##TITLE=NP0000004, Submission ID 334, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Cotinine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H12 N2 O ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 O 0 5 C 0 6 C 0 7 C 0 8 C 0 9 C 0 10 C 0 11 C 0 12 N 0 13 C 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 25 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 3 5 S 5 6 S 6 7 S 7 8 S 8 9 D 9 10 S 10 11 D 11 12 S 12 13 D 7 2 S 13 8 S 1 14 S 1 15 S 1 16 S 5 17 S 5 18 S 6 19 S 6 20 S 7 21 S 9 22 S 10 23 S 11 24 S 13 25 S ##STEREOCENTER= 7 M 0 ##$MOLFILE= RDKit 3D 25 26 0 0 0 0 0 0 0 0999 V2000 -1.1284 2.0656 0.5232 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3744 0.7525 0.0022 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.6562 0.1217 0.0371 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7968 0.6760 0.1508 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.5297 -1.3553 -0.0802 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0356 -1.5439 -0.1889 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5002 -0.1629 -0.6146 C 0 0 2 0 0 0 0 0 0 0 0 0 0.9115 -0.1433 -0.3150 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7048 1.0050 -0.2789 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0389 0.8942 0.0202 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6709 -0.2997 0.2947 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8935 -1.3954 0.2555 N 0 0 0 0 0 0 0 0 0 0 0 0 1.5820 -1.3228 -0.0341 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3315 2.0256 1.3108 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.9681 2.8458 -0.2383 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0198 2.4607 1.1053 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.0773 -1.7679 -0.9419 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.9482 -1.8088 0.8324 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.6861 -1.7907 0.8327 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7652 -2.2488 -0.9709 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.6115 -0.0693 -1.7392 H 0 0 0 0 0 0 0 0 0 0 0 0 1.2048 1.9207 -0.4986 H 0 0 0 0 0 0 0 0 0 0 0 0 3.6279 1.7922 0.0419 H 0 0 0 0 0 0 0 0 0 0 0 0 4.7250 -0.3617 0.5281 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0698 -2.2895 -0.0343 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 3 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 9 2 0 9 10 1 0 10 11 2 0 11 12 1 0 12 13 2 0 7 2 1 0 13 8 1 0 1 14 1 0 1 15 1 0 1 16 1 0 5 17 1 0 5 18 1 0 6 19 1 0 6 20 1 0 7 21 1 6 9 22 1 0 10 23 1 0 11 24 1 0 13 25 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,55584.00,0.0 ##XUNITS=PPM ##FIRSTX=11.882702828160427 ##LASTX=-2.127316778983599 ##MINX=-2.127316778983599 ##MAXX=11.882702828160427 ##XFACTOR=0.0002137791959579971 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-1.6665404942336888 ##LASTY=-0.5899037220167277 ##MINY=-148.36844740791426 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 55584eJ%Jj%J%%j%%%%j%%JJ%%J%%%%%%jj%JJ%%JJ%%%J%jjJ%%jj%%%JjJJKJ%j%%jj%%j%J%%%j%% 55510aj%J%jJ%JJ%J%%%%Jjj%JjjjJJjjjj%J%K%J%jjj%%J%Jjj%JKJ%%%%%Jj%jj%jJJjjjJJjjJJJ 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-8956@JJ%%jJ%%jkkj%%%JJJ%%JJJj%JJjkj%%j%KJ%j%%%%KJjkk%JJ%%jJ%J%%jkk%JKJ%%KJJjjjk -9030akjJJJJ%%%jJjkk%JJ%%J%%jJKJK%klk%J%%%KJJJ%jkj%%J%JJ%jjjjJJK%%kj%JJ%%JJ%%%J% -9104Cjkk%%%%%%j%%%J%KKK%jjj%jj%%%j%KKJk%%KJJ%J%klkj%K%%jJ%Jj%%JjkkjJ%Jjj%JJK%JJ -9178AJ%kj%JJ%%j%j%jjk%KJJ%%JJ%%%%J%jj%%%J%%%%jjj%J%%JJJ%jjj%%JJJ%jjJJjjj%%J%%J% -9252Ajj%Jjjj%JJ%%J%%%jjJ%%JJJj%jJ%j%J%%j%KJj%%JjjjjJ%%%jj%%j%JKLJjjj%j%jj%J%%%J -9326@JJjk%%%%jJ%%jJKJJ%j%%kjjJLJjkjJKJJ%jjkk%%%%J%JJK%%JJJjjkjj%J%jj%%j%JJ%%%Jj -9400@%%JJjk%J%%%%jjjJJjjJKJ%jkj%KKKjjJ%j%%J%%kkljJMK%%KK%kkjjjjjJKKJJ%jjkk%J%%% -9474bjJ%J%%j%jjJKJKJ%%j%j%Jj%jjJKJjjj%%%jJ%%%%jj%KKJjk%%%%%JJ%jkjJ%J%J%%kjJJ%jj -9548bJJ%%%Jjj%%j%J%%JJJjjjJ%%%Jjj%K%%j%J%jJK%j%%%jkj%%JJJkj%JJ%%j%j%KKJj%jjj%%J -9622@jJ%JjjJJ%%kjJJK%%jjj%J%J%%%%jjjJ%%%%%%%JJ%j%%%%%%%%j%J%%%J%k%JKJjkj%JJ%%j% -9696@%%%jj%%J%%J%%%%KJjjk%%%%KJ%j%K%jjkj%%J%%J%J%j%J%j%%JJjkj%JJ%%%%%j%j%%%J%JJ -9770A%jj%JJ%jj%KJ%%%%%jj%%k%%KJ%j%jj%JJJ%J%%jjjj%J%jjJJJ%j%JJJ%j%%J%%%%%jjj%JJ% -9844Ajj%J%%%%%%%JJ%jkjjj%JKJjj%JJJ%%%JJ%kj%jjkjjJ%KJJJ%%JJ%J%%%%jj%JJ%jk%JKJ%%j -9918C%jkkkj%JKJJJJ%%J%Jj%jjj%%j%J%Jjjj -9951b $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=59 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (2.6409606933593746, 3333.3333333333335) (2.6409606933593746, 3333.3333333333335) (2.6409606933593746, 3333.3333333333335) (2.6330566406249996, 424.25169184644784) (2.6230163574218746, 451.8734591103123) (2.6189575195312496, 455.46666235439295) (2.6110534667968746, 512.984033344236) (2.609024047851562, 518.831419711605) (2.6010131835937496, 456.3633919313063) (2.5969543457031246, 450.9613643222576) (2.587020874023437, 425.3935993538483) (1.9650573730468746, 424.25167900679565) (1.9550170898437496, 451.8734514909825) (1.9509582519531246, 455.46665691310585) (1.9430541992187496, 512.9840328485756) (1.941024780273437, 518.8314201976256) (1.9330139160156246, 456.36339738531996) (1.9289550781249996, 450.96137192812574) (1.919021606445312, 425.3936122265714) (2.6454467773437496, 418.46019374373054) (2.623764038085937, 507.7016866159161) (2.6208801269531246, 836.393026274745) (2.599197387695312, 835.3078776819711) (2.5963134765624996, 511.6326874025869) (2.574630737304687, 419.5326454445396) (1.973281860351562, 420.57561184109477) (1.957260131835937, 438.30316855983045) (1.9515991210937496, 472.2134692362104) (1.948501586914062, 468.73833655196296) (1.935470581054687, 468.8519383851038) (1.932479858398437, 474.42998225243457) (1.926712036132812, 437.82237959703264) (1.910690307617187, 420.761947956649) (4.8516387939453125, 424.798155668505) (4.837860107421875, 1261.0180439972964) (4.8240814208984375, 1257.5866887767554) (4.8104095458984375, 425.11689817572415) (7.793975830078125, 205.15939879298992) (7.7900238037109375, 628.0292572021012) (7.7859649658203125, 627.9293231492626) (7.782012939453125, 205.3277472107483) (7.7779541015625, 206.3267253517353) (7.7740020751953125, 623.7490761191531) (7.770050048828125, 625.2394890122048) (7.7660980224609375, 209.39017459973311) (7.5208587646484375, 418.23584619373594) (7.51904296875, 422.662658250857) (7.51092529296875, 416.6451203529056) (7.50921630859375, 415.38243378619154) (7.5048370361328125, 420.24366962031297) (7.503021240234375, 421.3208634802255) (7.494903564453125, 418.24618274833125) (7.493194580078125, 414.4098276680319) (8.515594482421875, 834.842836710009) (8.512283325195312, 837.1140324261941) (8.505661010742188, 832.7108085077896) (8.502456665039062, 830.067562081207) (8.467208862304688, 1667.143882133996) (8.46282958984375, 1672.3535882789383) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 10080645 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=59 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.641, , <14>) (2.641, , <15>) (2.641, , <16>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (2.61, , <17>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (1.942, , <18>) (2.61, , <19>) (2.61, , <19>) (2.61, , <19>) (2.61, , <19>) (2.61, , <19>) (2.61, , <19>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (1.942, , <20>) (4.831, , <21>) (4.831, , <21>) (4.831, , <21>) (4.831, , <21>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.78, , <22>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (7.507, , <23>) (8.509,
, <24>) (8.509,
, <24>) (8.509,
, <24>) (8.509,
, <24>) (8.465, , <25>) (8.465, , <25>) ##END= ##END=