NP-MRD: Showing NP-Card for (4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid (NP0289018)

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Record Information

Version

2.0

Created at

2022-09-09 19:00:21 UTC

Updated at

2022-09-09 19:00:22 UTC

NP-MRD ID

NP0289018

Secondary Accession Numbers

None

Natural Product Identification

Common Name

(4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

Description

(4E,7S)-N-{3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidic acid belongs to the class of organic compounds known as cyclohexenones. Cyclohexenones are compounds containing a cylohexenone moiety, which is a six-membered aliphatic ring that carries a ketone and has one endocyclic double bond. Based on a literature review very few articles have been published on (4E,7S)-N-{3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidic acid.

Structure

MOL 3D MOL SDF PDB SMILES InChI


  Mrv1652309092221002D          

 30 30  0  0  1  0            999 V2000
   -4.2081   -9.4323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3980   -9.2764    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.8579   -9.9000    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0477   -9.7441    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.5077  -10.3677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.6975  -10.2118    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.1574  -10.8355    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.6527  -10.6796    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    1.1928  -11.3032    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.0029  -11.1473    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5430  -11.7709    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.3531  -11.6150    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8932  -12.2387    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.7034  -12.0827    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    4.9734  -11.3032    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.2435  -12.7064    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    6.0536  -12.5505    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.3236  -11.7709    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    5.7835  -11.1473    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.0536  -10.3677    0.0000 Cl  0  0  0  0  0  0  0  0  0  0  0  0
    7.1338  -11.6150    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.4038  -10.8355    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.2139  -10.6796    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
    8.4840   -9.9000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.7540  -11.3032    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.4840  -12.0827    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.6739  -12.2387    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.4038  -13.0182    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    0.9227   -9.9000    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7329   -9.7441    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  7  8  1  0  0  0  0
  8  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  2  0  0  0  0
 11 12  1  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 14 15  1  0  0  0  0
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 16 17  1  4  0  0  0
 17 18  1  0  0  0  0
 18 19  2  0  0  0  0
 19 20  1  0  0  0  0
 18 21  1  0  0  0  0
 21 22  2  0  0  0  0
 22 23  1  0  0  0  0
 23 24  1  1  0  0  0
 23 25  1  0  0  0  0
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 26 27  1  0  0  0  0
 21 27  1  0  0  0  0
 27 28  2  0  0  0  0
  8 29  1  6  0  0  0
 29 30  1  0  0  0  0
M  END

     RDKit          3D

 68 68  0  0  0  0  0  0  0  0999 V2000
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   -6.8328    2.7087    1.4596 C   0  0  0  0  0  0  0  0  0  0  0  0
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    6.6651    0.2693   -0.1287 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.0687    0.3907   -0.6019 C   0  0  1  0  0  0  0  0  0  0  0  0
    8.2243    1.3501   -1.5691 O   0  0  0  0  0  0  0  0  0  0  0  0
    8.9781    0.6957    0.5962 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.9693   -0.5111    1.5332 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.7119   -1.3035    1.2746 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.7397   -2.5186    1.3916 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.1825   -2.0725   -2.8595 O   0  0  0  0  0  0  0  0  0  0  0  0
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M  END


  Mrv1652309092221002D          

 30 30  0  0  1  0            999 V2000
   -4.2081   -9.4323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.3980   -9.2764    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
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    6.0536  -10.3677    0.0000 Cl  0  0  0  0  0  0  0  0  0  0  0  0
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M  END
> <DATABASE_ID>
NP0289018

> <DATABASE_NAME>
NP-MRD

> <SMILES>
CCCCCCC[C@@H](C\C=C\CCC(O)=NC\C(=C\Cl)C1=C[C@@H](O)CCC1=O)OC

> <INCHI_IDENTIFIER>
InChI=1S/C24H38ClNO4/c1-3-4-5-6-8-11-21(30-2)12-9-7-10-13-24(29)26-18-19(17-25)22-16-20(27)14-15-23(22)28/h7,9,16-17,20-21,27H,3-6,8,10-15,18H2,1-2H3,(H,26,29)/b9-7+,19-17-/t20-,21-/m0/s1

> <INCHI_KEY>
YOJMGEDZKFQKKL-FZLMFBQKSA-N

> <FORMULA>
C24H38ClNO4

> <MOLECULAR_WEIGHT>
440.02

> <EXACT_MASS>
439.2489364

> <JCHEM_ACCEPTOR_COUNT>
5

> <JCHEM_ATOM_COUNT>
68

> <JCHEM_AVERAGE_POLARIZABILITY>
50.789925925898736

> <JCHEM_BIOAVAILABILITY>
0

> <JCHEM_DONOR_COUNT>
2

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
1

> <JCHEM_IUPAC>
(4E,7S)-N-[(2E)-3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

