##TITLE=NP0000253, Submission ID 268, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=L-Lysine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C6 H14 N2 O2 ##ATOMLIST= 1 N 0 2 C 0 3 C 0 4 C 0 5 C 0 6 C 0 7 N 0 8 C 0 9 O 0 10 O 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 S 5 6 S 6 7 S 6 8 S 8 9 D 8 10 S 1 11 S 1 12 S 2 13 S 2 14 S 3 15 S 3 16 S 4 17 S 4 18 S 5 19 S 5 20 S 6 21 S 7 22 S 7 23 S 10 24 S ##STEREOCENTER= 6 M 0 ##$MOLFILE= RDKit 3D 24 23 0 0 0 0 0 0 0 0999 V2000 3.6072 0.6572 0.3957 N 0 0 0 0 0 0 0 0 0 0 0 0 2.7599 -0.3751 -0.1249 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3024 -0.0602 0.2178 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4563 -1.1622 -0.3443 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9847 -1.0052 -0.0675 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6645 0.2182 -0.5952 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.1917 1.4629 -0.1410 N 0 0 0 0 0 0 0 0 0 0 0 0 -3.0968 0.0835 -0.2488 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7097 -0.9504 -0.5632 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7341 1.0974 0.4144 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1335 0.3768 1.2600 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0238 1.4949 0.6316 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8327 -0.4376 -1.2151 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9887 -1.3437 0.3860 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0358 0.9424 -0.2210 H 0 0 0 0 0 0 0 0 0 0 0 0 1.1666 -0.0165 1.3116 H 0 0 0 0 0 0 0 0 0 0 0 0 0.6887 -1.3616 -1.4144 H 0 0 0 0 0 0 0 0 0 0 0 0 0.8019 -2.1066 0.1770 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.1947 -1.0536 1.0320 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5649 -1.8830 -0.4860 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5782 0.2495 -1.7353 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5482 1.8129 0.7532 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.9347 2.1630 -0.8430 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5953 1.1970 1.4206 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 6 8 1 0 8 9 2 0 8 10 1 0 1 11 1 0 1 12 1 0 2 13 1 0 2 14 1 0 3 15 1 0 3 16 1 0 4 17 1 0 4 18 1 0 5 19 1 0 5 20 1 0 6 21 1 6 7 22 1 0 7 23 1 0 10 24 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58901.00,0.0 ##XUNITS=PPM ##FIRSTX=10.783570928905093 ##LASTX=-1.2145499998702283 ##MINX=-1.2145499998702283 ##MAXX=10.783570928905093 ##XFACTOR=0.00018307958997176854 