##TITLE=NP0000158, Submission ID 271, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Methyl hippurate ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H11 N O3 ##ATOMLIST= 1 C 0 2 O 0 3 C 0 4 O 0 5 C 0 6 N 0 7 C 0 8 O 0 9 C 0 10 C 0 11 C 0 12 C 0 13 C 0 14 C 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 25 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 3 5 S 5 6 S 6 7 S 7 8 D 7 9 S 9 10 D 10 11 S 11 12 D 12 13 S 13 14 D 14 9 S 1 15 S 1 16 S 1 17 S 5 18 S 5 19 S 6 20 S 10 21 S 11 22 S 12 23 S 13 24 S 14 25 S ##$MOLFILE= RDKit 3D 25 25 0 0 0 0 0 0 0 0999 V2000 -5.2446 0.5029 0.9386 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2936 0.2318 -0.0892 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.9504 0.2408 0.1771 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6077 0.5020 1.3798 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.8994 -0.0310 -0.8369 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5804 0.0541 -0.2410 N 0 0 0 0 0 0 0 0 0 0 0 0 0.5684 -0.1711 -1.0344 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4022 -0.4435 -2.2560 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9122 -0.0973 -0.4841 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1689 0.1937 0.8348 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4722 0.2485 1.2947 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5189 0.0141 0.4439 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2704 -0.2787 -0.8817 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9932 -0.3336 -1.3378 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2430 0.7602 0.4806 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.9495 1.3636 1.5623 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.3882 -0.4222 1.5517 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0659 -1.0497 -1.2619 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0364 0.7108 -1.6494 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5131 0.2806 0.7631 H 0 0 0 0 0 0 0 0 0 0 0 0 1.3392 0.3804 1.5132 H 0 0 0 0 0 0 0 0 0 0 0 0 3.6715 0.4809 2.3471 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5483 0.0470 0.7615 H 0 0 0 0 0 0 0 0 0 0 0 0 5.0828 -0.4704 -1.5849 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8238 -0.5675 -2.3913 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 3 5 1 0 5 6 1 0 6 7 1 0 7 8 2 0 7 9 1 0 9 10 2 0 10 11 1 0 11 12 2 0 12 13 1 0 13 14 2 0 14 9 1 0 1 15 1 0 1 16 1 0 1 17 1 0 5 18 1 0 5 19 1 0 6 20 1 0 10 21 1 0 11 22 1 0 12 23 1 0 13 24 1 0 14 25 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##.SHIFT REFERENCE=INTERNAL,TMS,116565.00,0.0 ##XUNITS=PPM ##FIRSTX=10.68310238136655 ##LASTX=-1.3294649607009221 ##MINX=-1.3294649607009221 ##MAXX=10.68310238136655 ##XFACTOR=9.164931481464578e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.2686363836888079 ##LASTY=-0.21205662167996203 ##MINY=-163.16564836149894 