##TITLE=NP0000380, Submission ID 307, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=2-Methylhippuric acid ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H11 N O3 ##ATOMLIST= 1 C 0 2 C 0 3 C 0 4 C 0 5 C 0 6 C 0 7 C 0 8 C 0 9 O 0 10 N 0 11 C 0 12 C 0 13 O 0 14 O 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 25 H 0 ##BONDLIST= 1 2 S 2 3 D 3 4 S 4 5 D 5 6 S 6 7 D 7 8 S 8 9 D 8 10 S 10 11 S 11 12 S 12 13 D 12 14 S 7 2 S 1 15 S 1 16 S 1 17 S 3 18 S 4 19 S 5 20 S 6 21 S 10 22 S 11 23 S 11 24 S 14 25 S ##$MOLFILE= RDKit 3D 25 25 0 0 0 0 0 0 0 0999 V2000 -1.0078 -2.0234 -0.2739 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6349 -0.7158 0.1270 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8461 -0.6749 0.7730 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4623 0.5271 1.1106 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8809 1.7348 0.8150 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6579 1.7087 0.1697 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0470 0.4897 -0.1702 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2394 0.4899 -0.8335 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3115 0.8460 -2.0584 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4409 0.1165 -0.1651 N 0 0 0 0 0 0 0 0 0 0 0 0 2.7046 0.1367 -0.8621 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7826 -0.2302 0.1101 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3876 -0.8225 1.1694 O 0 0 0 0 0 0 0 0 0 0 0 0 5.0755 0.0890 -0.1768 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8505 -2.0570 -1.4037 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0440 -2.2316 0.1525 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.7527 -2.8586 -0.0900 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.2840 -1.6524 0.9946 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.4071 0.5119 1.6059 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3730 2.6834 1.0920 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.1787 2.6471 -0.0688 H 0 0 0 0 0 0 0 0 0 0 0 0 1.3893 -0.1855 0.8333 H 0 0 0 0 0 0 0 0 0 0 0 0 2.7169 -0.6392 -1.6884 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8492 1.1486 -1.3081 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5293 0.9619 0.1460 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 2 0 3 4 1 0 4 5 2 0 5 6 1 0 6 7 2 0 7 8 1 0 8 9 2 0 8 10 1 0 10 11 1 0 11 12 1 0 12 13 2 0 12 14 1 0 7 2 1 0 1 15 1 0 1 16 1 0 1 17 1 0 3 18 1 0 4 19 1 0 5 20 1 0 6 21 1 0 10 22 1 0 11 23 1 0 11 24 1 0 14 25 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,117872.00,0.0 ##XUNITS=PPM ##FIRSTX=10.789896425302233 ##LASTX=-1.2082245394798097 ##MINX=-1.2082245394798097 ##MAXX=10.789896425302233 ##XFACTOR=9.153909686254735e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.1544341911002851 ##LASTY=0.045478010320620744 ##MINY=-3480.36650727457 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 117872Aj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 117799@%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%%%%%%%j%%%J%%%%%%%%%%%%%%%%%%% 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-11716@%j%%%J%%Jj%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -11789@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%j%%%%%J%J%%%%j%%%%%%%%%%% -11862@j%%%%%%%%%%%%%J%%%%%%%%%%%%%%%%%J%j%%%%j%%J%%%%j%%J%%%%%%%%%%%%%%%%%%%%%% -11935@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%% -12008a%J%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%J%%j%%%%%%%%%%%%%%%%%j%%%J%%%%%J%%%j% -12081@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%J%%%j%%%%%%%%%%%%%%% -12154@%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%j%%%%%%%%%%%%%%%%%J%%%%%%%%%%%%%%%%% -12227@j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12300@%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%J%%%%j%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%% -12373@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%J%%%%%%%%%%%%J%%%%%j -12446@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%J%%J%%%j%%%%%%%%%%%%%%%j%J% -12519@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j -12592a%%%J%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12665@%%%%%%%%%%%%%J%%%%%j%%%%%%%%Jj%%Jj%%%%%%%%%%%J%%%%%%%j%%%%%%%%%J%%j%%%%%% -12738@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%%j%%% -12811a%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12884@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12957@%%%%%%%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13030@%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13103@j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%jJ%%%%%%J%%%j%%%%%%%%%%%%%%%%Jj%%%%% -13176@%%%%%%%%%%%%%%%jJ%%%%%% -13199@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=30 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (2.380020141601562, 1297.1660891571948) (2.380020141601562, 1297.1660891571948) (2.380020141601562, 1297.1660891571948) (7.317169189453125, 314.7067624819045) (7.3162078857421875, 331.93011077066353) (7.3038177490234375, 317.31911192728444) (7.3028564453125, 328.6625513891871) (7.4486541748046875, 162.22780650636514) (7.4460906982421875, 160.83584590219874) (7.4334869384765625, 160.79587107257777) (7.4309234619140625, 161.5651107543785) (7.429107666015625, 162.89283036676804) (7.426544189453125, 161.98284283542264) (7.4139404296875, 162.85897766376715) (7.4112701416015625, 162.33311683520293) (7.324859619140625, 323.9309882090412) (7.3100128173828125, 645.8259228418638) (7.295166015625, 324.05081262183603) (7.4486541748046875, 162.22780650636514) (7.4460906982421875, 160.83584590219874) (7.4334869384765625, 160.79587107257777) (7.4309234619140625, 161.5651107543785) (7.429107666015625, 162.89283036676804) (7.426544189453125, 161.98284283542264) (7.4139404296875, 162.85897766376715) (7.4112701416015625, 162.33311683520293) (4.0358123779296875, 652.2706443453709) (4.024169921875, 652.7939461083785) (4.0358123779296875, 652.2706443453709) (4.024169921875, 652.7939461083785) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 8689499 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=30 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.38, , <15>) (2.38, , <16>) (2.38, , <17>) (7.31,
, <18>) (7.31,
, <18>) (7.31,
, <18>) (7.31,
, <18>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.43, , <19>) (7.31,
, <20>) (7.31,
, <20>) (7.31,
, <20>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (7.43, , <21>) (4.03, , <23>) (4.03, , <23>) (4.03, , <24>) (4.03, , <24>) ##END= ##END=