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.23509345553397376 ##LASTY=-0.07892605214736537 ##MINY=-469.32494436793286 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58901Aj%J%%%j%j%%J%%%%%%%%J%%%J%%%%j%%%%j%J%J%%j%%%%jj%%J%%%%%%%%J%%%j%%%%%%%j%J 58827@%%%%%%%%%%%%%jJ%%J%%%j%%%%%%%%%%j%%%J%%%%Jj%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%% 58753@%%J%%%j%%%jJ%%%%%j%%%J%J%%%%%%jj%J%%%%%%%%j%%J%%%%%%%%%%Jj%%%%%%%%%%%%%%%% 58679@%jJ%%%Jj%%%Jj%%%%%%%%%%%%%%%%j%J%%%Jj%%%%%%%%%%%%%jJ%%j%%%JJ%%%%j%%j%JJ%%j 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-5792a%JJ%%%j%%%%%%%%%%%%%%%j%J%%%%%%%%%%j%J%%%%%%J%%%%%%%jj%%%%%%JJj%%j%%%J%%%% -5866@%J%j%%%jJ%%%%%%%%%%%%%%%%%%J%jjjJ%J%%%%%J%%J%j%j%%%jJ%%j%%%%%J%%%%%%%%J%%% -5940A%%jj%%%%%J%Jj%%%%J%%%%%%%%j%%%jJ%j%jJ%%J%JjJ%%j%%%%J%%j%%%%jJj%j%%JJ%%%Jj% -6014@%%%%%%%%J%j%%%%%%%%J%j%%Jj%%%j%%J%%%%%%%%J%j%j%%%J%%%%%J%j%%%j%J%%%%%Jj%%% -6088@%%%%%%%%%%%JJ%j%%%%j%%%%%%%%%%%%Jj%%%Jj%%%%%%j%J%j%%Jj%%%%JJJ%Jjjj%%%%jJ%j -6162a%%%%%J%%%%%%J%%%%%%%%%%j%Jj%%%J%%j%%%%%J%%j%j%%%%J%%%%%%J%%j%jJ%%%%J%j%%%j -6236a%J%%%%%%Jj%%%J%j%%%%%%j%J%j%%J%J%%%%j%%%J%j%%%%%%j%%%JJ%%%%j%%j%%%jJ%%J%%J -6310A%j%%%%%%%J%j%%%%Jj%%%%%%%%%%%%%%%Jj%%%%j%%J%%%%%%%%j%J%%J%%%j%%%%%%%%j%%J% -6384@%Jj%j%%J%%%%%%%%%%%Jj%%%J%%%%j%j%%%%%%J%%%%%%%%%j%%J%%J%%j%%%%J%%j%j%%J%J% -6458Aj%%%%J%%j%%%%%j%%%%%%J%J%%%%j%%%jJ%%%%%%%J%jj%J%%%%%J%%%%j%%j%%%JJJ%%j%%%j -6532@%%J%%j%j%J%%%j%jJJ%J%j%%%j%%J%%%%%%%j%%J%J%%%%jjJ%JJ%j%j%%%jJ%%j%%%JJ%%%%% -6606A%j%%j%%JJj%%j%%%%J%%%%%J%%j% -6634@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=41 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.0420379638671875, 345.0272728888076) (3.0200347900390625, 689.1765388747191) (2.998031616210937, 345.34056322656113) (3.0420379638671875, 345.0272728888076) (3.0200347900390625, 689.1765388747191) (2.998031616210937, 345.34056322656113) (1.736160278320312, 88.6986969192756) (1.7230224609374996, 346.5018467615223) (1.7099914550781246, 518.1325929610745) (1.6969604492187496, 346.74148075690675) (1.683822631835937, 88.54660051591094) (1.736160278320312, 88.6986969192756) (1.7230224609374996, 346.5018467615223) (1.7099914550781246, 518.1325929610745) (1.6969604492187496, 346.74148075690675) (1.683822631835937, 88.54660051591094) (1.4863281249999996, 88.67242291101154) (1.473190307617187, 346.8688360471502) (1.459945678710937, 516.6847520326245) (1.4468078613281246, 346.80959332918064) (1.433670043945312, 88.67825798128095) (1.4863281249999996, 88.67242291101154) (1.473190307617187, 