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 116565a%%%%%%%J%%J%%%%%%%%%j%%%j%%%%%%J%JJ%%%%%j%j%%%%%Jj%%%%%%%%%%%%%j%J%%%%%%% 116492@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%j%%%%%%J%%%%%j%%%j%%%%%%%%%%%%%J%%% 116419@%%%%%%%%J%%J%%%j%%%%%%%%j%%%j%%%j%%%%%%J%%J%%%%J%%%%%%%j%%%%%J%%%%j%%%%%% 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-11050A%%%J%%%j%j%j%j%%j%%%%%%%%JJJ%J%%%%%%%j%%%%j%%J%%%J%J%J%%j%j%%%%%%JJJJ%%%% -11123Ejjjjjj%j%j%%%%%%J%J%J%J%%%%%J%%%%%j%j%%%%%%j%%jj%j%%%%%J%J%JJ%%%%%%j%%%%% -11196aJ%J%%J%%%%%%%%j%j%%jJ%J%J%%%%%%j%%j%%%%%%%%%%%%%%%%%%J%%J%%%%%j%%j%%%j%j% -11269b%%%J%J%%%%J%%j%%%%%%%J%%%%%%%%%%%%%%jJ%%%j%j%j%%%%%%%%%%j%%J%J%J%%%%%J%J% -11342BJ%J%%%j%%jj%j%%j%%%%%%%%%J%%J%J%%%j%j%%%j%%%%%%%%J%%%%%%%%%%%%%%%%J%%%%%% -11415A%%%%%J%%J%%%j%jjjjj%%%%JJ%J%%j%%%J%%J%J%J%J%J%J%J%JJ%Jj%%j%j%j%j%%%%%%%%j -11488D%%%%%%%%j%j%jj%%j%%%%%%J%JJ%J%%j%j%j%%%%j%jj%%%%%J%%%j%j%%%%j%%%%%%jj%%%J -11561fJ%JJJJJJ%J%%j%j%jj%j%%%%%%%%j%%J%J%JJ%J%%J%%%%j%jjj%j%j%%%%%%%%%%%j%jj%%% -11634gJ%JJ%J%%%J%%JJ%J%%J%%JJ%J%%%jj%j%j%%j%%j%%%%%%%%%j%%%%%%%%J%J%j%%j%%%%%J% -11707aJ%J%J%%%%%j%jj%j%%%%J%%Jj%%%j%j%%%J%%J%%%j%%j%%%%%JJJ%J%J%J%%%j%j%j%%%%%% -11780@J%%%%%%%%%j%j%%%%%%%%J%%%%%%J%%%j%%%%%%%j%%%j%%%%%J%J%J%%%j%j%%%J%J%%J%%% -11853B%%j%%%%%%%%%%j%%j%%%%%%%%J%J%%%%jj%j%j%j%jj%j%%j%J%%%J%JJJJJJJJJ%%%%%%jjj -11926@%j%j%j%%J%%J%J%JJ%J%%jj%j%%%%%%%%%%%%%%%%%%%%%%J%%j%%jj%j%%%%J%%J%%%J%J%% -11999A%%%J%%%%J%%%%j%%%j%j%j%%j%%j%%%%j%%%%J%%%J%%%JJJJJJJJJJJ%J%%%%%%j%%%j%%jj -12072F%jjj%j%%%%j%%%%%j%%%%%%J%%j%%j%%%J%%%J%j%%%%%%%J%J%%%%%%%j%%j%j%%%%%J%%%% -12145@%%%%%%%j%%%%%%%%%%J%J%%%j%%j%%%JJ%J%%%%j%jjjjj%j%%j%%%%j%J%%%%%%%j%%%%%JJ -12218e%JJ%J%%%j%%%%J%JJJJ%%%%%%j%j%%j%%%%J%%j%%j%%%jJ%%%J%%%%%%%J%%%J%%%%%%%%j% -12291@%%%%J%%%J%%%j%j%j%%%%%%%%%%%%%%%J%%%J%%%%%%%%j%%%%%%%%J%%%%%%%J%%%%j%j%j% -12364aj%%%%%%%J%%%%%%%%%%J%J%J%JJ%%%J%%%%%%j%j%%jJ%JJ%J%%%%j%%j%%%%%J%J%%%%%jj% -12437Djj%j%%j%%%J%%%%%%%j%%%%j%%%%%%%J%%%J%%%%%%%%%%%j%%%%%%%%%%J%J%%%%%%%jjjj% -12510bj%j%J%JJJJ%%%j%j%%%%J%%%%%j%jj%%%J%%%%%J%%%%%J%J%J%%%%j%j%%%%%J%J%%j%j%%% -12583@j%%%%%%%%%%%%%%%J%%%%%%%%%%JJ%J%J%%%j%jjjj%jj%%%%%%%%%J%%J%J%J%%%%Jj%%J%% -12656B%J%JJ%%%%%%jj%jj%%j%%%j%j%j%%%j%%J%%JJ%J%%Jj%%%%%J%%%%%%%%J%%%%%%j%%j%%%% -12729@%%%%%%%%%%%%%%j%%%%%%jJ%%%%%%%%%%%%J%%J%%J%%%%%j%%%%j%%j%%j%J%%%%%%%%%%%J -12802@%J%%%%%j%%%%%J%J%%J%%%j%%j%%j%%%J%%%%%j%j%%%%%%%j%%%%%%%%%J%%J%%j%%j%J%JJ -12875A%J%%Jj%%%%%%%j%%j%j%%%%%%%%%%%%%%J%J%J%J%%%%%j%jkjjkjj%%%%JJ%JJ%JJJJJ%J%J -12948D%%J%%%%%j%j%j%%%%%j%jjjj%%JJJJJJ%J%%%%%%%%j%jjj%j%j%%%%J%J%J%J%%J%J%J%%%% -13021Ej%jj%%j%%%%%j%jjj%j%%%%J%%%%J%%%%%J%%%%%%%%J%J%J%%%%j%%%%j%%j%%%%%J%%J%%% -13094A%%%%%j%%j%j%%jJ%JJ%JJ%%%%j%j%%%%%%%%%%%%%%%%%%%%j%%J%%%%j%%j%%%%J%%J%J%J% -13167B%%%%j%j%j%%%%%%J%%%J%%%j%%%%%j%%%%%%j%%%J%%%%%J%%%%%%%J%J%J%%j%%%%%%%%j%% -13240A%%%%%%j%j%j%%%%J%%%%%%%%%%J%%%%%%%j%J%%%J%%%j%j%%%%%%J%J%J%%%j%%%%%j%%%%% -13313@%%%J%%%%j%%j%j%%%%%%J%%J%J%J%%%%%%%j%%j%%jJ%%%%%%%%j%J%%%%%%%j%j%%J%%J%%J -13386A%%%%%%%%%%%%%%%%%j%%j%j%%j%%%J%J%JJ%%%J%%j%%%%%%J%%%%%%%j%%j%%%%j%%%j%%%% -13459b%%%%%%J%%%%J%J%%J%%j%%j%%%%%%%%%J%%J%%%%%%jjj%%j%%%J%%%%%%%%%J%%%J%%%j%%% -13532@%%%%%%j%%%J%JJ%J%j%jj%j%jJ%%%%%%%%%%%%Jj%%%%J%%%%j%%%%J%J%J%%Jj%%j%%%%%j% -13605@%%j%%%%%%%J%%%J%%%%%%%%%%%%%%j%%%%%%%%%%%%J%%%j%j%%j%%J%%J%%%%%%j%%%%%%%% -13678a%%%%%%J%%%%%%%%%%%%%%J%%%%%%%%%%%%j%%%%%%%%%%J%%%%%%j%%j%%%%%J%%J%%%%j%j% -13751aj%%J%%%J%%%%%J%%%%j%%%j%J%%%%%%%%%%J%%J%%%%%%%%j%%%j%j%j%j%%J%J%J%J%%%%%% -13824AJ%%j%%j%j%j%%%%%%%%%%j%J%J%JJ%J%%Jj%%%%j%j%j%%J%%%%%%%%%%%%%J%%%%%%%%j%%% -13897@%%%%%%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%J%J%%J%%%%j%% -13970Aj%%%%%%%%%%%j%%%J%%%J%%j%%j%%%%%%%%J%%%%%%%%J%j%%%%%%%%%%%%%j%%%%%%J%%J%% -14043A%%%%%j%%%%%%J%%%%%%j%%j%%%%%%%J%%J%%%j%%%%%%%%%%%%j%%%%J%%%%%%%j%%J%%%%%% -14116@%%%%%%%%%%%%%%%%%%%%%%%%%J%%%j%j%%%%%%%J%%%%%%J%%%%%%%%%%j%%%%%%%%%j%j%%% -14189b%%J%J%%J%%%%%%j%%%%j%%%J%%%%J%%%J%%%%j%%j%%%j%%%%%%%%%%%J%j%%%%%%J%%%%J%% -14262A%J%%%j%%j%%%j%%%%%%J%%%%%%%%%%J%%%%%%%j%%j%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%% -14335@%J%%%%%%j%%%%%%%%%%%%%%%j%j%%%%J%J%J%%J%%%%j%jj%j%%j%%%%%%%%%J%J%J%%J%%%% -14408Aj%%j%%j%%%%%%%J%%J%%%J%%%%%%%j%%j%%%J%%j%%%%%%%J%%%%%%%%%J%%%%%%%%%%j%%j% -14481a%%%%%%J%%%%%%%%%%J%%%j%%j -14506a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=36 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.7499847412109375, 2519.8959518522543) (3.7499847412109375, 2519.8959518522543) (3.7499847412109375, 2519.8959518522543) (4.1199798583984375, 2519.033689532218) (4.1199798583984375, 2519.033689532218) (7.859771728515625, 634.1069186695911) (7.8571014404296875, 631.0063992582528) (7.8428955078125, 631.0326472457319) (7.8402252197265625, 634.1544902063408) (7.4945831298828125, 328.62893815463605) (7.493621826171875, 298.3253431510861) (7.481231689453125, 340.5995875379867) (7.479949951171875, 610.7484191990729) (7.4787750244140625, 310.26456331782674) (7.4663848876953125, 295.32756229020214) (7.465423583984375, 331.3181228421293) (7.557281494140625, 155.13689790398828) (7.5548248291015625, 315.3327517267279) (7.5522613525390625, 157.7969705268267) (7.54254150390625, 316.54890555612155) (7.53997802734375, 631.2332280961152) (7.5375213623046875, 311.1968716862668) (7.5276947021484375, 153.68311935556977) (7.525238037109375, 314.9042864462423) (7.522674560546875, 159.79807159720198) (7.4969329833984375, 316.6480929339144) (7.4959716796875, 310.4629757589573) (7.481231689453125, 307.59064009906757) (7.4800567626953125, 610.1118539482633) (7.4787750244140625, 343.8174538417048) (7.4640350341796875, 307.2276301823248) (7.46307373046875, 319.4395922756181) (7.859771728515625, 634.1069186695911) (7.8571014404296875, 631.0063992582528) (7.8428955078125, 631.0326472457319) (7.8402252197265625, 634.1544902063408) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 8689499 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=36 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.75, , <15>) (3.75, , <16>) (3.75, , <17>) (4.12, , <18>) (4.12, , <19>) (7.85,
