##TITLE=NP0000152, Submission ID 458, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=22/01/19 ##TIME=19:52:31 ##LONG DATE=2022/01/19 19:52:31 ##TITLE=Citric acid ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=22/01/19 ##TIME=19:52:31 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2022/01/19 19:52:31 ##MOLFORM=C6 H8 O7 ##ATOMLIST= 1 O 0 2 C 0 3 O 0 4 C 0 5 C 0 6 O 0 7 C 0 8 C 0 9 O 0 10 O 0 11 C 0 12 O 0 13 O 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 ##BONDLIST= 1 2 D 2 3 S 2 4 S 4 5 S 5 6 S 5 7 S 7 8 S 8 9 D 8 10 S 5 11 S 11 12 D 11 13 S 3 14 S 4 15 S 4 16 S 6 17 S 7 18 S 7 19 S 10 20 S 13 21 S ##$MOLFILE= RDKit 3D 21 20 0 0 0 0 0 0 0 0999 V2000 -2.8734 0.9378 0.4652 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2463 -0.1449 0.3654 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9560 -1.2081 -0.2328 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8425 -0.3419 0.8381 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0481 0.3571 -0.1627 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.1117 -0.1724 -1.4400 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5242 0.3386 0.2290 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0470 -1.0122 0.3664 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2656 -1.4965 1.4982 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3018 -1.7675 -0.7587 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3462 1.7853 -0.1787 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2927 2.4329 0.8905 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7572 2.3665 -1.3440 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.8399 -2.1166 0.2127 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.6122 -1.4165 0.9188 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7345 0.1578 1.8247 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0354 -1.1677 -1.4336 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0552 0.8668 -0.5623 H 0 0 0 0 0 0 0 0 0 0 0 0 1.5345 0.8796 1.2218 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0901 -2.3671 -0.9028 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.2187 3.0890 -1.8151 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 2 4 1 0 4 5 1 0 5 6 1 6 5 7 1 0 7 8 1 0 8 9 2 0 8 10 1 0 5 11 1 0 11 12 2 0 11 13 1 0 3 14 1 0 4 15 1 0 4 16 1 0 6 17 1 0 7 18 1 0 7 19 1 0 10 20 1 0 13 21 1 0 M END ##END= ##TITLE=Experimental spectrum 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-6621@%%%%%%%%%%%J%j%%%%j%%%J% -6645@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=22/01/19 ##TIME=19:52:31 ##TEMPERATURE=NA ##LONG DATE=2022/01/19 19:52:31 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=8 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (2.550704956054687, 522.2816603399881) (2.5292358398437496, 519.5161624776597) (2.660720825195312, 522.2805077148608) (2.6392517089843746, 521.3702254299874) (2.550704956054687, 522.2816603399881) (2.5292358398437496, 519.5161624776597) (2.5706787109374996, 521.3514282609638) (2.5493164062499996, 521.3736878435866) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=22/01/19 ##TIME=19:52:31 ##TEMPERATURE=NA ##LONG DATE=2022/01/19 19:52:31 ##SOURCE REFERENCE=PMID 34609480 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=8 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.54, , <15>) (2.54, , <15>) (2.65, , <16>) (2.65, , <16>) (2.54, , <18>) (2.54, , <18>) (2.56, , <19>) (2.56, , <19>) ##END= ##END=