> <JCHEM_LOGP>
5.087971912666664

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
1

> <JCHEM_PHYSIOLOGICAL_CHARGE>
0

> <JCHEM_PKA>
14.807289756537514

> <JCHEM_PKA_STRONGEST_ACIDIC>
5.790612227937015

> <JCHEM_PKA_STRONGEST_BASIC>
3.6310018949678615

> <JCHEM_POLAR_SURFACE_AREA>
79.12000000000002

> <JCHEM_REFRACTIVITY>
125.11489999999998

> <JCHEM_ROTATABLE_BOND_COUNT>
15

> <JCHEM_RULE_OF_FIVE>
0

> <JCHEM_TRADITIONAL_IUPAC>
(4E,7S)-N-[(2E)-3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HEADER    PROTEIN                                 09-SEP-22   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   09-SEP-22         0                                  
HETATM    1  C   UNK     0      -7.855 -17.607   0.000  0.00  0.00           C+0
HETATM    2  C   UNK     0      -6.343 -17.316   0.000  0.00  0.00           C+0
HETATM    3  C   UNK     0      -5.335 -18.480   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0      -3.822 -18.189   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0      -2.814 -19.353   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0      -1.302 -19.062   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0      -0.294 -20.226   0.000  0.00  0.00           C+0
HETATM    8  C   UNK     0       1.218 -19.935   0.000  0.00  0.00           C+0
HETATM    9  C   UNK     0       2.227 -21.099   0.000  0.00  0.00           C+0
HETATM   10  C   UNK     0       3.739 -20.808   0.000  0.00  0.00           C+0
HETATM   11  C   UNK     0       4.747 -21.972   0.000  0.00  0.00           C+0
HETATM   12  C   UNK     0       6.259 -21.681   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0       7.267 -22.845   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0       8.780 -22.554   0.000  0.00  0.00           C+0
HETATM   15  O   UNK     0       9.284 -21.099   0.000  0.00  0.00           O+0
HETATM   16  N   UNK     0       9.788 -23.719   0.000  0.00  0.00           N+0
HETATM   17  C   UNK     0      11.300 -23.428   0.000  0.00  0.00           C+0
HETATM   18  C   UNK     0      11.804 -21.972   0.000  0.00  0.00           C+0
HETATM   19  C   UNK     0      10.796 -20.808   0.000  0.00  0.00           C+0
HETATM   20 Cl   UNK     0      11.300 -19.353   0.000  0.00  0.00          Cl+0
HETATM   21  C   UNK     0      13.316 -21.681   0.000  0.00  0.00           C+0
HETATM   22  C   UNK     0      13.820 -20.226   0.000  0.00  0.00           C+0
HETATM   23  C   UNK     0      15.333 -19.935   0.000  0.00  0.00           C+0
HETATM   24  O   UNK     0      15.837 -18.480   0.000  0.00  0.00           O+0
HETATM   25  C   UNK     0      16.341 -21.099   0.000  0.00  0.00           C+0
HETATM   26  C   UNK     0      15.837 -22.554   0.000  0.00  0.00           C+0
HETATM   27  C   UNK     0      14.325 -22.845   0.000  0.00  0.00           C+0
HETATM   28  O   UNK     0      13.820 -24.301   0.000  0.00  0.00           O+0
HETATM   29  O   UNK     0       1.722 -18.480   0.000  0.00  0.00           O+0
HETATM   30  C   UNK     0       3.235 -18.189   0.000  0.00  0.00           C+0
CONECT    1    2                                                            
CONECT    2    1    3                                                       
CONECT    3    2    4                                                       
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7                                                       
CONECT    7    6    8                                                       
CONECT    8    7    9   29                                                  
CONECT    9    8   10                                                       
CONECT   10    9   11                                                       
CONECT   11   10   12                                                       
CONECT   12   11   13                                                       
CONECT   13   12   14                                                       
CONECT   14   13   15   16                                                  
CONECT   15   14                                                            
CONECT   16   14   17                                                       
CONECT   17   16   18                                                       
CONECT   18   17   19   21                                                  
CONECT   19   18   20                                                       
CONECT   20   19                                                            
CONECT   21   18   22   27                                                  
CONECT   22   21   23                                                       
CONECT   23   22   24   25                                                  
CONECT   24   23                                                            
CONECT   25   23   26                                                       
CONECT   26   25   27                                                       
CONECT   27   26   21   28                                                  
CONECT   28   27                                                            
CONECT   29    8   30                                                       
CONECT   30   29                                                            
MASTER        0    0    0    0    0    0    0    0   30    0   60    0
END