, <21>) (7.85,
, <21>) (7.85,
, <21>) (7.85,
, <21>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.85,
, <25>) (7.85,
, <25>) (7.85,
, <25>) (7.85,
, <25>) ##END= ##END= ##TITLE=NP0000158, Submission ID 271, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Methyl hippurate ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H11 N O3 ##ATOMLIST= 1 C 0 2 O 0 3 C 0 4 O 0 5 C 0 6 N 0 7 C 0 8 O 0 9 C 0 10 C 0 11 C 0 12 C 0 13 C 0 14 C 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 25 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 3 5 S 5 6 S 6 7 S 7 8 D 7 9 S 9 10 D 10 11 S 11 12 D 12 13 S 13 14 D 14 9 S 1 15 S 1 16 S 1 17 S 5 18 S 5 19 S 6 20 S 10 21 S 11 22 S 12 23 S 13 24 S 14 25 S ##$MOLFILE= RDKit 3D 25 25 0 0 0 0 0 0 0 0999 V2000 -5.2446 0.5029 0.9386 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2936 0.2318 -0.0892 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.9504 0.2408 0.1771 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6077 0.5020 1.3798 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.8994 -0.0310 -0.8369 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5804 0.0541 -0.2410 N 0 0 0 0 0 0 0 0 0 0 0 0 0.5684 -0.1711 -1.0344 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4022 -0.4435 -2.2560 O 0 0 0 0 0 0 0 0 0 0 0 0 1.9122 -0.0973 -0.4841 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1689 0.1937 0.8348 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4722 0.2485 1.2947 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5189 0.0141 0.4439 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2704 -0.2787 -0.8817 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9932 -0.3336 -1.3378 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2430 0.7602 0.4806 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.9495 1.3636 1.5623 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.3882 -0.4222 1.5517 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0659 -1.0497 -1.2619 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0364 0.7108 -1.6494 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5131 0.2806 0.7631 H 0 0 0 0 0 0 0 0 0 0 0 0 1.3392 0.3804 1.5132 H 0 0 0 0 0 0 0 0 0 0 0 0 3.6715 0.4809 2.3471 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5483 0.0470 0.7615 H 0 0 0 0 0 0 0 0 0 0 0 0 5.0828 -0.4704 -1.5849 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8238 -0.5675 -2.3913 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 3 5 1 0 5 6 1 0 6 7 1 0 7 8 2 0 7 9 1 0 9 10 2 0 10 11 1 0 11 12 2 0 12 13 1 0 13 14 2 0 14 9 1 0 1 15 1 0 1 16 1 0 1 17 1 0 5 18 1 0 5 19 1 0 6 20 1 0 10 21 1 0 11 22 1 0 12 23 1 0 13 24 1 0 14 25 