529@%j%jJ%JJ%J%%j%j%%jJ%%J%%%%%%%%%j%j%%%%%%J%%Jj%j%%%%%%JJ%%j%j%%%J%J%%%%%%jj -6603aJJJ%%jj%j%%J%%%%%%J%%jj%%%%J%%%%J%J%%j%j%j%%J%%%%j%%% -6656a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/01/23 ##TIME=23:12:05 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:12:05 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=74 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (4.1309814453125, 1358.3312321360434) (4.1216888427734375, 1419.1828103060259) (4.118377685546875, 1424.983076772701) (4.1090850830078125, 1365.7660551349352) (2.3579101562499996, 245.23533196163882) (2.3570556640624996, 247.78867527943518) (2.3523559570312496, 251.39868444249578) (2.3515014648437496, 252.35440742418146) (2.3462142944335933, 256.1841708984232) (2.3453598022460933, 257.1098654608548) (2.340553283691406, 438.1025158177408) (2.3400192260742183, 507.6572031173596) (2.339431762695312, 434.08637206384435) (2.3346786499023433, 253.38073426957433) (2.3337707519531246, 254.69381169083363) (2.328536987304687, 248.72372819450513) (2.3276290893554683, 249.8512433990491) (2.322982788085937, 244.27335514362576) (2.3220748901367183, 243.7029225705941) (2.091842651367187, 340.8124195969644) (2.0814819335937496, 351.23094165288967) (2.0740051269531246, 988.9925890497864) (2.0637512207031246, 995.7510403151366) (2.0562744140624996, 994.9005361550899) (2.045913696289062, 983.8255884691945) (2.038436889648437, 350.52822385556607) (2.028182983398437, 342.4484064207344) (2.0167541503906246, 344.78911377228025) (2.0079956054687496, 369.7703693016747) (2.005111694335937, 380.56985063210163) (2.0013732910156246, 398.05343264375506) (1.999130249023437, 410.2307440516273) (1.996353149414062, 394.72989556210376) (1.9926147460937496, 417.94675892925494) (1.990371704101562, 571.7102066987765) (1.9896240234374996, 569.2121106231871) (1.987380981445312, 417.62602388960596) (1.9836425781249996, 394.21178075569117) (1.9808654785156246, 410.37767615591406) (1.9787292480468746, 401.1824709872602) (1.9748840332031246, 380.5237977361205) (1.972000122070312, 369.7856294251765) (1.963241577148437, 344.89910121350067) (2.0065002441406246, 485.56290393403964) (2.0056457519531246, 498.6818396794445) (2.000198364257812, 517.7087538074616) (1.999343872070312, 516.5118902315979) (1.9962463378906246, 519.4941462921049) (1.995285034179687, 513.9228202662019) (1.9909057617187496, 674.8077514515778) (1.9900512695312496, 959.9682439058254) (1.989089965820312, 674.8346250802933) (1.9847106933593746, 514.6049602632053) (1.983749389648437, 517.6417450034486) (1.9806518554687496, 516.4761840330048) (1.9797973632812496, 517.6972353476234) (1.974349975585937, 498.70901655310337) (1.973495483398437, 485.5907891579849) (3.427520751953125, 688.225968115388) (3.42132568359375, 699.7779516693138) (3.4141693115234375, 771.2108655235027) (3.412139892578125, 788.3632792950975) (3.407867431640625, 788.2108275005249) (3.4058380126953125, 773.0009449500061) (3.398681640625, 699.8428809643934) (3.392486572265625, 688.2803158088507) (3.348907470703125, 684.4332478009353) (3.34014892578125, 707.1177557283083) (3.33544921875, 770.1768877837861) (3.33331298828125, 767.5798041792136) (3.326690673828125, 767.766283035946) (3.324554443359375, 770.8114508826739) (3.319854736328125, 707.1712231888886) (3.31109619140625, 684.486863587026) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=22/01/23 ##TIME=23:12:05 ##TEMPERATURE=NA ##LONG DATE=2022/01/23 23:12:05 ##SOURCE REFERENCE=PMID 34732583 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=74 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (4.12,
, <10>) (4.12,
, <10>) (4.12,
, <10>) (4.12,
, <10>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.34, , <11>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (2.06, , <12>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <13>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (1.99, , <14>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.41, , <15>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) (3.33, , <16>) ##END= ##END=