##TITLE=NP0001065, Submission ID 273, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Theobromine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C7 H8 N4 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 N 0 5 C 0 6 C 0 7 C 0 8 O 0 9 N 0 10 C 0 11 O 0 12 N 0 13 C 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 4 5 S 5 6 D 6 7 S 7 8 S 7 9 D 9 10 S 10 11 D 10 12 S 12 13 S 6 2 S 12 5 S 1 14 S 1 15 S 1 16 S 3 17 S 8 18 S 13 19 S 13 20 S 13 21 S ##$MOLFILE= RDKit 3D 21 22 0 0 0 0 0 0 0 0999 V2000 -2.9600 -0.2018 -0.1805 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5874 -0.6293 -0.0383 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.1227 -1.8830 0.1212 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2315 -1.8698 0.2177 N 0 0 0 0 0 0 0 0 0 0 0 0 0.6134 -0.5779 0.1156 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5281 0.1994 -0.0449 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3928 1.5664 -0.1724 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5434 2.3152 -0.3308 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8428 2.0904 -0.1357 N 0 0 0 0 0 0 0 0 0 0 0 0 1.9312 1.3020 0.0221 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1068 1.7835 0.0587 O 0 0 0 0 0 0 0 0 0 0 0 0 1.8446 -0.0345 0.1500 N 0 0 0 0 0 0 0 0 0 0 0 0 3.0293 -0.8547 0.3180 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6694 -0.9571 0.2673 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.1771 0.7445 0.3634 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.2159 -0.1448 -1.2584 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.7798 -2.7444 0.1602 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5809 3.2257 -0.7712 H 0 0 0 0 0 0 0 0 0 0 0 0 2.7159 -1.9304 0.2149 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4406 -0.7336 1.3575 H 0 0 0 0 0 0 0 0 0 0 0 0 3.8011 -0.6658 -0.4344 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 2 0 6 7 1 0 7 8 1 0 7 9 2 0 9 10 1 0 10 11 2 0 10 12 1 0 12 13 1 0 6 2 1 0 12 5 1 0 1 14 1 0 1 15 1 0 1 16 1 0 3 17 1 0 8 18 1 0 13 19 1 0 13 20 1 0 13 21 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##.SHIFT REFERENCE=INTERNAL,TMS,116782.00,0.0 ##XUNITS=PPM ##FIRSTX=10.702990282681323 ##LASTX=-1.3095770593861502 ##MINX=-1.3095770593861502 ##MAXX=10.702990282681323 ##XFACTOR=9.164931481464578e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.03670395369287135 ##LASTY=-0.1028056200126411 ##MINY=-0.8317039791091222 ##MAXY=10000.000000000002 ##YFACTOR=0.30518509475997196 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 116782@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116709@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116636@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116563@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116490@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116417@%%%%%%%%%%%%%%%%%%%%%J%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116344@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116271@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116198@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116125@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116052@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115979@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115906@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115833@%%%%%%j%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%%% 115760@%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%J%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%j% 115687a%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115614@%%j%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%% 115541@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%% 115468@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115395@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115322@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115249@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115176@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%%%%%%j%%%%%%%%%% 115103@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115030@%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%j%%%J%%%%%%%%%%%%j%%%%J%%%%%%%%%% 114957@%%%%%%%%%%%J%%%%%%j%%%%%%%%%%%%%j%%%%%%%J%%j%%%J%%%%%%%%%j%%%%J%%%%%jJ%%% 114884@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%% 114811@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%% 114738@%%j%%%%%%%J%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%% 114665@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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1197@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%J%%%J%%%%%%% 1122B%J%%%%%%%%%%%%%%%J%%%J%JJJ%JJ%%%%%jJ%%JJ%JJJJJKJKKKKLLKLLLLLKKJJ%jjjlkmllml 1047C2lllllkkkjkj%jj%j%j%%j%%%j%%%%%%%%%%%%%%%%%%%%%J%%%%%%%j%%%%%%%j%%%%%%%%%%% 973@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%j%%%%%%%%%j%%%%%%%%%%%%%%% 897b%%%J%%%%%%%%%%%%%j%%%%%%J%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%J%%%%%%% 821@%%%j%%%%%%%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%% 745@%%%%%%%%%%%%%%%%j%%%%%%%%J%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 669@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%j%%%% 593b%%%%%%%%%%%%%%%%J%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%j%%%j%%J%j%%%%J%%%%j 517cJ%%%J%J%%%%J%%%%j%%%%%%%%%%%%%%j%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%% 441a%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%J%%%J%%%%J%%%%%%%%%%%j%J%%%%%%j%%%%%%%%%%%%% 365A%%%%%%%%j%J%%%%%%%%%J%%%J%%%%%%%%%%%%j%%%j%%J%%%%%%%%%Jj%J%%%%%%%%%%%%%%%%%% 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-10182@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%% -10255@j%%J%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j% -10328a%%%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -10401@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%j%%%%%%%%%%%%%%%j -10474a%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%% -10547@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%% -10620@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%J%%j%%%%J%%%%%%%%%%%j%%%% -10693a%%%%%%J%%%%%%%%%%j%%%%%%%J%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%j%%%%%%%J%%%%j%J% -10766@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%j%%%%%%%%%%%%J%%%%%%%%%%%%%% -10839@%%j%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%% -10912@j%%%J%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -10985@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%%%%%%%%%% -11058@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%j -11131aJ%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -11204@%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%% -11277@%%%%J%%%%j%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%% -11350@J%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -11423@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%% -11496@%%%%J%%%%%%j%%j%%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%J%%%j%%%%%%%% -11569@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%%%%%j%%%%%%%%%%%%%%%%%%J%%%j%%%% -11642@%Jj%%Jj%%%%%J%%j%%%%%J%%%j%%%%%%%%jJ%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%% -11715@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%% -11788@%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -11861@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%J%%%%%%%%%%%%%%%% -11934@%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%%%J%%%%%%%j%%%%%%%%%%%%%%%%% -12007@J%%%%%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%% -12080@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%%%%%%% -12153@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12226@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12299@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12372@%%%%%%%J%j%%%%%%%%%%%%%%j%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12445@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12518@%%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%j%%%J%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%% -12591@%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12664@%%%%%%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%% -12737@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12810@%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%% -12883@%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -12956@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%% -13029@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13102@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13175@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13248@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13321@%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13394@%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13467@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13540@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13613@%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13686@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13759@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13832@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13905@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13978@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14051@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14124@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14197@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14270@%%%%%%%%%%%%%%%%%%% -14289@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##NPOINTS=7 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.8499603271484375, 3333.3333333333344) (3.8499603271484375, 3333.3333333333344) (3.8499603271484375, 3333.3333333333344) (7.970001220703125, 3339.4193422415415) (3.3400421142578125, 3333.3333333333344) (3.3400421142578125, 3333.3333333333344) (3.3400421142578125, 3333.3333333333344) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 8445222 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##NPOINTS=7 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.85, , <14>) (3.85, , <15>) (3.85, , <16>) (7.97, , <17>) (3.34, , <19>) (3.34, , <20>) (3.34, , <21>) ##END= ##END= ##TITLE=NP0001065, Submission ID 273, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Theobromine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C7 H8 N4 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 N 0 5 C 0 6 C 0 7 C 0 8 O 0 9 N 0 10 C 0 11 O 0 12 N 0 13 C 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 4 5 S 5 6 D 6 7 S 7 8 S 7 9 D 9 10 S 10 11 D 10 12 S 12 13 S 6 2 S 12 5 S 1 14 S 1 15 S 1 16 S 3 17 S 8 18 S 13 19 S 13 20 S 13 21 S ##$MOLFILE= RDKit 3D 21 22 0 0 0 0 0 0 0 0999 V2000 -2.9600 -0.2018 -0.1805 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5874 -0.6293 -0.0383 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.1227 -1.8830 0.1212 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2315 -1.8698 0.2177 N 0 0 0 0 0 0 0 0 0 0 0 0 0.6134 -0.5779 0.1156 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5281 0.1994 -0.0449 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3928 1.5664 -0.1724 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5434 2.3152 -0.3308 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8428 2.0904 -0.1357 N 0 0 0 0 0 0 0 0 0 0 0 0 1.9312 1.3020 0.0221 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1068 1.7835 0.0587 O 0 0 0 0 0 0 0 0 0 0 0 0 1.8446 -0.0345 0.1500 N 0 0 0 0 0 0 0 0 0 0 0 0 3.0293 -0.8547 0.3180 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6694 -0.9571 0.2673 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.1771 0.7445 0.3634 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.2159 -0.1448 -1.2584 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.7798 -2.7444 0.1602 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5809 3.2257 -0.7712 H 0 0 0 0 0 0 0 0 0 0 0 0 2.7159 -1.9304 0.2149 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4406 -0.7336 1.3575 H 0 0 0 0 0 0 0 0 0 0 0 0 3.8011 -0.6658 -0.4344 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 2 0 6 7 1 0 7 8 1 0 7 9 2 0 9 10 1 0 10 11 2 0 10 12 1 0 12 13 1 0 6 2 1 0 12 5 1 0 1 14 1 0 1 15 1 0 1 16 1 0 3 17 1 0 8 18 1 0 13 19 1 0 13 20 1 0 13 21 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##.SHIFT