346.8688360471502) (1.459945678710937, 516.6847520326245) (1.4468078613281246, 346.80959332918064) (1.433670043945312, 88.67825798128095) (1.909408569335937, 175.83812931729636) (1.897018432617187, 374.62979333883385) (1.896163940429687, 442.9253912488326) (1.883773803710937, 448.12611355830217) (1.8830261230468746, 384.2870569908134) (1.8706359863281246, 175.5645408416123) (1.909408569335937, 175.83812931729636) (1.897018432617187, 374.62979333883385) (1.896163940429687, 442.9253912488326) (1.883773803710937, 448.12611355830217) (1.8830261230468746, 384.2870569908134) (1.8706359863281246, 175.5645408416123) (3.752227783203125, 348.5924938177396) (3.74005126953125, 691.1142215654983) (3.7277679443359375, 348.2566939460396) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 12097436 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=41 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.02, , <13>) (3.02, , <13>) (3.02, , <13>) (3.02, , <14>) (3.02, , <14>) (3.02, , <14>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (3.74, , <21>) (3.74, , <21>) (3.74, , <21>) ##END= ##END= ##TITLE=NP0000253, Submission ID 268, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=L-Lysine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C6 H14 N2 O2 ##ATOMLIST= 1 N 0 2 C 0 3 C 0 4 C 0 5 C 0 6 C 0 7 N 0 8 C 0 9 O 0 10 O 0 11 H 0 12 H 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 S 5 6 S 6 7 S 6 8 S 8 9 D 8 10 S 1 11 S 1 12 S 2 13 S 2 14 S 3 15 S 3 16 S 4 17 S 4 18 S 5 19 S 5 20 S 6 21 S 7 22 S 7 23 S 10 24 S ##STEREOCENTER= 6 M 0 ##$MOLFILE= RDKit 3D 24 23 0 0 0 0 0 0 0 0999 V2000 3.6072 0.6572 0.3957 N 0 0 0 0 0 0 0 0 0 0 0 0 2.7599 -0.3751 -0.1249 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3024 -0.0602 0.2178 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4563 -1.1622 -0.3443 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9847 -1.0052 -0.0675 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6645 0.2182 -0.5952 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.1917 1.4629 -0.1410 N 0 0 0 0 0 0 0 0 0 0 0 0 -3.0968 0.0835 -0.2488 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7097 -0.9504 -0.5632 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7341 1.0974 0.4144 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1335 0.3768 1.2600 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0238 1.4949 0.6316 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8327 -0.4376 -1.2151 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9887 -1.3437 