##TITLE=NP0000091, Submission ID 262, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Adenosine monophosphate ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H14 N5 O7 P ##ATOMLIST= 1 N 0 2 C 0 3 N 0 4 C 0 5 N 0 6 C 0 7 C 0 8 N 0 9 C 0 10 N 0 11 C 0 12 O 0 13 C 0 14 C 0 15 O 0 16 P 0 17 O 0 18 O 0 19 O 0 20 C 0 21 O 0 22 C 0 23 O 0 24 H 0 25 H 0 26 H 0 27 H 0 28 H 0 29 H 0 30 H 0 31 H 0 32 H 0 33 H 0 34 H 0 35 H 0 36 H 0 37 H 0 ##BONDLIST= 1 2 S 2 3 D 3 4 S 4 5 D 5 6 S 6 7 D 7 8 S 8 9 D 9 10 S 10 11 S 11 12 S 12 13 S 13 14 S 14 15 S 16 15 S 16 17 D 16 18 S 16 19 S 13 20 S 20 21 S 20 22 S 22 23 S 7 2 S 22 11 S 10 6 S 1 24 S 1 25 S 4 26 S 9 27 S 11 28 S 13 29 S 14 30 S 14 31 S 18 32 S 19 33 S 20 34 S 21 35 S 22 36 S 23 37 S ##STEREOCENTER= 11 M 0 13 M 0 20 P 0 22 P 0 ##$MOLFILE= RDKit 3D 37 39 0 0 0 0 0 0 0 0999 V2000 -5.6451 2.5846 -0.7966 N 0 0 0 0 0 0 0 0 0 0 0 0 -4.7814 1.7264 -0.0780 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1897 1.2583 1.1152 N 0 0 0 0 0 0 0 0 0 0 0 0 -4.3927 0.4463 1.8136 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1986 0.1219 1.2949 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7434 0.5614 0.1091 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5575 1.4019 -0.6239 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8772 1.6845 -1.7393 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.6930 1.0394 -1.6866 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5885 0.3346 -0.5453 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.5295 -0.4844 -0.0734 C 0 0 2 0 0 0 0 0 0 0 0 0 0.6727 0.2138 0.1254 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -0.8454 0.4969 C 0 0 2 0 0 0 0 0 0 0 0 0 2.9219 -0.4262 0.7228 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5168 0.1271 -0.3810 O 0 0 0 0 0 0 0 0 0 0 0 0 5.1141 0.5755 -0.0563 P 0 0 1 0 0 5 0 0 0 0 0 0 5.1752 1.0544 1.3685 O 0 0 0 0 0 0 0 0 0 0 0 0 6.1454 -0.7465 -0.3040 O 0 0 0 0 0 0 0 0 0 0 0 0 5.5238 1.8047 -1.1360 O 0 0 0 0 0 0 0 0 0 0 0 0 1.3433 -1.7844 -0.6697 C 0 0 1 0 0 0 0 0 0 0 0 0 1.5752 -3.1022 -0.2965 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1175 -1.5661 -1.0418 C 0 0 1 0 0 0 0 0 0 0 0 0 -0.8475 -2.7203 -0.6786 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.2108 2.1729 -1.5700 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.6810 3.5799 -0.5283 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.6707 0.0362 2.7864 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.9482 1.0921 -2.4577 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7776 -0.9439 0.9000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0459 -1.3269 1.3777 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4636 -1.3048 1.1296 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9126 