View in JSmol

Synonyms

Value	Source
(4E,7S)-N-{3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl}-7-methoxytetradec-4-enimidate	Generator

Chemical Formula

C₂₄H₃₈ClNO₄

Average Mass

440.0200 Da

Monoisotopic Mass

439.24894 Da

IUPAC Name

(4E,7S)-N-[(2E)-3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

Traditional Name

(4E,7S)-N-[(2E)-3-chloro-2-[(3S)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid

CAS Registry Number

Not Available

SMILES

CCCCCCC[C@@H](C\C=C\CCC(O)=NC\C(=C\Cl)C1=C[C@@H](O)CCC1=O)OC

InChI Identifier

InChI=1S/C24H38ClNO4/c1-3-4-5-6-8-11-21(30-2)12-9-7-10-13-24(29)26-18-19(17-25)22-16-20(27)14-15-23(22)28/h7,9,16-17,20-21,27H,3-6,8,10-15,18H2,1-2H3,(H,26,29)/b9-7+,19-17-/t20-,21-/m0/s1

InChI Key

YOJMGEDZKFQKKL-FZLMFBQKSA-N

Experimental Spectra

Not Available

Predicted Spectra

Spectrum Type	Description	Depositor ID	Depositor Organization	Depositor	Deposition Date	View
1D NMR	¹³C NMR Spectrum (1D, 25 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 100 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 252 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 1000 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 50 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 200 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 75 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 300 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 101 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 400 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 126 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 500 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 151 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 600 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 176 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 700 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 201 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 800 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹³C NMR Spectrum (1D, 226 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum
1D NMR	¹H NMR Spectrum (1D, 900 MHz, H₂O, predicted)	Wishart Lab	Wishart Lab	David Wishart	2021-06-20	View Spectrum

Chemical Shift Submissions

Not Available

Species

Species of Origin

Not Available

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as cyclohexenones. Cyclohexenones are compounds containing a cylohexenone moiety, which is a six-membered aliphatic ring that carries a ketone and has one endocyclic double bond.

Kingdom

Organic compounds

Super Class

Organic oxygen compounds

Class

Organooxygen compounds

Sub Class

Carbonyl compounds

Direct Parent

Cyclohexenones

Alternative Parents

Substituents

Cyclohexenone
Fatty amide
N-acyl-amine
Fatty acyl
Carboxamide group
Secondary alcohol
Secondary carboxylic acid amide
Carboxylic acid derivative
Dialkyl ether
Ether
Chloroalkene
Haloalkene
Vinyl chloride
Vinyl halide
Hydrocarbon derivative
Organohalogen compound
Organochloride
Organonitrogen compound
Alcohol
Organic nitrogen compound
Organic oxide
Aliphatic homomonocyclic compound

Molecular Framework

Aliphatic homomonocyclic compounds

External Descriptors

Not Available

Physical Properties

State

Not Available

Experimental Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Predicted Properties

Property	Value	Source
logP	5.09	ChemAxon
pKa (Strongest Acidic)	5.79	ChemAxon
pKa (Strongest Basic)	3.63	ChemAxon
Physiological Charge	0	ChemAxon
Hydrogen Acceptor Count	5	ChemAxon
Hydrogen Donor Count	2	ChemAxon
Polar Surface Area	79.12 Å²	ChemAxon
Rotatable Bond Count	15	ChemAxon
Refractivity	125.11 m³·mol⁻¹	ChemAxon
Polarizability	50.79 Å³	ChemAxon
Number of Rings	1	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	Yes	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

External Links

HMDB ID

Not Available

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FoodDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

10275266

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

21668294

PDB ID

Not Available

ChEBI ID

Not Available

Good Scents ID

Not Available

References

General References

LOTUS database [Link]

Showing NP-Card for (4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid (NP0289018)

MOL for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D MOL for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D SDF for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D-SDF for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

PDB for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D PDB for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

SMILES for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

INCHI for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

Structure for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)

3D Structure for NP0289018 ((4e,7s)-n-[(2e)-3-chloro-2-[(3s)-3-hydroxy-6-oxocyclohex-1-en-1-yl]prop-2-en-1-yl]-7-methoxytetradec-4-enimidic acid)