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##.SHIFT REFERENCE=INTERNAL,TMS,116565.00,0.0 ##XUNITS=PPM ##FIRSTX=10.68310238136655 ##LASTX=-1.3294649607009221 ##MINX=-1.3294649607009221 ##MAXX=10.68310238136655 ##XFACTOR=9.164931481464578e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.2686363836888079 ##LASTY=-0.21205662167996203 ##MINY=-163.16564836149894 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 116565a%%%%%%%J%%J%%%%%%%%%j%%%j%%%%%%J%JJ%%%%%j%j%%%%%Jj%%%%%%%%%%%%%j%J%%%%%%% 116492@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%j%%%%%%J%%%%%j%%%j%%%%%%%%%%%%%J%%% 116419@%%%%%%%%J%%J%%%j%%%%%%%%j%%%j%%%j%%%%%%J%%J%%%%J%%%%%%%j%%%%%J%%%%j%%%%%% 116346@%%%%%%%%%j%%%%%%%J%%%%%%%%%%%%%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%J%%%%%%j%%j% 116273a%%%%%%%%%%%%J%%%%%%J%%%%%%%%j%%j%%%%%%%%%J%%%%J%%j%%%%%%%%%J%%%%%%%%%j%%% 116200@%%%%%j%%%%%%%J%J%%%%%j%%j%%%%J%%%%%%j%%%%J%%J%%%%%%%%%j%%%%%%%%%%%j%%%%%% 116127a%%J%%%%J%%%%%j%j%%%%%%%J%%%%%%%%%%J%%%%%%%%%j%%%%%%%%%%%%%%J%%j%%%j%%%%%% 116054a%%%%%J%%%J%%%%%%%%%%%%j%%j%%j%%J%%%%J%%J%%J%%%j%%j%%%%%%%%%%%%%%%%%%%%%%% 115981@j%%%%%%%%%%%%%%%%%%J%%%j%%%%%J%%J%J%J%%%%j%%j%%j%%j%%%%%%%J%%%%%J%%%%%%%% 115908Aj%%%j%%%%%%J%%%j%%j%j%%%%%J%JJ%J%J%%%%j%%%%j%%%J%%%%%%%%j%%j%%%%%%%%J%%J% 115835A%%%%%%%%%%%%%j%%j%%J%%%J%%%%%%j%%%%%%%%j%%%j%%%%%%J%%J%J%%%%J%%%%%j%%j%%% 115762@j%%%%%%J%J%%%%%j%%%j%%j%%%%%J%%J%%J%%%%%%j%%%%J%%J%%j%jj%j%%%%%%%%%J%%J%% 115689@%%%%%%%J%%%%%%%%%j%%%%%j%%J%J%%J%%j%%%%%%%%%%%%j%%%%%j%%%j%%%%%%J%%J%J%%j 115616@%%j%%%%%J%%J%%%%%%j%j%j%%%%J%J%%J%%%%%%%%%%%j%%%%%%%%%%%%%j%%J%%J%%%%j%%% 115543@%j%j%%j%J%%J%J%J%%J%%%%%%%%%%j%%%%j%%j%%%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%%j% 115470a%%J%%%%%%%%%%%%%%%%%%%%%%%j%%J%%Jj%%%j%%%%%%%%J%J%%%%%jj%%j%%%%J%%%%%%JJ% 115397AJ%J%%%j%%j%%j%%%%%%%jj%j%%%%%%J%%J%j%j%j%%%J%J%%%%j%%%%%J%%J%%J%%%%%%%%%% 115324@J%%J%%%%j%%%j%%%j%j%%%%%%%%%%%J%%%J%%Jj%%J%%%%%j%%%J%%%%j%j%j%%%%%J%J%%%% 115251@%%%%J%%%%%%%%%j%%%%%j%%%%J%%J%%%%%%%%J%%%%%jj%jjj%j%%j%%%%%%%J%%JJ%JJ%%%J 115178A%j%%%%%%%%J%%%J%%jj%%j%%J%%%%J%%j%%%%%j%%%%%%%%%%%%%%%%%%%%J%%%j%%%J%J%%% 115105A%%%%%%%%%j%%%%%J%%%%j%J%%%%%%%j%%j%%%%%J%J%%%%%%j%%%%%J%%j%%%j%%J%J%%%%%% 115032Aj%%j%%%%%J%%%%%%j%%jJ%%%J%%j%%%%j%%j%%%%%J%J%JJ%J%%j%%J%%%%%%%%%%%%%j%%j% 114959@%%%%%%%%%%%%%%%%%J%%%%j%j%j%%%%%%%%%J%%%%%%%J%J%J%%%%%j%%%%%%j%%%%%%j%%%% 114886a%%J%%%%%%%%%%%%j%J%%%J%%%j%%%%%%jJ%%%J%%%j%%j%%%%%%J%%%%%%J%J%J%%%%j%%j%% 114813A%j%%%j%%j%%%%%%%J%J%%J%%%%%j%%%%j%%%%%%%J%%j%%j%%%%%%J%J%JJJ%J%j%j%j%%%j% 114740@%j%%%%%J%%J%%%%j%%j%%j%%%%%%%%%%J%%%J%J%%%%%j%%%%%%%j%j%%%%J%%J%J%%%%%%%% 