0.3268 1.5466 H 0 0 0 0 0 0 0 0 0 0 0 0 6.8862 -0.7312 0.3312 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8818 2.5474 -0.9900 H 0 0 0 0 0 0 0 0 0 0 0 0 1.9961 -1.5010 -1.5251 H 0 0 0 0 0 0 0 0 0 0 0 0 1.7375 -3.1111 0.6721 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.2575 -1.2940 -2.0892 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7048 -2.8018 0.3171 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 2 0 3 4 1 0 4 5 2 0 5 6 1 0 6 7 2 0 7 8 1 0 8 9 2 0 9 10 1 0 10 11 1 0 11 12 1 0 12 13 1 0 13 14 1 0 14 15 1 0 16 15 1 6 16 17 2 0 16 18 1 0 16 19 1 0 13 20 1 0 20 21 1 0 20 22 1 0 22 23 1 0 7 2 1 0 22 11 1 0 10 6 1 0 1 24 1 0 1 25 1 0 4 26 1 0 9 27 1 0 11 28 1 1 13 29 1 1 14 30 1 0 14 31 1 0 18 32 1 0 19 33 1 0 20 34 1 6 21 35 1 0 22 36 1 6 23 37 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,117277.00,0.0 ##XUNITS=PPM ##FIRSTX=10.737168033349805 ##LASTX=-1.2628946498633766 ##MINX=-1.2628946498633766 ##MAXX=10.737168033349805 ##XFACTOR=9.155391111015376e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.09943260569701591 ##LASTY=-0.2708039057337676 ##MINY=-2.3949169309985257 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 117277@j%%JJJJ%%%jj%%%%%%%%%%j%%J%J%%j%%%JJ%%%%%%%%%%%%j%%%%%%%Jj%%j%%%%%jjj%%%% 117204bJ%%JJ%J%J%%%%%%%%%j%%%jj%j%%J%%%j%J%J%%j%%%%JJ%%j%%j%%%%%%%j%%%%%%J%%%%%% 117131@%%%J%%j%%%%J%%%%j%%%%%%%%%%%%%J%j%%%%%%j%%J%%%%J%%%%%%j%j%%%j%J%J%J%%jj%% 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-12227b%JJ%J%%%J%%j%j%%%%%%%%%%%%%%%%%j%%%%J%J%J%%%%%%JJJJ%jkj%%%%%j%%JJJ%jjjj%% -12300@%%%%%J%Jj%j%j%%%%J%%%%%J%%%J%%%%j%%%%%%%j%%%j%j%%%%%JJK%j%j%%J%%%%%%%jJ%% -12373A%%j%jJ%%%%jj%j%%%%J%j%%j%%%J%J%J%%%%%%%%%%JJ%J%%%%%%%%jj%jj%J%%J%%%%j%%%J -12446@%j%J%%%jj%%%%j%%%JJJ%%%J%J%%%%%j%%j%j%j%J%j%%JJ%%%%%%%%j%%%J%%J%%%%j%%%%% -12519@%%%%%%%%%j%%%%JJ%%%%%%j%%%%%%%%%%J%%j%jj%j%%%%%%%j%J%%Jj%%%%%J%J%%J%%%%%% -12592@%%%%%J%j%%j%%%%%JJ%J%%j%%j%%%%%%%%j%%J%J%j%%%j%%%%J%%%%%%%J%%%%%%%%j%%%J% -12665A%%%%jj%%j%%%J%%JJJJ%%%%j%j%%j%%%%j%J%%%J%%J%%%jj%%%%J%J%%J%J%j%j%j%%j%%%% -12738@%%%%%%%j%%JJJ%J%%%%j%j%%%%%J%J%j%%%%%%J%%Jj%%j%%j%J%%%%%j%j%%J%j%%%%Jj%%j -12811a%%%JJ%%%j%%%%%%%%j%%%J%%%J%%%%%%j%j%%%%%%JJ%%Jj%%%%%j%%%%%%J%%%%%%%%%%%%j -12884@%jj%J%J%%%%j%%%%%J%%%j%%%%%%J%%%J%%Jj%%%%%%%j%%%%j%%J%%%%%%%%%%%%%%jj%%%% -12957bJ%J%%%%%%%%%J%%%j%%J%%Jj%%j%jj%j%JJJ%%%j%%%j%%j%j%%J%%%%%JJJJ%%%%%%j%%%%J -13030A%%%%%%j%%%%JJ%%%%%%j%%%%%j%j%%%j%JJJ%J%%J%j%j%%j%%%%%%J%JJ%Jj%%j%%%j%%%J% -13103BJ%j%%%j%%%%%j%%%%%J%J%%jjj%%%%%%J%J%j%%j%%%%%J%J%%%J%J%j%j%J%j%%%%j%%%%%% -13176@%%%%J%%jJ%%%j%%%%%%J%%%j%%%%%%%%%%%%j%%%%%J%%%%%j%%%%%%J%J%%j%%J%%%%%%%%% -13249A%%jj%%%j%J%%J%%%%J%%%j%J%%j%%%%J%%jj%j%J%%%%%%%%%%%J%J%%%%%%%j%%%%%%j%%%% -13322a%%J%%%%%J%J%%jjjj%%%%%JJ%Jj%jj%%%%%j%J%J%J%J%%%%%J%%%%%%%j%%%J%%j%j%J%%%% -13395Ajj%%%%%J%%%%%%%%%%%%%%%J%%%j%j%%%%jJ%%%%j%%J%J%%%%%%%%%%%j%%%J%%%j%%J%%%% -13468@%%J%%%%%%J%%j%%j%%%%%%j%J%%%%%%%%J%j%%j%%%J%%J%j%%j%%%%%%J%%j%%J%%J%%%%%% -13541A%%j%%j%%%J%J%%%%%j%%J%j%%j%%%%J%%%%%%%%%J%j%%%%%%%%%%%%j%%J%%%j%%jJ%%%%J% -13614@J%%J%j%%%j%J%%j%%%%%%%%%%%%j%%%J%%%%%%%J%%jj%%%J%%%%j%%%%%%%J%J%J%%%%%j%j -13687@%%j%jj%%J%%Jj%%j%J%%%J%%%J%J%%%%%%J%%j%jj%%%J%J%j%%%%J%j%%j%%%%%%%%J%%%j% -13760aJ%%J%%j%%%%%%%%J%J%%%%j%jj%%%%%%%% -13794a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=20 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (8.22998046875, 5012.342569835868) (8.580001831054688, 5014.630456247703) (6.1259002685546875, 2505.321040279886) (6.114044189453125, 2505.350891378266) (4.3647918701171875, 1418.952101972274) (4.3618011474609375, 1492.7978656222888) (4.3581695556640625, 1493.037104305177) (4.3551788330078125, 1418.3462728591626) (4.01776123046875, 1300.1047946170195) (4.01092529296875, 1574.622982759934) (4.009002685546875, 1557.1507663855623) (4.0022735595703125, 1301.0790998794914) (4.01776123046875, 1300.1047946170195) (4.01092529296875, 1574.622982759934) (4.009002685546875, 1557.1507663855623) (4.0022735595703125, 1301.0790998794914) (4.5085601806640625, 1294.423875089641) (4.501617431640625, 1400.321341083435) (4.4984130859375, 1402.6413876570555) (4.4914703369140625, 1293.5018395742725) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 6656991 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=20 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (8.23, , <26>) (8.58, , <27>) (6.12, , <28>) (6.12, , <28>) (4.36,
, <29>) (4.36,
, <29>) (4.36,
, <29>) (4.36,
, <29>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <31>) (4.01,
, <31>) (4.01,
, <31>) (4.01,
, <31>) (4.5,
, <36>) (4.5,
, <36>) (4.5,
, <36>) (4.5,
, <36>) ##END= ##END= ##TITLE=NP0000091, Submission ID 262, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Adenosine monophosphate ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C10 H14 N5 O7 P ##ATOMLIST= 1 N 0 2 C 0 3 N 0 4 C 0 5 N 0 6 C 0 7 C 0 8 N 0 9 C 0 10 N 0 11 C 0 12 O 0 13 C 0 14 C 0 15 O 0 16 P 0 17 O 0 18 O 0 19 O 0 20 C 0 21 O 0 22 C 0 23 O 0 24 H 0 25 H 0 26 H 0 27 H 0 28 H 0 29 H 0 30 H 0 31 H 0 32 H 0 33 H 0 34 H 0 35 H 0 36 H 0 37 H 0 ##BONDLIST= 1 2 S 2 3 D 3 4 S 4 5 D 5 6 S 6 7 D 7 8 S 8 9 D 9 10 S 10 11 S 11 12 S 12 13 S 13 14 S 14 15 S 16 15 S 16 17 D 16 18 S 16 19 S 13 20 S 20 21 S 20 22 S 22 23 S 7 2 S 22 11 S 10 6 S 1 24 S 1 25 S 4 26 S 9 27 S 11 28 S 13 29 S 14 30 S 14 31 S 18 32 S 19 33 S 20 34 S 21 35 S 22 36 S 23 37 S ##STEREOCENTER= 11 M 0 13 M 0 20 P 0 22 P 0 ##$MOLFILE= RDKit 3D 37 39 0 0 0 0 0 0 0 0999 V2000 -5.6451 2.5846 -0.7966 N 0 0 0 0 0 0 0 0 0 0 0 0 -4.7814 1.7264 -0.0780 