0.3860 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0358 0.9424 -0.2210 H 0 0 0 0 0 0 0 0 0 0 0 0 1.1666 -0.0165 1.3116 H 0 0 0 0 0 0 0 0 0 0 0 0 0.6887 -1.3616 -1.4144 H 0 0 0 0 0 0 0 0 0 0 0 0 0.8019 -2.1066 0.1770 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.1947 -1.0536 1.0320 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5649 -1.8830 -0.4860 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5782 0.2495 -1.7353 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.5482 1.8129 0.7532 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.9347 2.1630 -0.8430 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5953 1.1970 1.4206 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 6 8 1 0 8 9 2 0 8 10 1 0 1 11 1 0 1 12 1 0 2 13 1 0 2 14 1 0 3 15 1 0 3 16 1 0 4 17 1 0 4 18 1 0 5 19 1 0 5 20 1 0 6 21 1 6 7 22 1 0 7 23 1 0 10 24 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58901.00,0.0 ##XUNITS=PPM ##FIRSTX=10.783570928905093 ##LASTX=-1.2145499998702283 ##MINX=-1.2145499998702283 ##MAXX=10.783570928905093 ##XFACTOR=0.00018307958997176854 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.23509345553397376 ##LASTY=-0.07892605214736537 ##MINY=-469.32494436793286 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58901Aj%J%%%j%j%%J%%%%%%%%J%%%J%%%%j%%%%j%J%J%%j%%%%jj%%J%%%%%%%%J%%%j%%%%%%%j%J 58827@%%%%%%%%%%%%%jJ%%J%%%j%%%%%%%%%%j%%%J%%%%Jj%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%% 58753@%%J%%%j%%%jJ%%%%%j%%%J%J%%%%%%jj%J%%%%%%%%j%%J%%%%%%%%%%Jj%%%%%%%%%%%%%%%% 58679@%jJ%%%Jj%%%Jj%%%%%%%%%%%%%%%%j%J%%%Jj%%%%%%%%%%%%%jJ%%j%%%JJ%%%%j%%j%JJ%%j 58605@%%%%%%j%%%J%%j%J%Jj%%%%%%%%J%%j%J%j%%%%j%J%%%%J%%jjJ%%%%j%%%%J%%j%J%%J%%%% 58531A%%jj%%J%%%%%%jJ%%%%%%%%%J%jjJ%%%%%%%%%%%%%%j%J%%%J%%j%J%%%j%%%%%%j%j%%J%J% 58457@%%%%%J%j%%%%%J%%j%%%%J%J%j%j%j%%J%%%%%%j%%%%%J%%%jJ%%%%%%%%%%%%%%%%%%%%%%% 58383@%%%%j%%%%%%J%J%%%%j%%J%%%j%%%%%%%J%%jj%%%J%j%%%%%J%%J%j%%%%%%%%%%%J%%%%%%j 58309@%j%%%%%%%JJj%%%%%%Jj%%%%%%%J%%j%j%%%J%J%%%%%%j%%j%%%%J%%%%%%J%j%%%j%J%%%%% 58235@J%j%j%%%J%jJ%%%%%%%%Jj%%J%%%j%%%j%J%%J%%%%j%%%j%jJJ%%%%J%j%%jJ%%%%Jj%%%%%% 58161@%%J%j%j%%J%%%%%%%%%%%J%%%%%%j%jJ%%%%%%%j%J%%%j%J%%%J%j%%%%%%%%%%J%j%%%%j%J 58087@%%%%%%%%%%%%%%%%%%J%j%%%%%j%%J%%%%%%%%%%%%%%%%%%%j%%%%JJ%%j%%%%%%J%%%j%%%% 58013@%J%j%%%%%J%%j%%%j%%%JjJ%%j%J%%%%%%%%%%%%%%%%%%%%%J%%j%%j%%J%%%%%%%%%%%%%%% 57939@%%%%%%j%J%%%%J%%%j%j%J%%%%%J%%%%j%%%%%%%%j%%%J%%%%%%%%%j%J%%%%%J%%j%J%%jj% 57865a%J%jJ%%%%%%%%%%%%%%%%%%%J%%%j%j%%%J%%J%%%j%%%%%j%%J%j%J%%Jj%%%%%%j%J%%jJ%J 