##TITLE=NP0000414, Submission ID 249, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Dimethyl sulfone ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C2 H6 O2 S ##ATOMLIST= 1 C 0 2 S 0 3 C 0 4 O 0 5 O 0 6 H 0 7 H 0 8 H 0 9 H 0 10 H 0 11 H 0 ##BONDLIST= 2 1 S 2 3 S 2 4 D 2 5 D 1 6 S 1 7 S 1 8 S 3 9 S 3 10 S 3 11 S ##$MOLFILE= RDKit 3D 11 10 0 0 0 0 0 0 0 0999 V2000 -1.4649 -0.4030 -0.0325 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0407 0.6299 -0.1792 S 0 0 1 0 0 6 0 0 0 0 0 0 1.4566 -0.2176 0.2417 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1257 1.0737 -1.6247 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1354 1.8714 0.6393 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.1754 0.1049 0.6487 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9678 -0.5675 -1.0080 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.1435 -1.3673 0.3956 H 0 0 0 0 0 0 0 0 0 0 0 0 1.5516 -0.4299 1.3149 H 0 0 0 0 0 0 0 0 0 0 0 0 1.4962 -1.1449 -0.3428 H 0 0 0 0 0 0 0 0 0 0 0 0 2.2976 0.4502 -0.0530 H 0 0 0 0 0 0 0 0 0 0 0 0 2 1 1 6 2 3 1 0 2 4 2 0 2 5 2 0 1 6 1 0 1 7 1 0 1 8 1 0 3 9 1 0 3 10 1 0 3 11 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58931.32,0.0 ##XUNITS=PPM ##FIRSTX=10.789115722318883 ##LASTX=-1.2089981347406367 ##MINX=-1.2089981347406367 ##MAXX=10.789115722318883 ##XFACTOR=0.00018307948206341962 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-1.2149679376533593 ##LASTY=-1.2409916307018194 ##MINY=-34569.996366344596 ##MAXY=10000.0 ##YFACTOR=1.055024761691476 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58931aKjJ%l%K%%kKJj%J%%j%J%kJJkJJjjL%lJJ%JjjJ%k%%J%k%LJkj%%JJ%j%JjkjLKlKKmJLljKj 58857@%KjkJ%%Jj%Jj%JljM%kJJ%%jJjkJK%jjJJkJ%jJJkJJ%kjJJ%%%%J%j%jJ%j%K%j%%JJ%ljJ%% 58783aJ%J%kKJlJJlJKkJJk%J%%JjjJ%%Jl%MjkLjkKk%JkKLm%JjKjkK%jLjl%JKJkjjJKkjJJJkkLK 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TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=6 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 15996001 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=6 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.138, , <6>) (3.138, , <7>) (3.138, , <8>) (3.138, , <9>) (3.138, , <10>) (3.138, , <11>) ##END= ##END= ##TITLE=NP0000414, Submission ID 249, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Dimethyl sulfone ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C2 H6 O2 S ##ATOMLIST= 1 C 0 2 S 0 3 C 0 4 O 0 5 O 0 6 H 0 7 H 0 8 H 0 9 H 0 10 H 0 11 H 0 ##BONDLIST= 2 1 S 2 3 S 2 4 D 2 5 D 1 6 S 1 7 S 1 8 S 3 9 S 3 10 S 3 11 S ##$MOLFILE= RDKit 3D 11 10 0 0 0 0 0 0 0 0999 V2000 -1.4649 -0.4030 -0.0325 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0407 0.6299 -0.1792 S 0 0 1 0 0 6 0 0 0 0 0 0 1.4566 -0.2176 0.2417 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1257 1.0737 -1.6247 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1354 1.8714 0.6393 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.1754 0.1049 0.6487 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9678 -0.5675 -1.0080 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.1435 -1.3673 0.3956 H 0 0 0 0 0 0 0 0 0 0 0 0 1.5516 -0.4299 1.3149 H 0 0 0 0 0 0 0 0 0 0 0 0 1.4962 -1.1449 -0.3428 H 0 0 0 0 0 0 0 0 0 0 0 0 2.2976 0.4502 -0.0530 H 0 0 0 0 0 0 0 0 0 0 0 0 2 1 1 6 2 3 1 0 2 4 2 0 2 5 2 0 1 6 1 0 1 7 1 0 1 8 1 0 3 9 1 0 3 10 1 0 3 11 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,58931.32,0.0 ##XUNITS=PPM ##FIRSTX=10.789115722318883 ##LASTX=-1.2089981347406367 ##MINX=-1.2089981347406367 ##MAXX=10.789115722318883 ##XFACTOR=0.00018307948206341962 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=-1.2149679376533593 ##LASTY=-1.2409916307018194 ##MINY=-34569.996366344596 ##MAXY=10000.0 ##YFACTOR=1.055024761691476 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58931aKjJ%l%K%%kKJj%J%%j%J%kJJkJJjjL%lJJ%JjjJ%k%%J%k%LJkj%%JJ%j%JjkjLKlKKmJLljKj 58857@%KjkJ%%Jj%Jj%JljM%kJJ%%jJjkJK%jjJJkJ%jJJkJJ%kjJJ%%%%J%j%jJ%j%K%j%%JJ%ljJ%% 58783aJ%J%kKJlJJlJKkJJk%J%%JjjJ%%Jl%MjkLjkKk%JkKLm%JjKjkK%jLjl%JKJkjjJKkjJJJkkLK 58709BjKjk%%%j%KjkK%j%jJLj%%kJJkjMJljK%j%jJKjj%%JljN%%Kk%JmjLj%JlJKkJ%kJ%jJK%%jj 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NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=6 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) (3.1379547119140625, 1666.6666666666665) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 15996001 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=6 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.138, , <6>) (3.138, , <7>) (3.138, , <8>) (3.138, , <9>) (3.138, , <10>) (3.138, , <11>) ##END= ##END=