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1897 1.2583 1.1152 N 0 0 0 0 0 0 0 0 0 0 0 0 -4.3927 0.4463 1.8136 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1986 0.1219 1.2949 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7434 0.5614 0.1091 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5575 1.4019 -0.6239 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8772 1.6845 -1.7393 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.6930 1.0394 -1.6866 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5885 0.3346 -0.5453 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.5295 -0.4844 -0.0734 C 0 0 2 0 0 0 0 0 0 0 0 0 0.6727 0.2138 0.1254 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -0.8454 0.4969 C 0 0 2 0 0 0 0 0 0 0 0 0 2.9219 -0.4262 0.7228 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5168 0.1271 -0.3810 O 0 0 0 0 0 0 0 0 0 0 0 0 5.1141 0.5755 -0.0563 P 0 0 1 0 0 5 0 0 0 0 0 0 5.1752 1.0544 1.3685 O 0 0 0 0 0 0 0 0 0 0 0 0 6.1454 -0.7465 -0.3040 O 0 0 0 0 0 0 0 0 0 0 0 0 5.5238 1.8047 -1.1360 O 0 0 0 0 0 0 0 0 0 0 0 0 1.3433 -1.7844 -0.6697 C 0 0 1 0 0 0 0 0 0 0 0 0 1.5752 -3.1022 -0.2965 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1175 -1.5661 -1.0418 C 0 0 1 0 0 0 0 0 0 0 0 0 -0.8475 -2.7203 -0.6786 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.2108 2.1729 -1.5700 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.6810 3.5799 -0.5283 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.6707 0.0362 2.7864 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.9482 1.0921 -2.4577 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7776 -0.9439 0.9000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.0459 -1.3269 1.3777 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4636 -1.3048 1.1296 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9126 0.3268 1.5466 H 0 0 0 0 0 0 0 0 0 0 0 0 6.8862 -0.7312 0.3312 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8818 2.5474 -0.9900 H 0 0 0 0 0 0 0 0 0 0 0 0 1.9961 -1.5010 -1.5251 H 0 0 0 0 0 0 0 0 0 0 0 0 1.7375 -3.1111 0.6721 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.2575 -1.2940 -2.0892 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.7048 -2.8018 0.3171 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 2 0 3 4 1 0 4 5 2 0 5 6 1 0 6 7 2 0 7 8 1 0 8 9 2 0 9 10 1 0 10 11 1 0 11 12 1 0 12 13 1 0 13 14 1 0 14 15 1 0 16 15 1 6 16 17 2 0 16 18 1 0 16 19 1 0 13 20 1 0 20 21 1 0 20 22 1 0 22 23 1 0 7 2 1 0 22 11 1 0 10 6 1 0 1 24 1 0 1 25 1 0 4 26 1 0 9 27 1 0 11 28 1 1 13 29 1 1 14 30 1 0 14 31 1 0 18 32 1 0 19 33 1 0 20 34 1 6 21 35 1 0 22 36 1 6 23 37 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,117277.00,0.0 ##XUNITS=PPM ##FIRSTX=10.737168033349805 ##LASTX=-1.2628946498633766 ##MINX=-1.2628946498633766 ##MAXX=10.737168033349805 ##XFACTOR=9.155391111015376e-05 ##NPOINTS=131072 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-0.09943260569701591 ##LASTY=-0.2708039057337676 ##MINY=-2.3949169309985257 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 117277@j%%JJJJ%%%jj%%%%%%%%%%j%%J%J%%j%%%JJ%%%%%%%%%%%%j%%%%%%%Jj%%j%%%%%jjj%%%% 117204bJ%%JJ%J%J%%%%%%%%%j%%%jj%j%%J%%%j%J%J%%j%%%%JJ%%j%%j%%%%%%%j%%%%%%J%%%%%% 117131@%%%J%%j%%%%J%%%%j%%%%%%%%%%%%%J%j%%%%%%j%%J%%%%J%%%%%%j%j%%%j%J%J%J%%jj%% 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-13103BJ%j%%%j%%%%%j%%%%%J%J%%jjj%%%%%%J%J%j%%j%%%%%J%J%%%J%J%j%j%J%j%%%%j%%%%%% -13176@%%%%J%%jJ%%%j%%%%%%J%%%j%%%%%%%%%%%%j%%%%%J%%%%%j%%%%%%J%J%%j%%J%%%%%%%%% -13249A%%jj%%%j%J%%J%%%%J%%%j%J%%j%%%%J%%jj%j%J%%%%%%%%%%%J%J%%%%%%%j%%%%%%j%%%% -13322a%%J%%%%%J%J%%jjjj%%%%%JJ%Jj%jj%%%%%j%J%J%J%J%%%%%J%%%%%%%j%%%J%%j%j%J%%%% -13395Ajj%%%%%J%%%%%%%%%%%%%%%J%%%j%j%%%%jJ%%%%j%%J%J%%%%%%%%%%%j%%%J%%%j%%J%%%% -13468@%%J%%%%%%J%%j%%j%%%%%%j%J%%%%%%%%J%j%%j%%%J%%J%j%%j%%%%%%J%%j%%J%%J%%%%%% -13541A%%j%%j%%%J%J%%%%%j%%J%j%%j%%%%J%%%%%%%%%J%j%%%%%%%%%%%%j%%J%%%j%%jJ%%%%J% -13614@J%%J%j%%%j%J%%j%%%%%%%%%%%%j%%%J%%%%%%%J%%jj%%%J%%%%j%%%%%%%J%J%J%%%%%j%j -13687@%%j%jj%%J%%Jj%%j%J%%%J%%%J%J%%%%%%J%%j%jj%%%J%J%j%%%%J%j%%j%%%%%%%%J%%%j% -13760aJ%%J%%j%%%%%%%%J%J%%%%j%jj%%%%%%%% -13794a $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=20 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (8.22998046875, 5012.342569835868) (8.580001831054688, 5014.630456247703) (6.1259002685546875, 2505.321040279886) (6.114044189453125, 2505.350891378266) (4.3647918701171875, 1418.952101972274) (4.3618011474609375, 1492.7978656222888) (4.3581695556640625, 1493.037104305177) (4.3551788330078125, 1418.3462728591626) (4.01776123046875, 1300.1047946170195) (4.01092529296875, 1574.622982759934) (4.009002685546875, 1557.1507663855623) (4.0022735595703125, 1301.0790998794914) (4.01776123046875, 1300.1047946170195) (4.01092529296875, 1574.622982759934) (4.009002685546875, 1557.1507663855623) (4.0022735595703125, 1301.0790998794914) (4.5085601806640625, 1294.423875089641) (4.501617431640625, 1400.321341083435) (4.4984130859375, 1402.6413876570555) (4.4914703369140625, 1293.5018395742725) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 6656991 ##.OBSERVE FREQUENCY=600 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=20 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (8.23, , <26>) (8.58, , <27>) (6.12, , <28>) (6.12, , <28>) (4.36,
, <29>) (4.36,
, <29>) (4.36,
, <29>) (4.36,
, <29>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <30>) (4.01,
, <31>) (4.01,
, <31>) (4.01,
, <31>) (4.01,
, <31>) (4.5,
, <36>) (4.5,
, <36>) (4.5,
, <36>) (4.5,
, <36>) ##END= ##END=