57791A%%%j%%%%%%%Jj%%%%%%%%%j%J%J%%%%%j%%%%%j%%%J%%J%jj%%%JjJ%%%%%Jj%%%%%%J%%%%% 57717Ajj%JJj%jJ%%%%%%j%%%J%%jJ%%%%%%%%%J%%j%%%%%%j%J%%%%%%J%%j%%%%%%%J%%%%jj%jJJ 57643@%%%%%%%%%%%%%%%%%jJ%%J%j%j%J%J%%%%%j%%%%%%%j%%J%%%%%J%%j%%%%%%%%%%%%%J%%j% 57569@j%%J%%%%jJ%Jj%%%%%%j%%J%%J%%%%%j%jJ%%%%%jJJ%j%%%%%%%J%%%jj%%%J%%%%%%%%%%%% 57495@%%%%jJ%J%%%%%j%%%%%%%%%%j%%J%%%j%J%%J%j%%jJ%%%%%j%%JJ%%j%%J%j%%%%%%%%%%J%% 57421A%%%j%%%j%%%%%%%J%%jJ%%%%%%%%%%%%%%%j%%%J%J%%%%%%j%%%%%%%%%%%%%%%%%Jj%jJ%%% 57347@%J%%j%%jJ%%%%%%j%%%JJ%%%%%%j%%%%j%%j%JJ%%J%%%%%%%%j%j%%J%jJ%%j%%%J%%%%%%J% 57273A%j%%jJ%%%J%%%%%%jj%%%%%%%%JJ%%j%%%%j%%%J%%%%%%%J%%%%%j%jJ%j%%%%J%%J%%%%%jj 57199a%%Jj%J%Jj%%%%%Jj%%%%%j%%J%%%%j%%J%J%j%%%%%%%%JJ%jj%%%%%%%%%j%%%%J%%J%%%%%% 57125Ajj%jJJ%%%%%%%%%j%%J%%%%%%jJ%%J%%j%%%%%%%%%J%%j%%%%%%%%%%%%%j%J%%%%%Jj%%%%% 57051@%%%%%%%%%%%j%J%J%%j%%Jj%j%%%%J%jJ%J%%%%%%%%%j%%j%%%%J%j%%%%J%%%%%%%%%%%J%j 56977@%%J%j%%%%%%%%%%j%%%J%%J%%j%%j%J%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%JJ%%jjJ% 56903@%%%J%%%j%%%J%j%J%j%j%%%%%J%%%%%%%%jJ%%%%J%j%%%%j%J%%%%%%%%%J%%%jjJ%J%jj%j% 56829bJ%J%%J%%%%j%j%J%%%%%%%%%J%%j%jj%%%%%%%JJ%%%%%%%%%%%jJ%%%%%%J%%%%j%j%J%%%%% 56755@J%%j%j%%%%%J%J%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%%%J%%J%%%%%jj%%J%%%J%%%% 56681Aj%%%j%%%Jj%%J%%Jj%%%%%j%J%J%%%j%%j%%J%%%%%Jj%j%%%J%J%%j%%%%%%%%%%J%j%%%%%% 56607@j%%%%JJ%%%%%j%j%%%J%%%%%%%%%%J%%%%%%j%j%J%%%%%%%Jj%%%%J%j%%jj%J%J%%%%%J%j% 56533@%%%J%%j%%%%%%%j%%%J%%%%Jj%J%j%j%%J%%%%%%%%%%%%%%j%J%%%%%%%%J%j%%%j%%J%%%%% 56459@%%%%%%%J%%j%%%%%jJ%%%%%j%%Jj%J%%%J%%%%%%j%%%j%%J%%%%%%%%%%%%%%%%%%%%%%%%J% 56385Aj%%j%%%JJ%j%%%%%j%J%%%%%%%J%j%j%%J%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%%%%%%%J%% 56311Aj%%j%%%%J%%%%%%j%%%J%J%j%%%%%%j%J%%%%%%%%J%j%%%%%%%j%jJ%J%%%%%%%J%j%%%%%j% 56237aJ%%Jj%%%%J%j%Jj%%%%J%%%%j%j%%J%%%%%%%%%%%%j%%J%%%%%J%%%%%j%%j%%J%J%%j%%%%% 56163@jJ%%%%%%j%%J%%%%%Jj%%%%%%%j%%%J%J%%%j%%j%J%%%%%jJ%%J%%%jj%%%J%J%%j%%%%%%%% 56089@%%%%j%J%%%%%%J%%%%j%%%%%%%%%%%j%%%%J%%%%%%J%%j%%j%%J%%%%%%J%%%j%%%j%%%J%%% 56015@%%%J%%j%%%%%%%Jj%%%%%%%%%j%%J%j%J%J%j%%%J%%%j%%%%j%%%%JJJ%jj%%j%%%%J%%%%jJ 55941@%%Jj%%%%%J%%j%%j%J%J%%%j%%%%%%%%%%%Jj%j%J%jJ%%%%j%J%J%jj%JJ%j%%%%%%%%%%%%% 55867@%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%%%%%%%%%J%%j%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%% 55793@jJ%%%j%%%J%%%%%J%j%J%j%%%%%%%%%%%%jJ%%%%%%%J%%%%%j%j%%%%%J%%%%%%j%J%%%%%Jj 55719@%J%%%%%j%%%%%%%j%%J%%j%%J%%%%J%%%j%%%%%%%%%%%J%%j%%%J%%j%%j%%%%%%%J%%%%%jJ 55645@%J%%%%j%%%%%J%%%%%j%j%%JJj%%%%%j%%%%J%%J%j%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%% 