##TITLE=NP0000008, Submission ID 306, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Berberine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C20 H18 N O4+ ##ATOMLIST= 1 C 0 2 O 0 3 C 0 4 C 0 5 C 0 6 C 0 7 C 0 8 C 0 9 N 0 10 C 0 11 C 0 12 C 0 13 O 0 14 C 0 15 C 0 16 C 0 17 C 0 18 C 0 19 C 0 20 C 0 21 C 0 22 C 0 23 O 0 24 C 0 25 O 0 26 H 0 27 H 0 28 H 0 29 H 0 30 H 0 31 H 0 32 H 0 33 H 0 34 H 0 35 H 0 36 H 0 37 H 0 38 H 0 39 H 0 40 H 0 41 H 0 42 H 0 43 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 4 5 S 5 6 D 6 7 S 7 8 D 8 9 S 9 10 D 10 11 S 11 12 D 12 13 S 13 14 S 9 15 S 15 16 S 16 17 S 17 18 D 18 19 S 19 20 D 20 21 S 21 22 D 20 23 S 23 24 S 24 25 S 12 3 S 22 17 S 11 6 S 25 19 S 22 8 S 1 26 S 1 27 S 1 28 S 4 29 S 5 30 S 7 31 S 10 32 S 14 33 S 14 34 S 14 35 S 15 36 S 15 37 S 16 38 S 16 39 S 18 40 S 21 41 S 24 42 S 24 43 S ##CHARGE= +1 9 ##$MOLFILE= RDKit 3D 43 47 0 0 0 0 0 0 0 0999 V2000 -5.9601 -2.4283 -0.1872 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2946 -1.2021 0.1523 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.9020 -1.1655 0.0949 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1820 -2.2674 -0.2750 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8049 -2.2582 -0.3399 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1207 -1.1021 -0.0226 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2550 -1.0798 -0.0834 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9093 0.0949 0.2410 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2267 1.1833 0.6050 N 0 0 0 0 0 4 0 0 0 0 0 0 -1.1409 1.1441 0.6603 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8591 0.0117 0.3518 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2482 -0.0127 0.4127 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9106 1.1415 0.7956 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.2878 2.0556 -0.1990 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7897 2.4621 0.9654 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2601 2.5621 0.9239 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9754 1.3337 0.5157 C 0 0 0 0 0 0 0 0 0 0 0 0 4.3631 1.3664 0.4574 C 0 0 0 0 0 0 0 0 0 0 0 0 5.1159 0.2716 0.0879 C 0 0 0 0 0 0 0 0 0 0 0 0 4.4621 -0.9026 -0.2364 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0836 -0.9727 -0.1900 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3597 0.1508 0.1868 C 0 0 0 0 0 0 0 0 0 0 0 0 5.4558 -1.8207 -0.5641 O 0 0 0 0 0 0 0 0 0 0 0 0 6.6806 -1.1452 -0.7899 C 0 0 0 0 0 0 0 0 0 0 0 0 6.4875 0.0442 -0.0485 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.8822 -2.6277 -1.2756 H 0 0 0 0 0 0 0 0 0 0 0 0 -7.0211 -2.3921 0.1022 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4950 -3.2553 0.4209 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.6923 -3.1938 -0.5311 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.2340 -3.1257 -0.6313 H 0 0 0 0 0 0 0 0 0 0 0 0 0.7336 -1.9895 -0.3831 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.7129 2.0247 0.9557 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.0105 3.1006 0.0413 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.8272 1.8360 -1.1946 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4024 2.0656 -0.3370 H 0 0 0 0 0 0 0 0 0 0 0 0 0.3460 3.1903 0.2201 H 0 0 0 0 0 0 0 0 0 0 0 0 0.3588 2.8200 1.9483 H 0 0 0 0 0 0 0 0 0 0 0 0 2.7053 2.9180 1.8899 H 0 0 0 0 0 0 0 0 0 0 0 0 2.5812 3.3461 0.1738 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8580 2.3045 0.7179 H 0 0 0 0 0 0 0 0 0 0 0 0 2.6602 -1.9198 -0.4567 H 0 0 0 0 0 0 0 0 0 0 0 0 7.5581 -1.7138 -0.4260 H 0 0 0 0 0 0 0 0 0 0 0 0 6.7626 -0.8527 -1.8597 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 2 0 6 7 1 0 7 8 2 0 8 9 1 0 9 10 2 0 10 11 1 0 11 12 2 0 12 13 1 0 13 14 1 0 9 15 1 0 15 16 1 0 16 17 1 0 17 18 2 0 18 19 1 0 19 20 2 0 20 21 1 0 21 22 2 0 20 23 1 0 23 24 1 0 24 25 1 0 12 3 1 0 22 17 1 0 11 6 1 0 25 19 1 0 22 8 1 0 1 26 1 0 1 27 1 0 1 28 1 0 4 29 1 0 5 30 1 0 7 31 1 0 10 32 1 0 14 33 1 0 14 34 1 0 14 35 1 0 15 36 1 0 15 37 1 0 16 38 1 0 16 39 1 0 18 40 1 0 21 41 1 0 24 42 1 0 24 43 1 0 M CHG 1 9 1 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##.SHIFT REFERENCE=INTERNAL,TMS,116570.00,0.0 ##XUNITS=PPM ##FIRSTX=10.683560627940624 ##LASTX=-1.3290067141268507 ##MINX=-1.3290067141268507 ##MAXX=10.683560627940624 ##XFACTOR=9.164931481464578e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY 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-13792AkjJJJ%jjJJ%%j%j%JJ%jJ%%jj%J%J%J%jkjJK%%j%%%J%%j%j%%J%%jJ%%%jjJJJJ%%j%j%J% -13865AJjjj%JJ%%%j%%%%%J%%kj%K%%k%JKJjk%%JJjjJ%%%jJJ%%j%%j%%JJjj%JJkj%JJ%j%%%J%% -13938@%j%JJ%jj%%JJ%j%%%%%%%%%%J%jjj%JK%jJ%%jj%%J%%j%JJ%%k%KJ%jj%%JJ%Jj%j%jjjJKJ -14011Bjj%J%j%JJjj%K%jk%JJ%%Jj%jJ%%j%%%%jJKJkk%KJjj%JJjjjJ%%%%%%JKJkkjJ%j%JJ%j%J -14084AJ%jjJ%%%%j%%%J%jj%J%JJ%%j%j%%%%%%j%%JJj%j%J%J%%j%JJjkj%KJjj%JJJ%%jjjJJ%%j -14157@j%%J%J%%%%j%%%%j%JJ%jj%JJ%j%j%J%%%JJjjjj%KJ%jj%JJ%jjJJJjkj%JJ%j%%%%%%J%%% -14230@J%jjJJ%%j%JJ%jjjJ%%%%J%j%jJ%%%%jJ%%J%%%jjJ%Jjj%%J%%%%%jj%KJ%j%J%%jjJJ%j%% -14303@%%%%%%%%j%JJjj%JJ%j%%%%%%%j%%JJ%jjJ%%%%%%%%%Jj%%Jj%%%J%j%j%%%J%Jj%%%J%jj% -14376a%%J%%%%%j%JJ%%j%j%%JJ%%j%%%jJJ%%j%%%%jJ%j%%KJjjjJJ%j%%%%%%%j%%J%jjJJJ%%%% -14449A%%jjjJKJ%kk%JJ%%%%J%%jj%%J%%%%%%%%J%%j%J%j%%Jjj%JK%j -14501A $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=28 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (4.100006103515625, 2507.317180227267) (4.100006103515625, 2507.317180227267) (4.100006103515625, 2507.317180227267) (8.10906982421875, 1252.9973956459244) (8.090911865234375, 1253.0400984732175) (7.999053955078125, 1252.8945008885648) (7.98089599609375, 1252.9316082886994) (8.690017700195312, 2506.459222132886) (9.760055541992188, 2505.3738206836747) (4.199981689453125, 2506.4592221328858) (4.199981689453125, 2506.4592221328858) (4.199981689453125, 2506.4592221328858) (4.9427490234375, 635.0169845635883) (4.9300384521484375, 1258.892412985727) (4.9172210693359375, 634.8064537476915) (4.9427490234375, 635.0169845635883) (4.9300384521484375, 1258.892412985727) (4.9172210693359375, 634.8064537476915) (3.2627105712890625, 635.0756042503176) (3.25, 1261.247806844592) (3.2372894287109375, 635.107333678294) (3.2627105712890625, 635.0756042503176) (3.25, 1261.247806844592) (3.2372894287109375, 635.107333678294) (6.950004577636719, 1253.7658807562525) (7.63995361328125, 2506.0511598968087) (6.099998474121094, 1253.8016483839488) (6.099998474121094, 1253.8016483839488) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 15040083 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=28 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (4.1, , <26>) (4.1, , <27>) (4.1, , <28>) (8.1, , <29>) (8.1, , <29>) (7.99, , <30>) (7.99, , <30>) (8.69, , <31>) (9.76, , <32>) (4.2, , <33>) (4.2, , <34>) (4.2, , <35>) (4.93, , <36>) (4.93, , <36>) (4.93, , <36>) (4.93, , <37>) (4.93, , <37>) (4.93, , <37>) (3.25, , <38>) (3.25, , <38>) (3.25, , <38>) (3.25, , <39>) (3.25, , <39>) (3.25, , <39>) (6.95, , <40>) (7.64, , <41>) (6.1, , <42>) (6.1, , <43>) ##END= ##END=