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-13605@%%j%%%%%%%J%%%J%%%%%%%%%%%%%%j%%%%%%%%%%%%J%%%j%j%%j%%J%%J%%%%%%j%%%%%%%% -13678a%%%%%%J%%%%%%%%%%%%%%J%%%%%%%%%%%%j%%%%%%%%%%J%%%%%%j%%j%%%%%J%%J%%%%j%j% -13751aj%%J%%%J%%%%%J%%%%j%%%j%J%%%%%%%%%%J%%J%%%%%%%%j%%%j%j%j%j%%J%J%J%J%%%%%% -13824AJ%%j%%j%j%j%%%%%%%%%%j%J%J%JJ%J%%Jj%%%%j%j%j%%J%%%%%%%%%%%%%J%%%%%%%%j%%% -13897@%%%%%%%%%%%%%%j%%%%%%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%%%J%J%%J%%%%j%% -13970Aj%%%%%%%%%%%j%%%J%%%J%%j%%j%%%%%%%%J%%%%%%%%J%j%%%%%%%%%%%%%j%%%%%%J%%J%% -14043A%%%%%j%%%%%%J%%%%%%j%%j%%%%%%%J%%J%%%j%%%%%%%%%%%%j%%%%J%%%%%%%j%%J%%%%%% -14116@%%%%%%%%%%%%%%%%%%%%%%%%%J%%%j%j%%%%%%%J%%%%%%J%%%%%%%%%%j%%%%%%%%%j%j%%% -14189b%%J%J%%J%%%%%%j%%%%j%%%J%%%%J%%%J%%%%j%%j%%%j%%%%%%%%%%%J%j%%%%%%J%%%%J%% -14262A%J%%%j%%j%%%j%%%%%%J%%%%%%%%%%J%%%%%%%j%%j%%%%%%%%%J%%%%%%%%%%%%%%%%%%%%% -14335@%J%%%%%%j%%%%%%%%%%%%%%%j%j%%%%J%J%J%%J%%%%j%jj%j%%j%%%%%%%%%J%J%J%%J%%%% -14408Aj%%j%%j%%%%%%%J%%J%%%J%%%%%%%j%%j%%%J%%j%%%%%%%J%%%%%%%%%J%%%%%%%%%%j%%j% -14481a%%%%%%J%%%%%%%%%%J%%%j%%j -14506a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=36 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.7499847412109375, 2519.8959518522543) (3.7499847412109375, 2519.8959518522543) (3.7499847412109375, 2519.8959518522543) (4.1199798583984375, 2519.033689532218) (4.1199798583984375, 2519.033689532218) (7.859771728515625, 634.1069186695911) (7.8571014404296875, 631.0063992582528) (7.8428955078125, 631.0326472457319) (7.8402252197265625, 634.1544902063408) (7.4945831298828125, 328.62893815463605) (7.493621826171875, 298.3253431510861) (7.481231689453125, 340.5995875379867) (7.479949951171875, 610.7484191990729) (7.4787750244140625, 310.26456331782674) (7.4663848876953125, 295.32756229020214) (7.465423583984375, 331.3181228421293) (7.557281494140625, 155.13689790398828) (7.5548248291015625, 315.3327517267279) (7.5522613525390625, 157.7969705268267) (7.54254150390625, 316.54890555612155) (7.53997802734375, 631.2332280961152) (7.5375213623046875, 311.1968716862668) (7.5276947021484375, 153.68311935556977) (7.525238037109375, 314.9042864462423) (7.522674560546875, 159.79807159720198) (7.4969329833984375, 316.6480929339144) (7.4959716796875, 310.4629757589573) (7.481231689453125, 307.59064009906757) (7.4800567626953125, 610.1118539482633) (7.4787750244140625, 343.8174538417048) (7.4640350341796875, 307.2276301823248) (7.46307373046875, 319.4395922756181) (7.859771728515625, 634.1069186695911) (7.8571014404296875, 631.0063992582528) (7.8428955078125, 631.0326472457319) (7.8402252197265625, 634.1544902063408) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 8689499 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=Methanol ##NPOINTS=36 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.75, , <15>) (3.75, , <16>) (3.75, , <17>) (4.12, , <18>) (4.12, , <19>) (7.85,
, <21>) (7.85,
, <21>) (7.85,
, <21>) (7.85,
, <21>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.48, , <22>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.54, , <23>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.48, , <24>) (7.85,
, <25>) (7.85,
, <25>) (7.85,
, <25>) (7.85,
, <25>) ##END= ##END=