55571@%%%%%%%%%jJ%%%%%%J%%%%%jj%JJ%%%j%%%%j%%J%%%%%%%%%%%%j%Jj%%%J%%%%%%%J%%%%%% 55497Aj%%j%%%j%JJJ%Jj%j%j%J%%%%%%%%J%%j%%%%%jJ%%%%%%%J%%j%j%J%%%%%%%%%%%%%%%%j%J 55423@%%%%%J%j%%%%%j%%J%%%j%%J%J%%%%%%j%j%%%J%%%%%J%j%%%%j%%%%J%%%%%%%J%j%%%%%%% 55349@%%J%%j%%%%%%%%%%%%j%%%J%%%%%%%j%%%J%%%%%%j%J%%%J%j%%J%%%j%%%%%%%%jJ%%j%%%% 55275a%J%%%%%%%J%%%%%%%j%%%%j%J%Jj%%%%j%%%J%jJ%%%%%%J%j%%%%%%%%%%%%Jj%%%%%%%J%j% 55201@%%%%%%%%%%%j%%%J%%J%%j%%%%%%%J%j%%%%%%%%%J%j%%%%%%%%j%%%J%%%J%j%%%%%%%%jJJ 55127A%j%%j%%%%J%jJ%J%%%j%%J%%jJj%%%%%%%%j%%J%%%%%%%%j%J%%%%%%%%%%J%%%j%%J%j%%%% 55053@%%j%%%J%%%%%%%%%%J%%jj%%J%%%%%%%%j%%%JJ%j%%%%J%j%J%j%%%%%%%%%J%%j%%j%%%J%J 54979A%j%%%%%%%%%%%%%%%%%%%%%%J%jj%J%%%j%J%%%%J%j%J%j%%jJ%%%%J%%j%%j%%J%JjJ%%%jj 54905a%J%J%j%%%%%%%%%j%J%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%Jj%%%%J%j%%j%%J%%%%%% 54831@%%%J%j%%%%%%j%%J%%%%%%%%%%%%%%%J%%%%j%%%%%j%%J%%%%%jj%J%J%%%%%%%%%%%%%%%%J 54757A%%jJ%j%%%%%%j%Jj%%J%%%%J%j%%%%j%J%%%%J%%j%%%j%%J%%%%%J%%%j%%%%%%j%%%%%J%%% 54683@%%%J%j%%Jj%%%Jj%j%%%JJ%jJj%jJ%j%%J%%J%%%j%%j%%%%J%%J%%%jjJ%%%%%%%J%%j%%%%% 54609@%%%%%%%%%J%j%%%%%%%%%%%%j%%%%J%%j%%J%%J%%j%%%%%%%%%%%%%j%J%%J%j%%%%j%%JJj% 54535@J%j%%%%%%%j%%J%%j%%J%%J%%%%j%%%j%J%%%%j%J%%%J%j%%J%j%%%%%%j%%J%%%j%%J%J%%% 54461Aj%%j%%%%%%Jj%J%%Jj%J%%%j%%%%%%J%jj%J%%%j%J%%%%%%J%%j%%%%%%%%%%%%%%jJ%%%%%% 54387@%%J%j%j%%%%J%%%J%%%jj%J%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%%J%J%%%%%j% 54313@%j%Jj%J%%%%J%%j%%%j%%%J%%%%%%%%J%j%j%%%J%JJ%%jj%jJ%j%%JJ%%%%%%j%%%J%%%%%%% 54239A%%%J%%%j%j%Jj%%%%j%%Jj%%%J%J%%j%%%%%J%%j%%%j%%%J%J%j%j%J%%J%%%%j%%%%%J%j%j 54165aJ%%j%Jj%%%%J%%%%%J%%%j%%jJ%%%%%%Jj%%%%%%%%%%J%%jj%%j%JJJ%%%j%%%J%%%jj%%J%% 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-5866@%J%j%%%jJ%%%%%%%%%%%%%%%%%%J%jjjJ%J%%%%%J%%J%j%j%%%jJ%%j%%%%%J%%%%%%%%J%%% -5940A%%jj%%%%%J%Jj%%%%J%%%%%%%%j%%%jJ%j%jJ%%J%JjJ%%j%%%%J%%j%%%%jJj%j%%JJ%%%Jj% -6014@%%%%%%%%J%j%%%%%%%%J%j%%Jj%%%j%%J%%%%%%%%J%j%j%%%J%%%%%J%j%%%j%J%%%%%Jj%%% -6088@%%%%%%%%%%%JJ%j%%%%j%%%%%%%%%%%%Jj%%%Jj%%%%%%j%J%j%%Jj%%%%JJJ%Jjjj%%%%jJ%j -6162a%%%%%J%%%%%%J%%%%%%%%%%j%Jj%%%J%%j%%%%%J%%j%j%%%%J%%%%%%J%%j%jJ%%%%J%j%%%j -6236a%J%%%%%%Jj%%%J%j%%%%%%j%J%j%%J%J%%%%j%%%J%j%%%%%%j%%%JJ%%%%j%%j%%%jJ%%J%%J -6310A%j%%%%%%%J%j%%%%Jj%%%%%%%%%%%%%%%Jj%%%%j%%J%%%%%%%%j%J%%J%%%j%%%%%%%%j%%J% -6384@%Jj%j%%J%%%%%%%%%%%Jj%%%J%%%%j%j%%%%%%J%%%%%%%%%j%%J%%J%%j%%%%J%%j%j%%J%J% -6458Aj%%%%J%%j%%%%%j%%%%%%J%J%%%%j%%%jJ%%%%%%%J%jj%J%%%%%J%%%%j%%j%%%JJJ%%j%%%j -6532@%%J%%j%j%J%%%j%jJJ%J%j%%%j%%J%%%%%%%j%%J%J%%%%jjJ%JJ%j%j%%%jJ%%j%%%JJ%%%%% -6606A%j%%j%%JJj%%j%%%%J%%%%%J%%j% -6634@ $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=41 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.0420379638671875, 345.0272728888076) (3.0200347900390625, 689.1765388747191) (2.998031616210937, 345.34056322656113) (3.0420379638671875, 345.0272728888076) (3.0200347900390625, 689.1765388747191) (2.998031616210937, 345.34056322656113) (1.736160278320312, 88.6986969192756) (1.7230224609374996, 346.5018467615223) (1.7099914550781246, 518.1325929610745) (1.6969604492187496, 346.74148075690675) (1.683822631835937, 88.54660051591094) (1.736160278320312, 88.6986969192756) (1.7230224609374996, 346.5018467615223) (1.7099914550781246, 518.1325929610745) (1.6969604492187496, 346.74148075690675) (1.683822631835937, 88.54660051591094) (1.4863281249999996, 88.67242291101154) (1.473190307617187, 346.8688360471502) (1.459945678710937, 516.6847520326245) (1.4468078613281246, 346.80959332918064) (1.433670043945312, 88.67825798128095) (1.4863281249999996, 88.67242291101154) (1.473190307617187, 346.8688360471502) (1.459945678710937, 516.6847520326245) (1.4468078613281246, 346.80959332918064) (1.433670043945312, 88.67825798128095) (1.909408569335937, 175.83812931729636) (1.897018432617187, 374.62979333883385) (1.896163940429687, 442.9253912488326) (1.883773803710937, 448.12611355830217) (1.8830261230468746, 384.2870569908134) (1.8706359863281246, 175.5645408416123) (1.909408569335937, 175.83812931729636) (1.897018432617187, 374.62979333883385) (1.896163940429687, 442.9253912488326) (1.883773803710937, 448.12611355830217) (1.8830261230468746, 384.2870569908134) (1.8706359863281246, 175.5645408416123) (3.752227783203125, 348.5924938177396) (3.74005126953125, 691.1142215654983) (3.7277679443359375, 348.2566939460396) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 12097436 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=41 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.02, , <13>) (3.02, , <13>) (3.02, , <13>) (3.02, , <14>) (3.02, , <14>) (3.02, , <14>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <15>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.71, , <16>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <17>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.46, , <18>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <19>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (1.89, , <20>) (3.74, , <21>) (3.74, , <21>) (3.74, , <21>) ##END= ##END=