##TITLE=NP0000460, Submission ID 399, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Kaempferol ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C15 H10 O6 ##ATOMLIST= 1 O 0 2 C 0 3 C 0 4 O 0 5 C 0 6 C 0 7 C 0 8 C 0 9 C 0 10 O 0 11 C 0 12 C 0 13 O 0 14 C 0 15 C 0 16 C 0 17 O 0 18 C 0 19 C 0 20 O 0 21 C 0 22 H 0 23 H 0 24 H 0 25 H 0 26 H 0 27 H 0 28 H 0 29 H 0 30 H 0 31 H 0 ##BONDLIST= 1 2 D 2 3 S 3 4 S 3 5 D 5 6 S 6 7 D 7 8 S 8 9 D 9 10 S 9 11 S 11 12 D 5 13 S 13 14 S 14 15 D 15 16 S 16 17 S 16 18 D 18 19 S 19 20 S 19 21 D 21 2 S 12 6 S 21 14 S 4 22 S 7 23 S 8 24 S 10 25 S 11 26 S 12 27 S 15 28 S 17 29 S 18 30 S 20 31 S ##$MOLFILE= RDKit 3D 31 33 0 0 0 0 0 0 0 0999 V2000 -2.2787 -1.4681 -2.2450 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6647 -0.8603 -1.3486 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2582 -0.8695 -1.3118 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3474 -1.5767 -2.3079 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4478 -0.2163 -0.3470 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8955 -0.1985 -0.2699 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7683 -0.8088 -1.1169 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1616 -0.7227 -0.9434 C 0 0 0 0 0 0 0 0 0 0 0 0 4.6969 -0.0076 0.1044 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0590 0.1101 0.3222 O 0 0 0 0 0 0 0 0 0 0 0 0 3.8427 0.6173 0.9730 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4871 0.5183 0.7825 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2823 0.4283 0.5545 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5790 0.4724 0.5719 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2407 1.1831 1.5709 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6025 1.2695 1.6468 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2657 1.9794 2.6446 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.3358 0.6246 0.6928 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7291 -0.1075 -0.3390 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5216 -0.7149 -1.2411 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3473 -0.1652 -0.3728 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1672 -2.0571 -3.0174 H 0 0 0 0 0 0 0 0 0 0 0 0 2.4087 -1.3681 -1.9343 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8284 -1.2151 -1.6281 H 0 0 0 0 0 0 0 0 0 0 0 0 6.4865 -0.6014 0.9149 H 0 0 0 0 0 0 0 0 0 0 0 0 4.2156 1.1880 1.8074 H 0 0 0 0 0 0 0 0 0 0 0 0 1.7901 1.0147 1.4717 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.6641 1.6965 2.3301 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.7149 2.4589 3.3541 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4135 0.6510 0.6925 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3702 -1.2538 -2.0110 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 3 4 1 0 3 5 2 0 5 6 1 0 6 7 2 0 7 8 1 0 8 9 2 0 9 10 1 0 9 11 1 0 11 12 2 0 5 13 1 0 13 14 1 0 14 15 2 0 15 16 1 0 16 17 1 0 16 18 2 0 18 19 1 0 19 20 1 0 19 21 2 0 21 2 1 0 12 6 1 0 21 14 1 0 4 22 1 0 7 23 1 0 8 24 1 0 10 25 1 0 11 26 1 0 12 27 1 0 15 28 1 0 17 29 1 0 18 30 1 0 20 31 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=700 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58160.00,0.0 ##XUNITS=PPM ##FIRSTX=10.666825587555563 ##LASTX=-1.3526107068126247 ##MINX=-1.3526107068126247 ##MAXX=10.666825587555563 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-6548@%%%%Jj%J%%%%jJ%%j%%J%j%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%Jj%%%%%%%%%J%%%j%%%%% -6622@%%%%%%%%J%%%j%%%%%%%%%%%%%%%%j%J%%%%j%%%J%%%%%%%%jJ%%%%jJ%%%%%%%%%%%%%%%%% -6696@%%%%%%%%%%%%%%%%%%%%%%j%JjJj%%Jj%%J%%%%%%%%%%%%%%%%%%j%%%J%jJj%%%%%J%%%%%% -6770@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%j%%%J%%%%%%%Jj%%%%%%%%%%j%Jj%J%%%%% -6844@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%Jj%%%%%%%%%%%%%%%%%% -6918@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%% -6992@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%% -7066@%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%% -7140@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%% -7214@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -7288@%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -7362@%%%%%%%%%%%%% -7375@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=700 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=12 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (8.046371459960938, 4998.506699214109) (8.033554077148438, 4996.439291430462) (6.9863739013671875, 5000.0) (6.9735565185546875, 4996.468151992211) (6.9863739013671875, 5000.0) (6.9735565185546875, 4996.468151992211) (8.046371459960938, 4998.506699214109) (8.033554077148438, 4996.439291430462) (6.201416015625, 4974.472984428738) (6.198638916015625, 5008.555954835504) (6.0113983154296875, 4990.786746292229) (6.0086212158203125, 5000.333807829411) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 27000882 ##.OBSERVE FREQUENCY=700 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=12 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (8.04, , <23>) (8.04, , <23>) (6.98, , <24>) (6.98, , <24>) (6.98, , <26>) (6.98, , <26>) (8.04, , <27>) (8.04, , <27>) (6.2, , <28>) (6.2, , <28>) (6.01, , <30>) (6.01, , <30>) ##END= ##END=