REFERENCE=INTERNAL,TMS,116782.00,0.0 ##XUNITS=PPM ##FIRSTX=10.702990282681323 ##LASTX=-1.3095770593861502 ##MINX=-1.3095770593861502 ##MAXX=10.702990282681323 ##XFACTOR=9.164931481464578e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.03670395369287135 ##LASTY=-0.1028056200126411 ##MINY=-0.8317039791091222 ##MAXY=10000.000000000002 ##YFACTOR=0.30518509475997196 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 116782@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116709@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116636@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116563@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116490@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116417@%%%%%%%%%%%%%%%%%%%%%J%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116344@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116271@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116198@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116125@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 116052@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115979@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115906@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115833@%%%%%%j%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%%% 115760@%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%J%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%j% 115687a%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115614@%%j%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%% 115541@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%% 115468@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115395@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115322@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115249@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115176@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%%%%%%j%%%%%%%%%% 115103@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 115030@%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%%%%j%%%J%%%%%%%%%%%%j%%%%J%%%%%%%%%% 114957@%%%%%%%%%%%J%%%%%%j%%%%%%%%%%%%%j%%%%%%%J%%j%%%J%%%%%%%%%j%%%%J%%%%%jJ%%% 114884@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%% 114811@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%% 114738@%%j%%%%%%%J%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%% 114665@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 114592@%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 114519@%%%%%%%%%J%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 114446@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%J%%%%%%%%%%%%%%J%%%j 114373@%%%%%%%%J%%%%%%j%%%%%%%%%%%%%%j%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%% 114300A%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%% 114227a%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 114154@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 114081@%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j% 114008@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%%%%%%%%%%%J%%j%%%J%%%%%%%%%%%% 113935@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%%%%%%% 113862@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%% 113789@%%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%%%%%%%%%%j%%%%%%%%%%%%% 113716@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 113643@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 113570@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 113497@%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%% 113424@j%%J%%%%%%%%%%%J%%%%%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 113351@%%%%%%%%%%%%%%j%%%%%%%%%J%%%%%%j%J%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%j%%%%%% 113278a%J%%j%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 113205@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j 113132@%%%%%%%%J%%%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%J%%%j%%%%% 113059@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%% 112986@%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 112913@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%j%%%%%% 112840@%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 112767@%%%%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%%%J%%%%%%%% 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-12956@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%J%%%%%%%%%%%%%%% -13029@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13102@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13175@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13248@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13321@%%%%%%%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13394@%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13467@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13540@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13613@%%%%%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13686@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13759@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13832@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13905@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -13978@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14051@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14124@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14197@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -14270@%%%%%%%%%%%%%%%%%%% -14289@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##NPOINTS=7 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.8499603271484375, 3333.3333333333344) (3.8499603271484375, 3333.3333333333344) (3.8499603271484375, 3333.3333333333344) (7.970001220703125, 3339.4193422415415) (3.3400421142578125, 3333.3333333333344) (3.3400421142578125, 3333.3333333333344) (3.3400421142578125, 3333.3333333333344) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 8445222 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=DMSO ##NPOINTS=7 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.85, , <14>) (3.85, , <15>) (3.85, , <16>) (7.97, , <17>) (3.34, , <19>) (3.34, , <20>) (3.34, , <21>) ##END= ##END=